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1.发明授权Reaction of perfluoroolefins with Bis (Silyl) ethers to produce fluorinated compounds 失效全氟烯烃与双（甲硅烷基）醚的反应生成氟化物
公开(公告)号：US5969074A
公开(公告)日：1999-10-19
申请号：US64575
申请日：1993-05-21
IPC分类号： C07C43/13 , C07C43/17 , C07C43/192 , C07C43/247 , C07D323/00 , C07F7/18 , C08F20/14 , C08F214/18 , C08G65/00 , C08G65/336 , C08G65/34 , C08G67/00 , C07D317/16 , C07D321/00 , C07D319/12
CPC分类号： C07C43/17 , C07C43/137 , C07C43/192 , C07C43/247 , C07D323/00 , C07F7/1852 , C08F20/14 , C08F214/186 , C08G65/007 , C08G65/336 , C08G65/34 , C07C2101/04 , C07C2101/06
摘要： A reaction of perfluoroolefins with bis(silyl) ethers to produce novel partially fluorinated and perfluorinated copolymers and macrocyclic compounds is disclosed.
摘要翻译： 公开了全氟烯烃与双（甲硅烷基）醚的反应以产生新的部分氟化和全氟化的共聚物和大环化合物。
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2.发明授权Fluorinated polymers useful as photoresists, and processes for microlithography 失效用作光致抗蚀剂的氟化聚合物，以及微光刻法公开(公告)号：US07312287B2
公开(公告)日：2007-12-25
申请号：US10523490
申请日：2003-08-19
IPC分类号： C08F120/22
CPC分类号： C08F232/00 , C08F8/12 , C08F214/18 , C08F214/26 , C08F220/24 , C08F220/26 , C08F232/08 , C08F2800/20 , G03F7/0046 , G03F7/0395
摘要： This invention provides a fluorine-containing copolymer having a repeat unit derived from at least one fluorinated olefin and a repeat unit derived from at least one polycyclic ethylenically unsaturated monomer having pendant hydroxyl or esterified hydroxyl groups, and optionally other repeat units, typically derived from an acrylate. These polymers have high transparency at short wavelengths such as 193 nm and 157 nm, and provide good plasma etch resistance and adhesive properties. Also provided are photoresist compositions and substrates coated therewith.
摘要翻译： 本发明提供了含有至少一种氟化烯烃的重复单元和衍生自至少一种具有羟基或酯化羟基的多环烯属不饱和单体的重复单元的含氟共聚物，以及任选的其它重复单元，通常衍生自 丙烯酸酯。 这些聚合物在短波长如193nm和157nm处具有高透明度，并且提供良好的等离子体耐蚀刻性和粘合性。 还提供了光刻胶组合物和其上涂覆的基材。
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公开(公告)号：US07022457B2
公开(公告)日：2006-04-04
申请号：US10669492
申请日：2003-09-24
CPC分类号： G03F7/0395 , G03F7/0046 , G03F7/0397 , Y10S430/106 , Y10S430/108 , Y10S430/111 , Y10S430/115
摘要： The present invention pertains to photoimaging and the use of photoresists (positive-working and/or negative-working) for imaging in the production of semiconductor devices. The present invention also pertains to novel hydroxy ester-containing polymer compositions that are useful as base resins in resists and potentially in many other applications.
摘要翻译： 本发明涉及在制造半导体器件中的光成像和光致抗蚀剂（正性和/或负性）用于成像的用途。 本发明还涉及可用作抗蚀剂中的潜在的许多其它应用中的基础树脂的新型含羟基酯的聚合物组合物。
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公开(公告)号：US06486280B1
公开(公告)日：2002-11-26
申请号：US09615975
申请日：2000-07-14
申请人： Colin Anolick , Viacheslav Alexandrovich Petrov , Bruce Edmund Smart , Charles Winfield Stewart , Robert Clayton Wheland , William Brown Farnham , Andrew Edward Feiring , Weiming Qiu
发明人： Colin Anolick , Viacheslav Alexandrovich Petrov , Bruce Edmund Smart , Charles Winfield Stewart , Robert Clayton Wheland , William Brown Farnham , Andrew Edward Feiring , Weiming Qiu
IPC分类号： C08F1418
CPC分类号： C07C313/20 , C07C317/04 , C07C317/18 , C08F214/18 , C08F214/22 , C08F214/26 , C08F214/265 , C08F214/28 , C08L23/02 , C08L27/18 , C09D127/18 , C09D127/20 , C08L2666/04
摘要： Disclosed herein are novel amorphous tetrafluoroethylene-hexafluoropropylene (TFE-HFP) dipolymers, and other copolymers containing TFE, HFP and a third monomer, many of which are more random than previous amorphous TFE-HFP copolymers, as well as a novel high productivity continuous process for making these polymers. The polymers are particularly useful in the form of coatings, films and encapsulants.
