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    Process for producing vinyl ether compounds
    1.
    发明授权
    Process for producing vinyl ether compounds 失效
    制备乙烯基醚化合物的方法

    公开(公告)号：US07074970B2

    公开(公告)日：2006-07-11

    申请号：US10231115

    申请日：2002-08-30

    申请人： Yasutaka Ishii ,  Tatsuya Nakano ,  Keizo Inoue

    发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Keizo Inoue

    IPC分类号： C07C43/00

    CPC分类号： C07D313/10 ,  C07C41/16 ,  C07C43/162 ,  C07C49/753 ,  C07C69/757 ,  C07C2601/14 ,  C07C2603/74 ,  C07C2603/86 ,  C07D307/33 ,  C07D307/93 ,  Y02P20/55 ,  C07C43/16 ,  C07C43/168 ,  C07C43/178 ,  C07C43/188 ,  C07C43/215

    摘要： A process produces vinyl ether compounds and includes allowing a vinyl ester compound represented by following Formula (1): wherein R1, R2, R3 and R4 are the same or different and are each a hydrogen atom or an organic group, to react with a hydroxy compound represented by following Formula (2): R5OH  (2) wherein R5 is an organic group, in the presence of at least one transition element compound to thereby yield a vinyl ether compound represented by following Formula (3): wherein R2, R3, R4 and R5 have the same meanings as defined above. Such transition element compounds include iridium compounds and other compounds containing Group VIII elements.

    摘要翻译： 一种方法制备乙烯基醚化合物，包括使下式（1）表示的乙烯基酯化合物：其中R 1，R 2，R 3， >和R 4相同或不同，并且各自为氢原子或有机基团，与下式（2）表示的羟基化合物反应：<？在线式描述= “在线公式”end =“lead”？> 5 OH（2）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 在至少一种过渡元素化合物的存在下，有机基团是有机基团，从而得到下式（3）表示的乙烯基醚化合物：其中R 2，R R 4，R 4和R 5具有与上述相同的含义。 这种过渡元素化合物包括铱化合物和含有VIII族元素的其它化合物。

    Process for producing vinyl ether compounds
    2.
    发明授权
    Process for producing vinyl ether compounds 有权
    制备乙烯基醚化合物的方法

    公开(公告)号：US07271297B2

    公开(公告)日：2007-09-18

    申请号：US11437616

    申请日：2006-05-22

    申请人： Yasutaka Ishii ,  Tatsuya Nakano ,  Keizo Inoue

    发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Keizo Inoue

    IPC分类号： C07C43/05 ,  C07C51/00

    CPC分类号： C07D313/10 ,  C07C41/16 ,  C07C43/162 ,  C07C49/753 ,  C07C69/757 ,  C07C2601/14 ,  C07C2603/74 ,  C07C2603/86 ,  C07D307/33 ,  C07D307/93 ,  Y02P20/55 ,  C07C43/16 ,  C07C43/168 ,  C07C43/178 ,  C07C43/188 ,  C07C43/215

    摘要： A process produces vinyl ether compounds and includes allowing a vinyl ester compound represented by following Formula (1): wherein R1, R2, R3 and R4 are the same or different and are each a hydrogen atom or an organic group, to react with a hydroxy compound represented by following Formula (2): R5OH  (2) wherein R5 is an organic group, in the presence of at least one transition element compound to thereby yield a vinyl ether compound represented by following Formula (3): wherein R2, R3, R4 and R5 have the same meanings as defined above. Such transition element compounds include iridium compounds and other compounds containing Group VIII elements.

