Method for producing fluorine-containing compound having iodine atom content reduced

    公开(公告)号:US10604461B2

    公开(公告)日:2020-03-31

    申请号:US15943750

    申请日:2018-04-03

    申请人: AGC Inc.

    发明人: Atsushi Watakabe

    摘要: The purpose of the present invention is to obtain a fluorine-containing compound which is easily stabilized without irradiation of ultraviolet light, by efficiently converting a C—I bond in an iodine-containing compound having a group represented by —CFRf—I (wherein Rf is a fluorine atom or a perfluoroalkyl group) to a C—H bond. A method for producing a fluorine-containing compound having an iodine atom content reduced than the following iodine-containing compound, which comprises subjecting an iodine-containing compound having a group represented by —CFRf—I (wherein Rf is a fluorine atom or a perfluoroalkyl group) to deiodinating treatment in the presence of an organic peroxide and a hydrogen-containing compound having a group represented by —CHR1—CHR2—CHR3— (wherein R1, R2 and R3 are each independently a hydrogen atom or an alkyl group).

    Photoacid generators for extreme ultraviolet lithography
    3.
    发明授权
    Photoacid generators for extreme ultraviolet lithography 有权
    用于极紫外光刻的光酸发生器

    公开(公告)号:US08039194B2

    公开(公告)日:2011-10-18

    申请号:US11970827

    申请日:2008-01-08

    申请人: Martin Glodde

    发明人: Martin Glodde

    摘要: A photoacid generator P+ A− comprises (a) an antenna group P+ comprising atoms with high EUV photoabsorption cross-sections according to FIG. 1 and A− anions; or (b) an antenna group P+ and A− comprising anions with low photoabsorption cross-sections for EUV; or (c) an antenna group P+, comprising atoms with high EUV photoabsorption cross-sections according to FIG. 1 and A− comprising anions with low photoabsorption cross-sections for EUV. Novel compounds comprise DTFPIO PFBuS, and DTBPIO CN5.

    摘要翻译: 光致酸发生器P + A-包括(a)包含根据图1的具有高EUV光吸收横截面的原子的天线组P + 1和A-阴离子; 或(b)天线组P +和A-包括对EUV具有低光吸收横截面的阴离子; 或(c)天线组P +,包括根据图1的具有高EUV光吸收横截面的原子。 1和A-包括对于EUV具有低光吸收横截面的阴离子。 新型化合物包括DTFPIO PFBuS和DTBPIO CN5。

    Process for production of polyfluoroolefins
    4.
    发明授权
    Process for production of polyfluoroolefins 失效
    生产聚氟烯烃的方法

    公开(公告)号:US5276221A

    公开(公告)日:1994-01-04

    申请号:US63379

    申请日:1993-01-25

    申请人: Carl G. Krespan

    发明人: Carl G. Krespan

    摘要: This invention concerns a process for the production of polyfluoroolefins by the catalytic addition of polyfluoroallylic fluorides to fluoroethylenes. 1:1 and 1:2 Adducts such as F-pentene-2 and F-heptene-3 can be formed selectively and reduced further to dihydro- or trihydropolyfluoroalkanes, which are useful as HFC cleaning agents.

    摘要翻译: 本发明涉及通过将多氟氟化物催化加成氟乙烯来生产聚氟烯烃的方法。 1:1和1:2可以选择性地形成F-戊烯-2和F-庚烯-3等加合物,进一步还原成可用作HFC清洗剂的二氢或三氢多氟烷烃。

    Process for preparing hexachlorocyclopentadiene
    6.
    发明授权
    Process for preparing hexachlorocyclopentadiene 失效
    六氯环戊二烯的制备方法

