公开(公告)号：US09922745B2

公开(公告)日：2018-03-20

申请号：US14650379

申请日：2014-02-25

申请人： Toray Industries, Inc.

发明人： Naoyo Okamoto ,  Kazunori Hondo ,  Hidekazu Nishino ,  Kenichi Sato

IPC分类号： H01B1/04 ,  C01B31/02 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C01B32/174

CPC分类号： H01B1/04 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C01B32/174 ,  C01B2202/04 ,  C01B2202/22 ,  C01B2202/30 ,  C01B2202/36 ,  Y10S977/742 ,  Y10S977/842 ,  Y10S977/932

摘要： An aggregate of carbon nanotubes has an acid adsorption amount equal to or greater than 0.6 mass % and equal to or less than 12 mass %, which is obtained by subjecting a starting material composition containing carbon nanotubes to a two-stage wet oxidation treatment. A method of producing an aggregate of carbon nanotubes includes a primary oxidation treatment step, wherein a starting material composition containing carbon nanotubes is subjected to a wet oxidation treatment to give a primary treated aggregate of carbon nanotubes having a ratio (G/D ratio) of the height of G band to that of D band in Raman spectroscopic analysis at 532 nm wavelength equal to or greater than 30; and a secondary oxidation treatment step of performing a wet oxidation treatment under an oxidizing condition stronger than that of the primary oxidation treatment step.

公开(公告)号：US09266735B2

公开(公告)日：2016-02-23

申请号：US13507924

申请日：2012-08-07

申请人： Mark C. Hersam ,  Jung-Woo T. Seo ,  Alexander Lee Antaris ,  Alexander A. Green

发明人： Mark C. Hersam ,  Jung-Woo T. Seo ,  Alexander Lee Antaris ,  Alexander A. Green

IPC分类号： C01B31/02 ,  C08L71/02 ,  B01D21/26 ,  B82Y30/00 ,  B82Y40/00

CPC分类号： C01B31/0266 ,  B01D21/26 ,  B01D21/262 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/172 ,  C01B2202/02 ,  C01B2202/22 ,  C01B2202/30 ,  C08G2650/58 ,  C08L71/02

摘要： The separation of single-walled carbon nanotubes (SWCNTs), by electronic type, using centrifugation of compositions of SWCNTs and surface active block copolymers in self-forming density gradient media.

公开(公告)号：US20130095314A1

公开(公告)日：2013-04-18

申请号：US13521494

申请日：2011-01-11

申请人： Angel A. Marti-Arbona ,  Avishek Saha ,  Matteo Pasquali

发明人： Angel A. Marti-Arbona ,  Avishek Saha ,  Matteo Pasquali

IPC分类号： B05D3/10

CPC分类号： B05D3/107 ,  B05D1/18 ,  B05D5/00 ,  B05D7/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/00 ,  C01B32/166 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/04 ,  C01B2202/06 ,  C01B2202/30 ,  C01B2202/34 ,  C01B2202/36 ,  Y10S977/742 ,  Y10S977/743 ,  Y10S977/744 ,  Y10S977/745 ,  Y10S977/746 ,  Y10S977/748 ,  Y10S977/749 ,  Y10S977/75 ,  Y10S977/752 ,  Y10S977/842 ,  Y10S977/953 ,  Y10T428/249978 ,  Y10T428/25

摘要： In some embodiments, the present invention provides methods of immobilizing carbon nanotubes on a surface, wherein the method comprises: (1) mixing carbon nanotubes with a superacid to form a carbon nanotube solution; and (2) exposing the carbon nanotube solution to the surface. The exposing results in the immobilization of the carbon nanotubes on the surface. In some embodiments, the method occurs without the utilization of carbon nanotube wrapping molecules. Other embodiments of the present invention pertain to systems that comprise immobilized carbon nanotubes on a surface, as developed by the aforementioned methods.