    摘要翻译： 一种方法制备乙烯基醚化合物，包括使下式（1）表示的乙烯基酯化合物：其中R 1，R 2，R 3， >和R 4相同或不同，并且各自为氢原子或有机基团，与下式（2）表示的羟基化合物反应：<β在线式描述= “在线公式”end =“lead”？> 5 OH（2）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 在至少一种过渡元素化合物的存在下，有机基团是有机基团，从而得到下式（3）表示的乙烯基醚化合物：其中R 2，R R 4，R 4和R 5具有与上述相同的含义。 这种过渡元素化合物包括铱化合物和含有VIII族元素的其它化合物。

    Process for producing vinyl ether compounds
    3.
    发明申请
    Process for producing vinyl ether compounds 有权
    制备乙烯基醚化合物的方法

    公开(公告)号：US20060205957A1

    公开(公告)日：2006-09-14

    申请号：US11437616

    申请日：2006-05-22

    申请人： Yasutaka Ishii ,  Tatsuya Nakano ,  Keizo Inoue

    发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Keizo Inoue

    IPC分类号： C07D307/77 ,  C07D307/92 ,  C07C43/18

    CPC分类号： C07D313/10 ,  C07C41/16 ,  C07C43/162 ,  C07C49/753 ,  C07C69/757 ,  C07C2601/14 ,  C07C2603/74 ,  C07C2603/86 ,  C07D307/33 ,  C07D307/93 ,  Y02P20/55 ,  C07C43/16 ,  C07C43/168 ,  C07C43/178 ,  C07C43/188 ,  C07C43/215

    摘要： A process produces vinyl ether compounds and includes allowing a vinyl ester compound represented by following Formula (1): wherein R1, R2, R3 and R4 are the same or different and are each a hydrogen atom or an organic group, to react with a hydroxy compound represented by following Formula (2): R5OH  (2) wherein R5 is an organic group, in the presence of at least one transition element compound to thereby yield a vinyl ether compound represented by following Formula (3): wherein R2, R3, R4 and R5 have the same meanings as defined above. Such transition element compounds include iridium compounds and other compounds containing Group VIII elements.

    摘要翻译： 一种方法制备乙烯基醚化合物，包括使下式（1）表示的乙烯基酯化合物：其中R 1，R 2，R 3， >和R 4相同或不同，并且各自为氢原子或有机基团，与下式（2）表示的羟基化合物反应：<β在线式描述= “在线公式”end =“lead”？> 5 OH（2）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 在至少一种过渡元素化合物的存在下，有机基团是有机基团，从而得到下式（3）表示的乙烯基醚化合物：其中R 2，R R 4，R 4和R 5具有与上述相同的含义。 这种过渡元素化合物包括铱化合物和含有VIII族元素的其它化合物。

    Polymerizable alicyclic esters and process producing the same
    4.
    发明授权
    Polymerizable alicyclic esters and process producing the same 失效
    可聚合脂环酯和其生产方法

    公开(公告)号：US06218569B1

    公开(公告)日：2001-04-17

    申请号：US09600717

    申请日：2000-07-20

    申请人： Yasutaka Ishii ,  Keizo Inoue

    发明人： Yasutaka Ishii ,  Keizo Inoue

    IPC分类号： C07C6952

    CPC分类号： C07C69/54 ,  C07C2602/28 ,  C07C2603/24 ,  C07C2603/68 ,  Y02P20/55

    摘要： The invented polymerizable alicyclic esters are shown by the following formula (1) or (2): wherein each of ring A, ring B, ring C, ring D, and ring E is a non-aromatic carbon ring, R is a polymerizable unsaturated group, and each of Ra1, Rb1, and Rc1 is, identical to or different from one another, a hydrogen atom, a hydroxyl group which may be protected by a protective group, or an RCO2 group, where R has the same meaning as defined above. Each of the ring A, ring B, ring C, ring D, and ring E is, for example, a cyclopentane ring, a cyclohexane ring, or a bridged ring. R includes, for example, a vinyl group, an isopropenyl group, or an aryl group.

