公开(公告)号：US20110245376A1

公开(公告)日：2011-10-06

申请号：US13133878

申请日：2009-12-17

申请人： William J. Schultz ,  Chad A. Haraldson ,  Nathan E. Schultz ,  Wendy L. Thompson ,  James E. Thorson ,  Douglas P. Goetz ,  Steven C. Hackett ,  James M. Nelson

发明人： William J. Schultz ,  Chad A. Haraldson ,  Nathan E. Schultz ,  Wendy L. Thompson ,  James E. Thorson ,  Douglas P. Goetz ,  Steven C. Hackett ,  James M. Nelson

IPC分类号： C08L63/00 ,  C08L21/00

CPC分类号： C08L63/00

摘要： Compositions comprising surface-modified nanocalcite particles dispersed in a curable resin, and to coatings and fibrous composites incorporating such compositions are described. The surface-modifying agents include a binding group ionically associated with the calcite and a compatiblizing segment, compatible with the curable resin. The surface-modifying agent may also include a reactive group capable of reacting with the curable resin. Methods of preparing nanocalcite composites and coating a fibrous composites prepared from such nanocalcite composites are also described.

摘要翻译： 描述了包含分散在可固化树脂中的表面改性纳米碳酸钙颗粒的组合物，以及包含这种组合物的涂料和纤维复合材料。 表面改性剂包括与方解石离子键合的结合基团和与可固化树脂相容的相容片段。 表面改性剂也可以包括能够与可固化树脂反应的反应性基团。 还描述了制备纳米碳酸钙复合材料和涂覆由这种纳米碳酸钙复合材料制备的纤维复合材料的方法。

公开(公告)号：US09221970B2

公开(公告)日：2015-12-29

申请号：US13133878

申请日：2009-12-17

申请人： William J. Schultz ,  Chad A. Haraldson ,  Nathan E. Schultz ,  Wendy L. Thompson ,  James E. Thorson ,  Douglas P. Goetz ,  Steven C. Hackett ,  James M. Nelson

发明人： William J. Schultz ,  Chad A. Haraldson ,  Nathan E. Schultz ,  Wendy L. Thompson ,  James E. Thorson ,  Douglas P. Goetz ,  Steven C. Hackett ,  James M. Nelson

IPC分类号： C08L63/00

CPC分类号： C08L63/00

摘要： Compositions comprising surface-modified nanocalcite particles dispersed in a curable resin, and to coatings and fibrous composites incorporating such compositions are described. The surface-modifying agents include a binding group ionically associated with the calcite and a compatiblizing segment, compatible with the curable resin. The surface-modifying agent may also include a reactive group capable of reacting with the curable resin. Methods of preparing nanocalcite composites and coating a fibrous composites prepared from such nanocalcite composites are also described.

摘要翻译： 描述了包含分散在可固化树脂中的表面改性纳米碳酸钙颗粒的组合物，以及包含这种组合物的涂料和纤维复合材料。 表面改性剂包括与方解石离子键合的结合基团和与可固化树脂相容的相容片段。 表面改性剂也可以包括能够与可固化树脂反应的反应性基团。 还描述了制备纳米碳酸钙复合材料和涂覆由这种纳米碳酸钙复合材料制备的纤维复合材料的方法。

公开(公告)号：US10035909B2

公开(公告)日：2018-07-31

申请号：US13502836

申请日：2009-12-17

申请人： William J. Schultz ,  Mary I. Buckett ,  Peter D. Condo ,  Douglas P. Goetz ,  Chad A. Haraldson ,  Mark McCormick ,  Wendy L. Thompson ,  Steven J. Pachuta

发明人： William J. Schultz ,  Mary I. Buckett ,  Peter D. Condo ,  Douglas P. Goetz ,  Chad A. Haraldson ,  Mark McCormick ,  Wendy L. Thompson ,  Steven J. Pachuta

IPC分类号： C08L63/00 ,  C08K3/26 ,  C08K9/04 ,  C08K5/42 ,  C08K9/08

CPC分类号： C08L63/00 ,  C08K3/26 ,  C08K5/42 ,  C08K9/04 ,  C08K2003/265

摘要： Compositions comprising surface-modified calcite nanoparticles dispersed in a curable resin and to coatings and fibrous composites incorporating such compositions are described. The nanocalcite particles have a high magnesium to calcium surface concentration ratio. The surface-modifying agents include a binding group ionically associated with the nanoparticles, and a compatiblizing segment compatible with the curable resin. The surface-modifying agent may also include a reactive group capable of reacting with the curable resin. Methods of preparing nanocalcite composites, and coatings and fibrous composites prepared from such nanocalcite composites are also described.