摘要翻译： 在一些实施方案中，本发明提供了将碳纳米管固定在表面上的方法，其中所述方法包括：（1）将碳纳米管与超强酸混合以形成碳纳米管溶液; 和（2）将碳纳米管溶液暴露于表面。 曝光导致碳纳米管固定在表面上。 在一些实施方案中，该方法在不利用碳纳米管包裹分子的情况下发生。 本发明的其它实施方案涉及通过上述方法开发的在表面上包含固定碳纳米管的体系。

公开(公告)号：US08287836B2

公开(公告)日：2012-10-16

申请号：US11841952

申请日：2007-08-20

申请人： Xinjie Zhang ,  Jun Ma ,  Howard Tennent ,  Robert Hoch

发明人： Xinjie Zhang ,  Jun Ma ,  Howard Tennent ,  Robert Hoch

IPC分类号： D01F9/12 ,  B82B3/00

CPC分类号： B82Y40/00 ,  B01J23/881 ,  B01J23/882 ,  B82Y30/00 ,  C01B32/162 ,  C01B2202/02 ,  C01B2202/26 ,  C01B2202/30 ,  C01B2202/34 ,  Y10S977/843

摘要： Methods of preparing single walled carbon nanotubes are provided. Carbon containing gas is contacted with a supported metal catalyst under reaction conditions to yield at least 90% single walled carbon nanotubes and at least 1 gram single walled carbon nanotubes/gram metal catalyst. The support material may be calcined at temperatures between 150 and 600° C., and may have at least one oxidized planar surface. Reaction conditions include less than 10 atmospheres pressure and less than 800° C.

摘要翻译： 提供制备单壁碳纳米管的方法。 在反应条件下，将含碳气体与负载金属催化剂接触，得到至少90％的单壁碳纳米管和至少1克单壁碳纳米管/克金属催化剂。 支撑材料可以在150℃和600℃之间的温度下煅烧，并且可以具有至少一个氧化的平面表面。 反应条件包括小于10大气压和小于800℃

公开(公告)号：US08114518B2

公开(公告)日：2012-02-14

申请号：US12945073

申请日：2010-11-12

申请人： Kenji Hata ,  Sumio Iijima ,  Motoo Yumura ,  Don N. Futaba

发明人： Kenji Hata ,  Sumio Iijima ,  Motoo Yumura ,  Don N. Futaba

IPC分类号： B32B9/00 ,  D01F9/12

CPC分类号： B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/17 ,  C01B32/178 ,  C01B2202/02 ,  C01B2202/08 ,  C01B2202/30 ,  C01B2202/34 ,  Y02E60/324 ,  Y10S977/742 ,  Y10S977/75 ,  Y10T428/2918 ,  Y10T428/30

摘要： This invention provides an aligned single-layer carbon nanotube bulk structure, which comprises an assembly of a plurality of aligned single-layer carbon nanotube and has a height of not less than 10 μm, and an aligned single-layer carbon nanotube bulk structure which comprises an assembly of a plurality of aligned single-layer carbon nanotubes and has been patterned in a predetermined form. This structure is produced by chemical vapor deposition (CVD) of carbon nanotubes in the presence of a metal catalyst in a reaction atmosphere with an oxidizing agent, preferably water, added thereto. An aligned single-layer carbon nanotube bulk structure, which has realized high purify and significantly large scaled length or height, its production process and apparatus, and its applied products are provided.

公开(公告)号：US20110127472A1

公开(公告)日：2011-06-02

申请号：US12449646

申请日：2008-02-19

申请人： Kenichi Sato ,  Masahito Yoshikawa ,  Shuko Ikeuchi

发明人： Kenichi Sato ,  Masahito Yoshikawa ,  Shuko Ikeuchi

IPC分类号： H01B1/04 ,  D01F9/12 ,  H01B1/24 ,  B82Y30/00 ,  B82Y40/00

CPC分类号： C09D5/24 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B32/17 ,  C01B32/174 ,  C01B2202/02 ,  C01B2202/04 ,  C01B2202/06 ,  C01B2202/20 ,  C01B2202/28 ,  C01B2202/30 ,  C01P2002/82 ,  C01P2004/04 ,  C01P2004/13 ,  C01P2004/133 ,  C08K3/04 ,  C09C1/44 ,  C09D7/70 ,  H01B1/24

摘要： Provided is an aggregate of carbon nanotubes wherein a mixture of 10 mg of aggregate of carbon nanotubes, 30 mg of sodium polystyrene sulfonate and 10 mL of water is subjected to ultrasonic homogenizer treatment, subsequently subjected to centrifugal treatment at 20000 G, then 9 mL of supernatant is sampled, and the content of aggregate of carbon nanotubes in the supernatant is 0.6 mg/mL or more. The aggregate of carbon nanotubes of the present invention can provide a dispersion of an aggregate of carbon nanotubes having a high concentration through very good dispersibility.