    摘要翻译： 本发明的可聚合脂环族酯由下式（1）或（2）表示：其中环A，环B，环C，环D和环E均为非芳族碳环，R为可聚合不饱和 并且Ra1，Rb1和Rc1各自彼此相同或不同，为氢原子，可被保护基保护的羟基或RCO 2基团，其中R具有与所定义相同的含义 以上。 环A，环B，环C，环D和环E各自为例如环戊烷环，环己烷环或桥环。 R包括例如乙烯基，异丙烯基或芳基。

    Process for producing hydroxylactones
    5.
    发明授权
    Process for producing hydroxylactones 失效
    制备羟基内酯的方法

    公开(公告)号：US07038064B2

    公开(公告)日：2006-05-02

    申请号：US10332049

    申请日：2001-07-18

    申请人： Yasutaka Ishii ,  Tatsuya Nakano ,  Keizo Inoue

    发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Keizo Inoue

    IPC分类号： C07D307/32 ,  C07D309/30

    CPC分类号： C07D307/935 ,  C07D307/32 ,  C07D309/30

    摘要： A process of the present invention produces a hydroxylactone by subjecting an unsaturated carboxylic acid having a double bond not conjugated to a carboxyl group or an ester thereof to (i) a reaction with hydrogen peroxide in the presence of a metallic compound containing a metallic element selected from W, Mo, V and Mn or (ii) a reaction with a peroxide containing the metallic element to thereby yield a corresponding hydroxylactone having a hydroxyl group combined with one of carbon atoms constituting the double bond and being cyclized at the other carbon atom position. The metallic compound may be one selected from oxides, oxoacids and salts thereof. The unsaturated carboxylic acid includes, for example, β,γ-unsaturated carboxylic acids, γ,δ-unsaturated carboxylic acids, and δ,ε-unsaturated carboxylic acids. The process can produce hydroxylactones in high yields at low cost.

    摘要翻译： 本发明的方法通过使具有未与羧基键合的双键的不饱和羧酸或其酯与（ⅰ）在含有选自金属元素的金属化合物存在下与过氧化氢反应来制备羟基内酯 由W，Mo，V和Mn反应，或者（ii）与含有金属元素的过氧化物反应，得到具有与构成双键的碳原子结合的羟基的相应羟基内酯，并在另一个碳原子位置环化 。 金属化合物可以是选自氧化物，含氧酸及其盐中的一种。 不饱和羧酸包括例如β，γ-不饱和羧酸，γ，δ-不饱和羧酸和δ-不饱和羧酸。 该方法可以以低成本高产率生产羟基内酯。

    Polycyclic ester containing cyano group and lactone skeleton
    6.
    发明授权
    Polycyclic ester containing cyano group and lactone skeleton 有权

    公开(公告)号：US07834114B2

    公开(公告)日：2010-11-16

    申请号：US12628874

    申请日：2009-12-01

    申请人： Keizo Inoue ,  Takahiro Iwahama ,  Masamichi Nishimura ,  Kiyoharu Tsutsumi

    发明人： Keizo Inoue ,  Takahiro Iwahama ,  Masamichi Nishimura ,  Kiyoharu Tsutsumi

    IPC分类号： C08F24/00 ,  C08F34/02

    CPC分类号： C07D307/93 ,  C08F220/36

    摘要： Disclosed is a polycyclic ester containing a cyano group and a lactone skeleton, represented by following Formula (1): wherein Ra represents, for example, a hydrogen atom or an alkyl group having one to six carbon atoms which may have a halogen atom; R1s each represent, for example, a halogen atom or an alkyl or haloalkyl group having one to six carbon atoms; “m” is the number of R1s; “n” is the number of cyano groups; and CH2═C(Ra)COO— group may have either of an endo conformation and an exo conformation. Accordingly, there is provided a novel polycyclic ester containing a cyano group and a lactone skeleton which is useful typically as a monomeric component for highly functional polymers. A polymer, for example, derived from this compound is highly soluble in an organic solvent while remaining stable typically to chemicals and exhibits improved hydrolyzability and/or improved solubility in water after hydrolysis.