摘要翻译： 本文公开了新型无定形四氟乙烯 - 六氟丙烯（TFE-HFP）二元聚合物，以及含有TFE，HFP和第三单体的其它共聚物，其中许多比以前的无定形TFE-HFP共聚物更随机，以及新颖的高生产率连续方法 用于制备这些聚合物。 聚合物特别可用于涂料，薄膜和密封剂的形式。
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公开(公告)号：US07632966B2
公开(公告)日：2009-12-15
申请号：US11578268
申请日：2005-05-11
IPC分类号： C07C327/00 , C07C329/00 , C01B31/00
CPC分类号： C08F2/38 , C07C329/00
摘要： This invention provides an efficient method for synthesizing trithiocarbonate RAFT agents, RSC(S)SR′, that can be used in the living polymerization of methacrylates and other olefinic monomers. This invention also provides an efficient method of synthesizing bis(alkylsulfanylthiocarbonyl) disulfides that are useful as intermediates in the synthesis of trithiocarbonate RAFT agents.
摘要翻译： 本发明提供了可用于甲基丙烯酸酯和其它烯烃单体的活性聚合中的三硫代碳酸酯RAFT试剂RSC（S）SR'的有效方法。 本发明还提供了合成双（烷基硫烷基硫代羰基）二硫化物的有效方法，其可用作合成三硫代碳酸酯RAFT试剂的中间体。
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6.发明授权Fluorinated polymers having polycyclic groups with fused 4-membered carbocyclic rings, useful as photoresists, and processes for microlithography 失效具有稠合的4元碳环多环基团的氟化聚合物，可用作光致抗蚀剂，以及用于微光刻公开(公告)号：US07264914B2
公开(公告)日：2007-09-04
申请号：US10523491
申请日：2003-08-08
申请人： Andrew E. Feiring , Frank L Schadt, III , Viacheslav Alexandrovich Petrov , Bruce Edmund Smart , William Brown Farnham
发明人： Andrew E. Feiring , Frank L Schadt, III , Viacheslav Alexandrovich Petrov , Bruce Edmund Smart , William Brown Farnham
IPC分类号： G03F7/004 , C08F232/04
CPC分类号： C08F214/18 , C08F214/26 , C08F220/24 , C08F232/08 , G03F7/0046 , G03F7/0382 , G03F7/0395 , Y10S430/106 , Y10S430/108 , Y10S430/111
摘要： This invention provides novel fluorine containing polymers which comprise at least one fluorinated olefin, at least one polycyclic ethylenically unsaturated monomer with a fused 4-membered carbocyclic ring and, optionally, other components. The polymers are useful for photoimaging compositions and, in particular, photoresist compositions (positive-working and/or negative-working) for imaging in the production of semiconductor devices. The polymers are especially useful in photoresist compositions having high UV transparency (particularly at short wavelengths, e.g., 157 nm) which are useful as base resins in resists and potentially in many other applications.
摘要翻译： 本发明提供新颖的含氟聚合物，其包含至少一种氟化烯烃，至少一种具有稠合的4元碳环的多烯键式不饱和单体和任选的其它组分。 聚合物可用于光成像组合物，特别是用于制造半导体器件的成像的光致抗蚀剂组合物（正性和/或负性）。 聚合物特别适用于具有高UV透明度（特别是短波长，例如157nm）的光致抗蚀剂组合物，其可用作抗蚀剂中的基础树脂并且潜在地在许多其它应用中。
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公开(公告)号：US06287722B1
公开(公告)日：2001-09-11
申请号：US09383129
申请日：1999-08-25
申请人： Kelly David Barton , Christopher Marc Doyle , William Brown Farnham , Charlie David Lang , Antonio Vidal
发明人： Kelly David Barton , Christopher Marc Doyle , William Brown Farnham , Charlie David Lang , Antonio Vidal
IPC分类号： H01M204
CPC分类号： H01G9/025 , B29C47/00 , B29C47/0021 , H01M4/13 , H01M4/139 , H01M6/181 , H01M8/1025 , H01M8/1039 , H01M8/1072 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M2300/0082 , H01M2300/0094 , Y02P70/56
摘要： The invention concerns a process for melt forming conductive compositions comprising ionomers into multi-layer electrochemical cells suitable for use in electrochemical applications such as batteries, fuel cells, electrolysis cells, ion exchange membranes, sensors, electrochemical capacitors, and modified electrodes.
