Oxidation catalyst
    1.
    发明授权
    Oxidation catalyst 失效
    氧化催化剂

    公开(公告)号:US06391821B1

    公开(公告)日:2002-05-21

    申请号:US09334379

    申请日:1999-06-16

    IPC分类号: B01J2300

    摘要: An oxidation catalyst according to the present invention is prepared, for example, by heat processing a gold compound at 150° C. to 80° C., yielding ultrafine gold particles, which are then mixed with a palladium compound and a compound containing at least one element selected from the group consisting of alkaline metals and the elements of Groups IIA, IIIA, VIA, IIB, VB, and VIII of the Periodic Table. By an oxidation reaction between a benzyl compound such as p-xylene and a carboxylic acid such as acetic acid in the presence of oxygen and the oxidation catalyst prepared as above, a benzyl ester such as p-methylbenzyl acetate or p-xylylene diacetate can be produced. Consequently, it is possible to provide an oxidation catalyst suitable for use in industrially producing the foregoing benzyl esters, a method of preparing the foregoing oxidation catalyst, and a method of producing the foregoing benzyl esters efficiently and at low cost.

    摘要翻译: 根据本发明的氧化催化剂例如通过在150℃至80℃下热处理金化合物而制备,产生超细金颗粒,然后将其与钯化合物和至少含有化合物 选自碱金属和元素周期表IIA,IIIA,VIA,IIB,VB和VIII族元素的一种元素。 通过苄基化合物如对二甲苯和羧酸如乙酸在氧气存在下的氧化反应和如上制备的氧化催化剂,可以将苄基酯如对甲基苄基乙酸酯或对二甲苯基二乙酸酯 生产。 因此,可以提供适用于工业生产上述苄基酯的氧化催化剂,制备上述氧化催化剂的方法,以及以低成本有效地生产上述苄基酯的方法。

    Producing method of (hydroxyalkyl) alicyclic carboxylic acids and intermediates for producing the same and producing method of such intermediates
    2.
    发明授权
    Producing method of (hydroxyalkyl) alicyclic carboxylic acids and intermediates for producing the same and producing method of such intermediates 失效
    (羟基烷基)脂环族羧酸的制造方法及其制造方法和中间体的制造方法

    公开(公告)号:US06444843B1

    公开(公告)日:2002-09-03

    申请号:US09541609

    申请日:2000-04-03

    IPC分类号: C07C6700

    摘要: (Acyloxyalkyl)aromatic carboxylic acids are produced by partial oxidation of alkyl substituted aromatic compounds which are represented by the following General Formula (1) CHR1R2—Ar—(R3)n  (1) (where Ar is an aromatic ring of two or greater valency, R1 is a hydrogen atom or alkyl group having a carbon number of 1 to 3, R2 is a hydrogen atom, alkyl group having a carbon number of 1 to 3, or —OCOR5 group, R3 is an alkyl group having a carbon number of 1 to 4, —COOH group, —CHO group, —CH2R4 group, or —COOR group, n is an integer of 1 to 5, R4 is a halogen atom, —OH group, or —OCOR5 group, and R5 is an alkyl group having a carbon number of 1 to 4), and carboxylic acids in the presence of oxygen using a catalyst including an element which belongs to Group VIII of the periodic table. (Hydroxyalkyl)alicyclic carboxylic acids are produced by carrying out hydrogenation and hydrolysis using the (acyloxyalkyl)carboxylic acids as a starting material.

    摘要翻译: (Acyloxalkyl)芳族羧酸通过部分氧化由以下通式(1)表示的烷基取代的芳族化合物(其中Ar是两价或更多价的芳环,R 1是氢原子或具有 碳原子数为1〜3,R2为氢原子,碳数为1〜3的烷基或-OCOR5基,R3为碳数为1〜4的烷基,-COOH基,-CHO基 ,-CH2R4基或-COOR基,n为1〜5的整数,R4为卤素原子,-OH基或-OCOR5基,R5为碳数为1〜4的烷基) 和羧酸在氧的存在下使用包括属于周期表第VIII族的元素的催化剂。 (羟基烷基)脂环族羧酸通过使用(酰氧基烷基)羧酸作为原料进行氢化和水解来制备。

    Producing method of alcohols such as cyclohexanedimethanol
    3.
    发明授权
    Producing method of alcohols such as cyclohexanedimethanol 失效
    醇类如环己烷二甲醇的生产方法

    公开(公告)号:US06600080B1

    公开(公告)日:2003-07-29

    申请号:US09676937

    申请日:2000-10-02

    IPC分类号: C07C3113

    摘要: In a producing method of alcohols such as cyclohexanedimethanol, a benzyl ester is obtained, for example, by the reaction between a benzyl compound and carboxylic acid in the presence of oxygen and a catalyst including palladium, gold ultra fine particles, and at least one kind of element selected from the group consisting of Group IIA, IIIA, VIA, IIB, VB, and VIII of the periodic table, and alkali metal. The alcohols are produced by hydrogenating a benzene ring of the benzyl ester and then hydrolyzing the resultant esters. Alternatively, the benzyl ester is hydrolyzed to produce benzyl alcohols, and a benzene ring of the benzyl alcohols is hydrogenated to produce the alcohols.