摘要翻译： 提供了碳纳米管的集合体，其中将10mg碳纳米管聚集体，30mg聚苯乙烯磺酸钠和10mL水的混合物进行超声均化处理，随后在20000G下离心处理，然后加入9mL 取上清液，上清液中碳纳米管的聚集体含量为0.6mg / mL以上。 本发明的碳纳米管集合体可通过非常好的分散性提供具有高浓度的碳纳米管集合体的分散体。

公开(公告)号：US20110000198A1

公开(公告)日：2011-01-06

申请号：US12496808

申请日：2009-07-02

申请人： Yousef Haik ,  Saud Aldajah ,  Emad Elnajjar

发明人： Yousef Haik ,  Saud Aldajah ,  Emad Elnajjar

IPC分类号： F01N3/022 ,  F01N3/02 ,  F01N3/029

CPC分类号： B01D53/944 ,  B01D46/0057 ,  B01D46/0063 ,  B01D46/42 ,  B01D67/0039 ,  B01D69/10 ,  B01D69/12 ,  B01D71/021 ,  B01D71/022 ,  B01D2277/20 ,  B01D2279/30 ,  B01D2323/08 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  C01B32/162 ,  C01B32/164 ,  C01B32/17 ,  C01B2202/30 ,  C01B2202/34 ,  C01B2202/36 ,  F01N3/022 ,  F01N3/025 ,  F01N3/029 ,  F01N2330/02

摘要： We disclose a novel filter and process that converts the wastes in automotive exhausts into carbon nanotubes. The filter surface is composed of iron of similar catalyst. The filter is placed along the pathway of exhaust streamlines preferably at an angle of more than 5° and less than 15°. The filter is heated to temperatures in the range of 200-1000° C. The filter described in this invention can work in its won or supplement existing filtration systems. The end product of this filtration system is a material that is commercially valuable. The synthesized carbon nanotubes are purified using ionic liquid solution that is capable of removing undesirable carbonated material and leaving 95% purified carbon nanotubes. The purified carbon nanotubes have a diameter of 20-50 nm and a length of 1-10 micro meters.

摘要翻译： 我们公开了一种新型的过滤器和过程，将汽车废气中的废物转化为碳纳米管。 过滤表面由类似催化剂的铁组成。 过滤器优选以大于5°且小于15°的角度沿排气流线的路径放置。 将过滤器加热至200-1000℃的温度范围。本发明中描述的过滤器可以在其获得或补充现有的过滤系统中工作。 该过滤系统的最终产品是具有商业价值的材料。 使用能够去除不需要的碳酸化材料并留下95％纯化的碳纳米管的离子液体溶液来纯化合成的碳纳米管。 纯化的碳纳米管的直径为20-50nm，长度为1-10微米。

公开(公告)号：US07785472B2

公开(公告)日：2010-08-31

申请号：US10597790

申请日：2005-02-10

申请人： Kei Murakoshi

发明人： Kei Murakoshi

IPC分类号： B01D15/08 ,  C09C1/44

CPC分类号： H01M4/96 ,  B82Y15/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/172 ,  C01B2202/02 ,  C01B2202/30 ,  C01B2202/36 ,  G01N2030/8859 ,  G01P15/08 ,  G01P15/0802 ,  H01M4/8605 ,  H01M4/9083 ,  Y10S977/745 ,  Y10S977/748 ,  Y10S977/751 ,  Y10S977/845 ,  Y10S977/848

摘要： A method of separating, concentrating or purifying uniform carbon nanotubes with desired properties (diameter, chiral vector, etc) in a highly sensitive manner by the use of structure-sensitive properties peculiar to carbon nanotubes; and an apparatus therefor. There is provided a method of separating, concentrating, or purifying carbon nanotubes with the desired properties contained in a sample, comprising the steps of (a) irradiating a sample containing carbon nanotubes with light; and (b) selecting carbon nanotubes with desired properties. In a preferred embodiment, the light irradiation of the step (a) can be carried out in the presence of a metal so as to cause specified carbon nanotubes to selectively induce a photocatalytic reaction, resulting in metal deposition. Further, in a preferred embodiment, a given magnetic filed can be applied in the steps (b) so as to attain accumulation or concentration or carbon nanotubes with metal deposited.