摘要翻译： 本发明涉及将包含离聚物的导电组合物熔融形成为适用于电化学应用如电池，燃料电池，电解槽，离子交换膜，传感器，电化学电容器和改性电极的多层电化学电池的方法。
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8.发明授权
公开(公告)号：US5670679A
公开(公告)日：1997-09-23
申请号：US458784
申请日：1995-06-02
IPC分类号： C07B31/00 , C07B37/02 , C07B61/00 , C07C17/00 , C07C17/281 , C07C17/354 , C07C17/361 , C07C19/08 , C07C19/10 , C07C22/08 , C07C43/12 , C07C69/63 , C07C255/10 , C07F15/04 , C07F17/00 , C07F9/02
CPC分类号： C07F15/04 , C07B31/00 , C07B37/02 , C07B61/00 , C07C17/281 , C07C17/361 , C07C19/08 , C07C19/10 , C07C22/08 , C07C255/10 , C07C43/123 , C07C69/63
摘要： A process is disclosed for the manufacture of product compounds of the formula HC(R.sup.1).sub.2 C(R.sup.1).sub.2 C(R.sup.2).sub.2 C(R.sup.2).sub.2 H wherein each R.sup.1 is independently selected from the group consisting of H, F, Cl, CN, R, OR, CO.sub.2 R, C(O)R, OC(O)R, R.sup.f, OR.sup.f, CO.sub.2 R.sup.f C(O)R.sup.f and OC(O)R.sup.f where R is a hydrocarbyl group and R.sup.f is a C.sub.1 to C.sub.10 polyfluoroalkyl group, provided that at least one R.sup.1 is F, and wherein each R.sup.2 is independently selected from the group consisting of H, F, Cl, CN, R, OR, CO.sub.2 R, C(O)R, OC(O)R, R.sup.f, OR.sup.f, CO.sub.2 R.sup.f, C(O)R.sup.f, OC(O)R.sup.f and difunctional linkages where an R.sup.2 group on each of two adjacent carbon atoms together form a link selected from the group consisting of --CH.sub.2 CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH(CH.sub.3 --, --CH.sub.2 CH(CH.sub.3)CH.sub.2 --, --C(O)OC(O)--, and norborndiyl. The process involves reacting a metallacycle of the formula L.sub.m M(1,4-C(R.sup.1).sub.2 C(R.sup.1).sub.2 C(R.sup.2).sub.2 C(R.sup.2).sub.2 --) wherein R.sup.1 and R.sup.2 are as defined above, and wherein M is a metal selected from the group consisting of Group 8, Group 9 and Group 10 metals, each L is a ligand selected from the group consisting of Group 14, Group 15 and Group 16 ligands, and m is an integer from 1 to 4, in the liquid phase with hydrogen. Also disclosed are certain compositions comprising product compounds within the above product compound formula and certain metallacycle compounds within the above metallacycle formula.
摘要翻译： 公开了制备式HC（R1）2C（R1）2C（R2）2C（R2）2H的产物化合物的方法，其中每个R 1独立地选自H，F，Cl，CN，R ，OR，CO 2 R，C（O）R，OC（O）R，R f，OR f，CO 2 R f C（O）R f和OC（O）R f，其中R是烃基，Rf是C1至C10多氟烷基， 至少一个R1是F，并且其中每个R 2独立地选自H，F，Cl，CN，R，OR，CO 2 R，C（O）R，OC（O）R，R f，OR f， CO 2 R f，C（O）R f，OC（O）R f和双官能键，其中两个相邻碳原子上的每一个上的R 2基团一起形成选自-CH 2 CH 2 CH 2 - ， - CH 2 CH 2 CH 2 CH 2 - ， - CH 2 CH 2 CH 所述方法包括使式LmM（1,4-C（R 1）2 C（R 1）2 C（R 2））的金属环反应， 2C（R2）2-）其中R1和R2如上定义，并且其中M是选自第8族，第9族和第10族金属的金属，每个L是配体 选自第14族，第15族和第16族配体，m为1至4的整数，在液相中为氢。 还公开了包含上述产物化合物式中的产物化合物和上述金属环状配方中的某些金属环化合物的某些组合物。
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公开(公告)号：US5639837A
公开(公告)日：1997-06-17
申请号：US658676
申请日：1996-06-04
CPC分类号： C08F14/18
摘要： Disclosed herein is a process in which fluorine containing olefins are polymerized using an initiation system which is a combination of a fluoroaliphatic sulfinate or sulfinic acid and chlorate, bromate or hypochlorite ions. The resulting polymer contains fewer deleterious end groups and is more stable and/or easier to process. The polymers produced are useful as thermoplastics and elastomers.
摘要翻译： 本文公开的是使用作为氟代脂族亚磺酸盐或亚磺酸与氯酸盐，溴酸盐或次氯酸盐离子的组合的引发体系聚合含氟烯烃的方法。 所得聚合物含有较少有害的末端基团并且更稳定和/或更容易加工。 所生产的聚合物可用作热塑性塑料和弹性体。
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公开(公告)号：US07807755B2
公开(公告)日：2010-10-05
申请号：US11578226
申请日：2005-05-11
CPC分类号： C08F8/04 , C08F2438/03 , C08F2800/10 , C08F2800/20 , C08F2220/281 , C08F2220/1833 , C08F212/14 , C08F2220/1825 , C08F220/14 , C08F212/08
摘要： This invention provides a method for removing certain sulfur-containing groups from polymers, especially those made via RAFT polymerization processes.
摘要翻译： 本发明提供从聚合物中去除某些含硫基团的方法，特别是通过RAFT聚合方法制备的那些。
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