摘要:
Disclosed is a shell-and-tube reactor that may be used for fixed-bed catalytic partial oxidation, the reactor being characterized by including at least one reaction zone of a first-step reaction zone for mainly producing unsaturated aldehydes and a second-step reaction zone for mainly producing unsaturated acids, wherein at least one reaction zone of the above reaction zones comprises two or more catalytic layers; each of the catalytic layers is packed with a formed product of catalyst that is different in pore density and/or pore size in a catalytically active component; and the pore density and/or pore size is controlled in such a manner that specific surface area of the catalytically active component increases from the inlet of the reactor to the outlet of the reactor. A method for producing unsaturated aldehydes and/or unsaturated fatty acids from olefins using the same reactor is also disclosed. According to the present invention, it is possible to control the temperature efficiently at a hot spot, thereby permitting stable use of a catalyst, and to produce unsaturated aldehydes and/or unsaturated fatty acids with high yield.
摘要:
Disclosed is a shell-and-tube reactor that may be used in a method for producing unsaturated aldehydes and/or unsaturated acids from olefins by means of fixed-bed catalytic partial oxidation. The reactor includes at least one reaction zone of a first-step reaction zone for producing unsaturated aldehydes as a main product and a second-step reaction zone for producing unsaturated acids as a main product, and at least one reaction zone of the reaction zones comprises two or more catalytic layers, each of the catalytic layers being packed with a formed product of catalyst as secondary particles, wherein the secondary particles in each catalytic layer are formed of primary particles of a catalytically active component having a different particle size, and the particle size of primary particles of the catalytically active component is controlled so that it decreases from an inlet of the reactor to an outlet of the reactor. A method for producing unsaturated aldehydes and/or unsaturated fatty acids from olefins using the same reactor is also disclosed. According to the present invention, it is possible to control the temperature efficiently at a hot spot, thereby permitting a catalyst to be used stably, and to produce unsaturated aldehydes and/or unsaturated fatty acids with high yield.
摘要:
Disclosed is a method for producing unsaturated aldehydes or unsaturated fatty acids from at least one compound selected from the group consisting of propylene, propane, (meth)acrolein, isobutylene, t-butyl alcohol, methyl-t-butyl ether and o-xylene by means of fixed-bed catalytic partial oxidation in a shell-and-tube reactor, characterized in that the reactor includes a reaction zone for producing unsaturated aldehydes as a main product, the reaction zone having an inactive material layer inserted into a position where a hot spot is to be generated in a reaction tube. A fixed-bed shell-and-tube reactor for use in the above method is also disclosed. According to the present invention, at least one layer of inactive material is packed at the point of a hot spot to control the hot spot temperature efficiently, thereby increasing the lifetime of a catalyst and producing unsaturated aldehydes and unsaturated fatty acids with high yield.
摘要:
Disclosed are a Mo—Bi—Nb—Te based composite metal oxide; and a process for producing (meth)acrylic acid from at least one reaction material selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, wherein the Mo—Bi—Nb—Te based composite metal oxide is used as a catalyst. Also, disclosed is a process for producing (meth)acrylic acid comprising a first step of producing (meth)acrolein as a main product from at least one reaction material selected from the group consisting of propylene, propane, isobutylene, t-butyl alcohol and methyl-t-butyl ether, and a second step of producing (meth)acrylic acid from the (meth)acrolein, wherein yield of (meth)acrylic acid in the product of the first step is 20 mole % or higher.
摘要:
Disclosed is a method for producing unsaturated fatty acids from unsaturated aldehydes by means of fixed-bed catalytic partial oxidation in a shell-and-tube reactor, characterized in that the reactor includes a reaction zone for producing unsaturated fatty acids, the reaction zone having an inactive material layer inserted into a position where a hot spot is to be generated in a reaction tube. A fixed-bed shell-and-tube reactor for use in the above method is also disclosed. According to the present invention, at least one layer of inactive material is packed at the point of a hot spot to control the hot spot temperature efficiently, thereby increasing the lifetime of a catalyst and producing unsaturated fatty acids with high yield.
摘要:
The present invention relates to a method for preparing a catalyst which is used in a process of producing acrolein and acrylic acid by the reaction of oxygen-containing gas and propylene. According to the present invention, a sublimable material, such as urea (NH2CONH2), melamine (C3H6N6), ammonium oxalate (C2H8N2O4), methyl oxalate (C4H6O4) or naphthalene (C10H8), is added as a catalyst additive in the preparation of the catalyst. Using the catalyst prepared by the present invention, acrolein and acrylic can be produced at high yield.
摘要翻译:本发明涉及一种制备催化剂的方法,该催化剂用于通过含氧气体和丙烯的反应生产丙烯醛和丙烯酸的方法。 根据本发明,可升华的材料,例如脲(NH 2 CONH 2 H 2),三聚氰胺(C 3 H 6) 草酸铵(C 2 H 2 N 2 N 2 O 4) 草酸甲酯(C 4 H 6 O 4 O 4)或萘(C 10 H 2 O) 作为催化剂添加剂加入催化剂的制备中。 使用本发明制备的催化剂可以高产率生产丙烯醛和丙烯酸。
摘要:
The present invention provides norbornene-based copolymers for which one monomer is at least selected from a group consisting of norbornene and dicyclopentadiene, and the other from norbornene-based comonomers of Formula 1 shown below: In Formula 1, R1, R2 and a are defined in this specification. The present invention provides insulating elements for multi-chip packages and antireflection films for the exposure process of semiconductor fabrication using said norbornene-based copolymers. Norbornene-based copolymers according to the present invention have low dielectric constant as well as high thermal stability and excellent solubility to various organic solvents.
摘要:
A manufacturing method of a wire grid polarizer includes the steps of: preparing a mold; sequentially forming a metal foil and a polymer on a substrate; molding a polymer by using the mold; etching the metal foil by using the molded polymer, and forming a wire grid pattern; and removing the polymer.
摘要:
Disclosed is a method for fabricating Surface Acoustic Wave filter packages using a package sheet having an outline pattern and anti-bur holes and a package sheet used therein. In the package sheet for a Surface Acoustic Wave filter package, an outline pattern is formed along outer peripheries of predetermined areas to be mounted with a plurality of SAW filter chips. The outline pattern is contacted with a metal shield layer formed on the SAW filter chips and a predetermined region of the package sheet. Circular anti-bur holes cover the corners of the areas to be mounted with the SAW filter chips and are intersected by cutting lines functioning as reference lines for cutting the sheet into a plurality of SAW filter packages.
摘要:
A serial flash memory is provided with multiple configurable pins, at least one of which is selectively configurable for use in either single-bit serial data transfers or multiple-bit serial data transfers. In single-bit serial mode, data transfer is bit-by-bit through a pin. In multiple-bit serial mode, a number of sequential bits are transferred at a time through respective pins. The serial flash memory may have 16 or fewer pins, and even 8 or fewer pins, so that low pin count packaging such as the 8-pin or 16-pin SOIC package and the 8-contact MLP/QFN/SON package may be used. The availability of the single-bit serial type protocol enables compatibility with a number of existing systems, while the availability of the multiple-bit serial type protocol enables the serial flash memory to provide data transfer rates, in systems that can support them, that are significantly faster than available with standard serial flash memories.