摘要翻译： 通过使用碳纳米管特有的结构敏感性质，以高度敏感的方式分离，浓缩或纯化具有所需性质（直径，手性载体等）的均匀碳纳米管的方法; 及其装置。 提供了一种分离，浓缩或净化样品中包含的所需性质的碳纳米管的方法，包括以下步骤：（a）用光照射含有碳纳米管的样品; 和（b）选择具有所需性质的碳纳米管。 在优选的实施方案中，步骤（a）的光照射可以在金属的存在下进行，以使特定的碳纳米管选择性地诱导光催化反应，导致金属沉积。 此外，在优选实施例中，可以在步骤（b）中施加给定的磁场，以便获得积聚或浓缩或者沉积金属的碳纳米管。

公开(公告)号：US07670431B2

公开(公告)日：2010-03-02

申请号：US10768153

申请日：2004-02-02

申请人： Tomoko Miyahara ,  Kazunori Anazawa ,  Hiroyuki Watanabe

发明人： Tomoko Miyahara ,  Kazunori Anazawa ,  Hiroyuki Watanabe

IPC分类号： C23C16/00 ,  C23C16/02 ,  C23C16/26

CPC分类号： B01J15/005 ,  B01J19/2415 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/30 ,  C01B2202/34 ,  C01B2202/36

摘要： A gas decomposer formed from a porous material to decompose a carbon-containing raw material carried on a gas flow and to synthesize a carbon nanotube from the decomposed carbon-containing raw material is provided as a member suitable for use in carbon nanotube manufacture that offers a user a choice of using, or not using, a metal catalyst according to the user's need in vapor phase growth, which allows successive operation and which is therefore fit for mass production. Also provided are carbon nanotube manufacturing apparatus and method which use the gas decomposer.

摘要翻译： 提供了一种由多孔材料形成的气体分解器，用于分解携带在气流上的含碳原料并从分解的含碳原料合成碳纳米管，作为适用于碳纳米管制造的部件，其提供 使用者根据用户需要在气相生长中使用或不使用金属催化剂的选择，这允许连续的操作，因此适合批量生产。 还提供了使用气体分解器的碳纳米管制造装置和方法。

公开(公告)号：US07625545B2

公开(公告)日：2009-12-01

申请号：US10519294

申请日：2003-06-30

申请人： Yasuhiko Nishi ,  Hirotaka Mukai ,  Daisuke Ozamoto

发明人： Yasuhiko Nishi ,  Hirotaka Mukai ,  Daisuke Ozamoto

IPC分类号： D01F9/12 ,  D01F9/127

CPC分类号： B82Y30/00 ,  B82Y10/00 ,  B82Y40/00 ,  C01B32/162 ,  C01B2202/30 ,  C01B2202/34 ,  C01B2202/36 ,  H01J1/304 ,  H01J9/025 ,  H01J2201/30469 ,  Y10S977/843 ,  Y10S977/844 ,  Y10T29/49124

摘要： A process for producing a tape-like material uniformly containing highly pure single-walled or multi-walled carbon nanotubes and a tape-like material produced thereby; a high-performance field emission electrode including the tape-like material; and a process for producing the field emission electrode. The carbon nanotubes are synthesized by arc discharge, wherein an inert gas or inert gas-containing mixed gas is jetted onto a cathode having a carbon material from the inside of a hollow electrode (11) used as an anode, and simultaneously an arc is generated to form a path of arc discharge along a stream of the gas. At the same time, by relative movement of the electrodes, the cathode spot of the arc is moved on the cathode, and the synthesized carbon nanotubes are formed into a tape.

摘要翻译： 一种均匀地含有高纯度单壁或多壁碳纳米管的带状材料的制造方法以及由此生产的带状材料。 包括带状材料的高性能场致发射电极; 以及用于制造场致发射电极的方法。 通过电弧放电合成碳纳米管，其中惰性气体或惰性气体混合气体从用作阳极的中空电极（11）的内部喷射到具有碳材料的阴极上，同时产生电弧 以沿着气体流形成电弧放电的路径。 同时，通过电极的相对运动，电弧的阴极点在阴极上移动，合成的碳纳米管形成带状。