    摘要翻译: 在诸如环己烷二甲醇的醇的制备方法中,例如苄基化合物和羧酸在氧气和催化剂(包括钯,金超细颗粒)和至少一种 的选自元素周期表的IIA,IIIA,VIA,IIB,VB和VIII族的元素和碱金属。 醇通过将苯甲酯的苯环氢化,然后水解所得的酯来制备。 或者,将苄基酯水解生成苄醇,将苯甲醇的苯环氢化生成醇。

    Soft magnetic thin film
    4.
    发明授权
    Soft magnetic thin film 失效
    软磁薄膜

    公开(公告)号:US5302469A

    公开(公告)日:1994-04-12

    申请号:US704093

    申请日:1991-05-22

    摘要: A soft magnetic thin film according to the invention has an atomic ratio composition represented by the formula:Fe.sub.(100-a-b) M.sub.a O.sub.bwherein M is at least one element selected from Group 3A elements and Group 4A elements, 2.ltoreq.a.ltoreq.15 and 4.ltoreq.b.ltoreq.35. It has a high saturation magnetic flux density Bs, high magnetic permeability .mu., low coercive force Hc, improved frequency response, high electric resistivity .rho., and good corrosion resistance.

    摘要翻译: 根据本发明的软磁薄膜具有由下式表示的原子比组成:Fe(100-ab)MaOb其中M是选自3A族元素和4A族元素中的至少一种元素,2 <= a <= 15 和4 <= b <= 35。 具有高的饱和磁通密度Bs,高导磁率(my),低矫顽力Hc,改善的频率响应,高电阻率(rho)和良好的耐腐蚀性。

    Liquid-phase diffusion bonding alloy foils for joining heat-resistant
metals in oxidizing atmospheres
    5.
    发明授权
    Liquid-phase diffusion bonding alloy foils for joining heat-resistant metals in oxidizing atmospheres 失效
    用于在氧化性气氛中接合耐热金属的液相扩散接合合金箔

    公开(公告)号:US5683822A

    公开(公告)日:1997-11-04

    申请号:US716183

    申请日:1996-09-27

    摘要: Alloy foils for liquid-phase diffusion bonding of heat-resisting metals in an oxidizing atmosphere comprise 6.0 to 15.0 percent silicon, 0.1 to 2.0 percent manganese, 0.50 to 30.0 percent chromium, 0.10 to 5.0 percent molybdenum, 0.50 to 10.0 percent vanadium, 0.02 to 1.0 percent niobium, 0.10 to 5.0 percent tungsten, 0.05 to 2.0 percent nitrogen, 0.50 to 20.0 percent phosphorus, plus 0.005 to 1.0 percent carbon, and/or either or both of 0.01 to 5.0 percent titanium and 0.01 to 5.0 percent zirconium, all by mass, with the balance comprising nickel and impurities, and have a thickness of 3.0 to 300 .mu.m. Alloy foils for liquid-phase diffusion bonding of heat-resisting metals in an oxidizing atmosphere are also available with substantially vitreous structures.

    摘要翻译: PCT No.PCT / JP95 / 00673 Sec。 371日期1996年9月27日第 102(e)日期1996年9月27日PCT提交1995年4月6日PCT公布。 公开号WO95 / 27586 日期:1995年10月19日在氧化气氛中耐热金属的液相扩散接合用合金箔包含6.0〜15.0%的硅,0.1〜2.0%的锰,0.50〜30.0%的铬,0.10〜5.0%的钼,0.50〜10.0 的钒,0.02〜1.0%的铌,0.10〜5.0%的钨,0.05〜2.0%的氮,0.50〜20.0%的磷,0.005〜1.0%的碳,和/或0.01〜5.0%的钛和0.01〜5.0 百分比的锆,质量均匀,余量包括镍和杂质,并且具有3.0至300μm的厚度。 用于在氧化气氛中耐热金属的液相扩散接合的合金箔也可用于基本上玻璃质结构。

    Polymer production apparatus and polymer production method
    6.
    发明授权
    Polymer production apparatus and polymer production method 有权
    聚合物生产设备和聚合物生产方法