公开(公告)号：US20120245253A1

公开(公告)日：2012-09-27

申请号：US13502836

申请日：2009-12-17

申请人： William J. Schultz ,  Mary I. Buckett ,  Peter D. Condo ,  Douglas P. Goetz ,  Chad A. Haraldson ,  Mark McCormick ,  Wendy L. Thompson ,  Steven J. Pachuta

发明人： William J. Schultz ,  Mary I. Buckett ,  Peter D. Condo ,  Douglas P. Goetz ,  Chad A. Haraldson ,  Mark McCormick ,  Wendy L. Thompson ,  Steven J. Pachuta

IPC分类号： C09D163/00 ,  B05D3/00

CPC分类号： C08L63/00 ,  C08K3/26 ,  C08K5/42 ,  C08K9/04

摘要： Compositions comprising surface-modified calcite nanoparticles dispersed in a curable resin and to coatings and fibrous composites incorporating such compositions are described. The nanocalcite particles have a high magnesium to calcium surface concentration ratio. The surface-modifying agents include a binding group ionically associated with the nanoparticles, and a compatiblizing segment compatible with the curable resin. The surface-modifying agent may also include a reactive group capable of reacting with the curable resin. Methods of preparing nanocalcite composites, and coatings and fibrous composites prepared from such nanocalcite composites are also described.

摘要翻译： 描述了包含分散在可固化树脂中的表面改性方解石纳米颗粒的组合物和包含这种组合物的涂层和纤维复合材料。 纳米碳酸钙颗粒具有高镁/钙表面浓度比。 表面改性剂包括与纳米颗粒离子键合的结合基团和与可固化树脂相容的相容片段。 表面改性剂也可以包括能够与可固化树脂反应的反应性基团。 还描述了制备纳米碳酸钙复合材料的方法，以及由这种纳米碳酸钙复合材料制备的涂层和纤维复合材料。

公开(公告)号：US09783681B2

公开(公告)日：2017-10-10

申请号：US13500836

申请日：2010-10-21

申请人： Peter D. Condo ,  Jung-Sheng Wu ,  Chad A. Haraldson ,  William J. Schultz ,  Emily S. Goenner ,  James E. Thorson ,  Wendy L. Thompson

发明人： Peter D. Condo ,  Jung-Sheng Wu ,  Chad A. Haraldson ,  William J. Schultz ,  Emily S. Goenner ,  James E. Thorson ,  Wendy L. Thompson

IPC分类号： C09C1/02 ,  C09C3/04 ,  C09C3/08 ,  C08J3/20 ,  C08K3/26 ,  C08K5/42 ,  C08K5/51 ,  C08K5/521 ,  C08K5/5317 ,  B82Y30/00 ,  C01F11/18

CPC分类号： C09C1/021 ,  B82Y30/00 ,  C01P2004/62 ,  C01P2004/64 ,  C08J3/203 ,  C08J2367/06

摘要： Methods of compounding nanoparticles with a resin, e.g., a curable resin and one or more surface modifying agents are described. The methods use wet milling technology, including both continuous and batch milling processes, and can be used to functionalize the nanoparticles and disperse the functionalized nanoparticles into the resin system in a single process. Methods of compounding curable resin systems containing reactive diluents are also disclosed.

公开(公告)号：US20120214948A1

公开(公告)日：2012-08-23

申请号：US13500836

申请日：2010-10-21

申请人： Peter D. Condo ,  Jung-Sheng Wu ,  Chad A. Haraldson ,  William J. Schultz ,  Emily S. Goenner ,  James E. Thorson ,  Wendy L. Thompson

发明人： Peter D. Condo ,  Jung-Sheng Wu ,  Chad A. Haraldson ,  William J. Schultz ,  Emily S. Goenner ,  James E. Thorson ,  Wendy L. Thompson

IPC分类号： C08F118/04 ,  C08G59/02 ,  B82Y30/00

CPC分类号： C09C1/021 ,  B82Y30/00 ,  C01P2004/62 ,  C01P2004/64 ,  C08J3/203 ,  C08J2367/06

摘要： Methods of compounding nanoparticles with a resin, e.g., a curable resin and one or more surface modifying agents are described. The methods use wet milling technology, including both continuous and batch milling processes, and can be used to functionalize the nanoparticles and disperse the functionalized nanoparticles into the resin system in a single process. Methods of compounding curable resin systems containing reactive diluents are also disclosed.