    Phospholipid derivatives
    9.
    发明授权
    Phospholipid derivatives 失效
    磷脂衍生物

    公开(公告)号：US4778912A

    公开(公告)日：1988-10-18

    申请号：US933210

    申请日：1986-11-21

    申请人： Keizo Inoue ,  Hiroaki Normura ,  Tetsuya Okutani

    发明人： Keizo Inoue ,  Hiroaki Normura ,  Tetsuya Okutani

    IPC分类号： A61K31/685 ,  A61P35/00 ,  C07F9/10 ,  C07F9/58

    CPC分类号： C07F9/581 ,  C07F9/10 ,  Y02P20/55

    摘要： Phospholipid derivatives of the formula: ##STR1## wherein R.sup.1 is a higher alkyl, acylmethyl or alkylcarbamoyl group which may be substituted by cycloalkyl; R.sup.2 is a lower alkyl which may be substituted by carboxy, formyl or lower acyl, a carbamoyl or thiocarbamoyl group which is substituted by lower alkyl, or an acetoacetyl group; R.sup.3, R.sup.4 and R.sup.5 are independently hydrogen or lower alkyl, or ##STR2## represents a cyclic ammonio group; and n represents an integer of 8 to 14, and salts thereof have antitumor activity.

    摘要翻译： 下式的磷脂衍生物：其中R1是可被环烷基取代的高级烷基，酰基甲基或烷基氨基甲酰基; R2是可被羧基，甲酰基或低级酰基取代的低级烷基，被低级烷基或乙酰乙酰基取代的氨基甲酰基或硫代氨基甲酰基; R3，R4和R5独立地为氢或低级烷基，或者“IMAGE”表示环氨基; n表示8〜14的整数，其盐具有抗肿瘤活性。

    Polycyclic ester containing cyano group and lactone skeleton
    10.
    发明授权
    Polycyclic ester containing cyano group and lactone skeleton 有权
    含有氰基和内酯骨架的多环酯

    公开(公告)号：US08236971B2

    公开(公告)日：2012-08-07

    申请号：US12900776

    申请日：2010-10-08

    申请人： Keizo Inoue ,  Takahiro Iwahama ,  Masamichi Nishimura ,  Kiyoharu Tsutsumi

    发明人： Keizo Inoue ,  Takahiro Iwahama ,  Masamichi Nishimura ,  Kiyoharu Tsutsumi

    IPC分类号： C07D307/93 ,  C08G61/04

    CPC分类号： C07D307/93 ,  C08F220/36

    摘要： A polycyclic ester containing a cyano group and a lactone skeleton, represented by following Formula (1): wherein Ra represents, for example, a hydrogen atom or an alkyl group having one to six carbon atoms which may have a halogen atom; R1s each represent, for example, a halogen atom or an alkyl or haloalkyl group having one to six carbon atoms; “m” is the number of R1s; “n” is the number of cyano groups; and CH2═C(Ra)COO— group may have either of an endo conformation and an exo conformation. Accordingly, there is provided a novel polycyclic ester containing a cyano group and a lactone skeleton which is useful typically as a monomeric component for highly functional polymers. A polymer, for example, derived from this compound is highly soluble in an organic solvent while remaining stable typically to chemicals and exhibits improved hydrolyzability and/or improved solubility in water after hydrolysis.

    摘要翻译： 由下式（1）表示的含有氰基和内酯骨架的多环酯：其中，Ra表示例如可以具有卤素原子的氢原子或碳原子数1〜6的烷基， R 1各自表示例如卤素原子或具有1〜6个碳原子的烷基或卤代烷基; “m”是R1的数量; “n”是氰基的数目; 和CH 2 = C（Ra）COO-基团可以具有内部构象和外部构象。 因此，提供了含有氰基和内酯骨架的新型多环酯，其通常用作高官能聚合物的单体组分。 例如衍生自该化合物的聚合物高度可溶于有机溶剂，同时通常保持稳定化学品，并且在水解后表现出改善的水解性和/或改善的在水中的溶解性。