    公开(公告)号:US09447228B2

    公开(公告)日:2016-09-20

    申请号:US14542804

    申请日:2014-11-17

    摘要: A polymer production apparatus, including: supplying unit containing first supplying unit to supply raw materials containing monomer, and second supplying unit to supply compressive fluid; contacting unit to bring the monomer and the compressive fluid into contact together; and outlet configured to discharge reaction product of the monomer, wherein reaction unit is provided between the contacting unit and the outlet, where the reaction unit is to pass the monomer from the contacting unit side to the outlet side, while allowing the monomer to carry out a polymerization reaction in the presence of the compressive fluid, and wherein the reaction unit contains circulation unit containing first pipe and second pipe, where a fluid is passed through the first pipe from the contacting unit side to the outlet side, and the second pipe is to return the fluid from return port provided upstream extrusion unit to inlet provided upstream the return port.

    摘要翻译: 一种聚合物制造装置,包括:含有第一供给单元的供给单元,供给含有单体的原料,第二供给单元供给压缩流体; 接触单元使单体和压缩流体接触在一起; 和排出口,用于排出单体的反应产物,其中反应单元设置在接触单元和出口之间,其中反应单元将单体从接触单元侧通过到出口侧,同时允许单体进行 在压缩流体存在下的聚合反应,其中反应单元包含含有第一管和第二管的循环单元,其中流体从接触单元侧通过第一管至出口侧,第二管为 将流体从提供的上游挤出单元的返回口返回到在返回端口上游提供的入口。

    Process for production of alkyl ether of phenol and catalyst used therein
    7.
    发明授权
    Process for production of alkyl ether of phenol and catalyst used therein 失效
    苯酚烷基醚的制备方法及其中使用的催化剂

    公开(公告)号:US5817886A

    公开(公告)日:1998-10-06

    申请号:US772908

    申请日:1996-12-24

    IPC分类号: B01J23/04 C07C41/09

    CPC分类号: B01J23/04 C07C41/09

    摘要: The present invention provides a process for producing an alkyl ether of a phenol from a phenol and an alcohol at a selectivity and a yield higher than in conventional processes, stably over a long period of time. The process is characterized by alkyl-etherifying a phenol with an alcohol in the presence of an oxide catalyst comprising an alkali metal as a constituent element.

    摘要翻译: 本发明提供一种苯酚和醇的苯酚烷基醚的制备方法,其选择性和产率高于常规方法,长期稳定。 该方法的特征在于在包含碱金属作为构成元素的氧化物催化剂的存在下,用醇烷基醚化苯酚。

    Liquid-phase diffusion bonding alloy foils for joining heat-resistant
metals in oxidizing atmospheres
    8.
    发明授权
    Liquid-phase diffusion bonding alloy foils for joining heat-resistant metals in oxidizing atmospheres 失效
    用于在氧化性气氛中接合耐热金属的液相扩散接合合金箔

    公开(公告)号:US5759300A

    公开(公告)日:1998-06-02

    申请号:US716314

    申请日:1996-09-27

    摘要: Alloy foils for liquid-phase diffusion bonding of heat-resisting metals in an oxidizing atmosphere comprise 6.0 to 15.0 percent silicon, 0.1 to 2.0 percent manganese, 0.50 to 30.0 percent chromium, 0.10 to 5.0 percent molybdenum, 0.50 to 10.0 percent vanadium, 0.02 to 1.0 percent niobium, 0.10 to 5.0 percent tungsten, 0.01 to 0.5 percent nitrogen, 0.10 to 5.0 percent boron, plus 0.005 to 1.0 percent carbon, and/or either or both of 0.01 to 5.0 percent titanium and 0.01 to 5.0 percent zirconium, all by mass, with the balance comprising nickel and impurities, and have a thickness of 3.0 to 300 .mu.m. Alloy foils for liquid-phase diffusion bonding of heat-resisting metals in an oxidizing atmosphere are also available with substantially vitreous structures.

    摘要翻译: PCT No.PCT / JP95 / 00594 Sec。 371日期1996年9月27日第 102(e)1996年9月27日PCT 1995年3月29日PCT PCT。 出版物WO95 / 26419 日期:1995年10月5日耐热金属在氧化性气氛中的液相扩散接合用合金箔包含6.0〜15.0%的硅,0.1〜2.0%的锰,0.50〜30.0%的铬,0.10〜5.0%的钼,0.50〜10.0 0.01-0.0%的铌,0.10〜5.0%的钨,0.01〜0.5%的氮,0.10〜5.0%的硼,0.005〜1.0%的碳,和/或0.01〜5.0%的钛和0.01〜5.0 百分比的锆,质量均匀,余量包括镍和杂质,并且具有3.0至300μm的厚度。 用于在氧化气氛中耐热金属的液相扩散接合的合金箔也可用于基本上玻璃质结构。