摘要翻译： 描述了将纳米颗粒与树脂例如可固化树脂和一种或多种表面改性剂混合的方法。 该方法使用湿式研磨技术，包括连续和间歇式研磨方法，并且可用于官能化纳米颗粒并且在单一工艺中将功能化纳米颗粒分散到树脂体系中。 还公开了含有反应性稀释剂的可固化树脂体系的混合方法。

公开(公告)号：US20110028605A1

公开(公告)日：2011-02-03

申请号：US12933526

申请日：2009-03-26

申请人： James M. Nelson ,  Matthrew N. Archibald ,  Brant U. Kolb ,  Wendy L. Thompson ,  William J. Schultz ,  Steven C. Hackett

发明人： James M. Nelson ,  Matthrew N. Archibald ,  Brant U. Kolb ,  Wendy L. Thompson ,  William J. Schultz ,  Steven C. Hackett

IPC分类号： C08L63/00 ,  C08K5/541 ,  C08K5/17 ,  C08K5/36 ,  C08K5/09

CPC分类号： C08J3/20 ,  B82Y30/00 ,  C08J5/005 ,  C08J2323/04

摘要： A method of making a filled resin includes providing functionalized particles; and combining and homogenously mixing the functionalized particles with an organic matrix in a vacuum kneader to provide the filled resin so that the functionalized particles comprise at least about 20% by weight of the filled resin. The step of providing functionalized particles can also include providing a feedstock of (i) untreated particles, (ii) a surface treatment agent reactive with the particles, and (iii) solvent, and directing the feedstock through a continuous reactor maintained at a temperature sufficient to react the particles with the surface treatment agent to provide the functionalized particles in less than about 4 hours; and directing the functionalized particles from the continuous reactor directly into the vacuum kneader. In another aspect, the a finished resin comprises at least about 20% by weight of functionalized particles in an organic matrix.

摘要翻译： 制备填充树脂的方法包括提供官能化颗粒; 并在真空捏合机中将官能化颗粒与有机基质混合并均匀混合以提供填充的树脂，使得官能化颗粒占填充树脂的至少约20重量％。 提供官能化颗粒的步骤还可以包括提供（i）未处理颗粒的原料，（ii）与颗粒反应的表面处理剂，和（iii）溶剂，并引导原料通过维持在足够温度的连续反应器 使颗粒与表面处理剂反应以在小于约4小时内提供官能化颗粒; 并将来自连续反应器的官能化颗粒直接引入真空捏合机中。 在另一方面，成品树脂包含至少约20重量％的有机基质中的官能化颗粒。

公开(公告)号：US08487019B2

公开(公告)日：2013-07-16

申请号：US12933526

申请日：2009-03-26

申请人： James M. Nelson ,  Matthew N. Archibald ,  Brant U. Kolb ,  Wendy L. Thompson ,  William J. Schultz ,  Steven C. Hackett

发明人： James M. Nelson ,  Matthew N. Archibald ,  Brant U. Kolb ,  Wendy L. Thompson ,  William J. Schultz ,  Steven C. Hackett

IPC分类号： C08J3/02 ,  C08K9/00

CPC分类号： C08J3/20 ,  B82Y30/00 ,  C08J5/005 ,  C08J2323/04

摘要： A method of making a filled resin includes providing functionalized particles; and combining and homogenously mixing the functionalized particles with an organic matrix in a vacuum kneader to provide the filled resin so that the functionalized particles comprise at least about 20% by weight of the filled resin. The step of providing functionalized particles can also include providing a feedstock of (i) untreated particles, (ii) a surface treatment agent reactive with the particles, and (iii) solvent, and directing the feedstock through a continuous reactor maintained at a temperature sufficient to react the particles with the surface treatment agent to provide the functionalized particles in less than about 4 hours; and directing the functionalized particles from the continuous reactor directly into the vacuum kneader. In another aspect, the a finished resin comprises at least about 20% by weight of functionalized particles in an organic matrix.

摘要翻译： 制备填充树脂的方法包括提供官能化颗粒; 并在真空捏合机中将官能化颗粒与有机基质混合并均匀混合以提供填充的树脂，使得官能化颗粒占填充树脂的至少约20重量％。 提供官能化颗粒的步骤还可以包括提供（i）未处理颗粒的原料，（ii）与颗粒反应的表面处理剂，和（iii）溶剂，并引导原料通过维持在足够温度的连续反应器 使颗粒与表面处理剂反应以在小于约4小时内提供官能化颗粒; 并将来自连续反应器的官能化颗粒直接引入真空捏合机中。 在另一方面，成品树脂包含至少约20重量％的有机基质中的官能化颗粒。

公开(公告)号：US20110097212A1

公开(公告)日：2011-04-28

申请号：US12997939

申请日：2009-06-16

申请人： Wendy L. Thompson ,  William J. Schultz ,  MIchael A. Kropp ,  Jayshree Seth ,  Douglas P. Goetz ,  Andrew M. Hine

发明人： Wendy L. Thompson ,  William J. Schultz ,  MIchael A. Kropp ,  Jayshree Seth ,  Douglas P. Goetz ,  Andrew M. Hine

IPC分类号： F03D11/00 ,  C08L63/00 ,  C09D163/00 ,  C09J163/00 ,  B82Y30/00

CPC分类号： C08L63/00 ,  C08K9/04 ,  C08L51/003 ,  C08L2666/04 ,  C08L2666/54

摘要： Toughened curable compositions are described. The curable compositions include a curable resin, surface-modified nanoparticles, and rubber nano-domains. Both core-shell rubber nano-domains, and nano-rubber domains arising from self-assembled block co-polymers are disclosed. Toughened, cured resin compositions, and articles comprising such cured compositions are also discussed.

摘要翻译： 描述了增韧的可固化组合物。 可固化组合物包括可固化树脂，表面改性纳米颗粒和橡胶纳米结构域。 公开了两种核 - 壳橡胶纳米域和由自组装嵌段共聚物引起的纳米橡胶畴。 还讨论了增韧的固化树脂组合物和包含这种固化组合物的制品。

公开(公告)号：US07327039B2

公开(公告)日：2008-02-05

申请号：US10441879

申请日：2003-05-20

申请人： Scott B. Charles ,  Kathleen M. Gross ,  Steven C. Hackett ,  Michael A. Kropp ,  William J. Schultz ,  Wendy L. Thompson

发明人： Scott B. Charles ,  Kathleen M. Gross ,  Steven C. Hackett ,  Michael A. Kropp ,  William J. Schultz ,  Wendy L. Thompson

IPC分类号： H01L23/48 ,  H01L23/52 ,  H01L29/40 ,  H01L21/44 ,  H01L21/48 ,  H01L21/50

CPC分类号： H01L23/295 ,  H01L21/563 ,  H01L23/293 ,  H01L24/29 ,  H01L2224/16 ,  H01L2224/2929 ,  H01L2224/29386 ,  H01L2224/73203 ,  H01L2224/73204 ,  H01L2924/01004 ,  H01L2924/01012 ,  H01L2924/01019 ,  H01L2924/0102 ,  H01L2924/01021 ,  H01L2924/01029 ,  H01L2924/01046 ,  H01L2924/01057 ,  H01L2924/01063 ,  H01L2924/01066 ,  H01L2924/01067 ,  H01L2924/01068 ,  H01L2924/01077 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/01087 ,  H01L2924/01322 ,  H01L2924/10253 ,  H01L2924/14 ,  H05K3/305 ,  H01L2924/00 ,  H01L2924/0665 ,  H01L2924/05442

摘要： The invention provides electronic articles and methods of making said articles. The electronic articles comprise an electronic component bonded and electrically connected to a substrate using an underfill adhesive comprising the reaction product of a thermosetting resin, curing catalyst, and surface-treated nanoparticles that are substantially spherical, non-agglomerated, amorphous, and solid.

摘要翻译： 本发明提供了制造所述制品的电子制品和方法。 电子制品包括使用包含热固性树脂，固化催化剂和基本上球形，非聚集，无定形和固体的表面处理纳米颗粒的反应产物的底部填充粘合剂粘合并电连接到基底的电子部件。