    公开(公告)号:US4255597A

    公开(公告)日:1981-03-10

    申请号:US141458

    申请日:1980-04-18

    IPC分类号: C07C17/02 C07C17/06 C07C23/08

    CPC分类号: C07C23/08 C07C17/02 C07C17/06

    摘要: There is disclosed a process for the production of hexachlorocyclopentadiene comprising the steps of:1. Reacting liquid cyclopentadiene and chlorine at a temperature of from about 0.degree. to about 100.degree. C. until an average of at least 4 chlorine atoms has been added per mole of cyclopentadiene to form a first-stage product;2. heating the resultant liquid reaction product of Step 1 in a second stage at a temperature of from about 140.degree. C. to below about 200.degree. C. with chlorine in the presence of from about 0.0001% to about 5.0% (by weight) of an aromatic compound until the reaction products of Step 1 contain an average of about 6 chlorine atoms per molecule, based on cyclopentadiene starting material; wherein said aromatic compound contains from 1 to 3 aromatic rings; at least one of the rings containing a nitrogen atom;3. vaporizing and heating the resulting reaction products of Step 2 in a third stage in the presence of chlorine to a temperature of above 450.degree. C. until at least a major portion of said products are converted to hexachlorocyclopentadiene.

    摘要翻译: 公开了一种生产六氯环戊二烯的方法,包括以下步骤:1.在约0℃至约100℃的温度下反应液体环戊二烯和氯,直到每摩尔加入平均至少4个氯原子 的环戊二烯以形成第一级产物; 2.在大约140℃至低于约200℃的温度下,在约0.0001%至约5.0%(重量)的存在下,用氯气将所得到的步骤1的液体反应产物加热至第二阶段, 的芳族化合物,直到步骤1的反应产物基于环戊二烯起始材料每分子平均含有约6个氯原子; 其中所述芳族化合物含有1至3个芳环; 至少一个含有氮原子的环; 3.在氯存在下将第二步产生的反应产物蒸发并加热至高于450℃的温度,直到所述产物的至少大部分转化为六氯环戊二烯。

    Process for preparing hexachlorocyclopentadiene
    7.
    发明授权
    Process for preparing hexachlorocyclopentadiene 失效
    六氯环戊二烯的制备方法

    公开(公告)号:US4246205A

    公开(公告)日:1981-01-20

    申请号:US77463

    申请日:1979-09-20

    CPC分类号: C07C23/08 C07C17/02 C07C17/10

    摘要: There is disclosed a process for the production of hexachlorocyclopentadiene comprising the steps of:1. Reacting liquid cyclopentadiene and chlorine at a temperature of from about 0.degree. to about 100.degree. C. until an average of at least 4 chlorine atoms has been added per mole of cyclopentadiene to form a first-stage product;2. heating the resultant liquid reaction product of Step 1 in a second stage at a temperature of from about 140.degree. C. to below about 200.degree. C. with chlorine in the presence of from about 0.0001% to about 5.0% (by weight) of an aromatic compound until the reaction products of Step 1 contain an average of about 6 chlorine atoms per molecule, based on cyclopentadiene starting material; wherein said aromatic compound contains from about 4 to about 30 carbon atoms and from 1 to about 4 aromatic rings; and3. vaporizing and heating the resulting reaction products of Step 2 in a third stage in the presence of chlorine to a temperature of above 450.degree. C. until at least a major portion of said products are converted to hexachlorocyclopentadiene; and recovering therefrom hexachlorocyclopentadiene.

    摘要翻译: 公开了一种生产六氯环戊二烯的方法,包括以下步骤:1.在约0℃至约100℃的温度下反应液体环戊二烯和氯,直到每摩尔加入平均至少4个氯原子 的环戊二烯以形成第一级产物; 2.在大约140℃至低于约200℃的温度下,在约0.0001%至约5.0%(重量)的存在下,用氯气将所得到的步骤1的液体反应产物加热至第二阶段, 的芳族化合物,直到步骤1的反应产物基于环戊二烯起始材料每分子平均含有约6个氯原子; 其中所述芳族化合物含有约4至约30个碳原子和1至约4个芳环; 3.在第三阶段,在氯存在下,将得到的步骤2的反应产物汽化和加热至450℃以上,直至所述产物的至少大部分转化为六氯环戊二烯; 并从中回收六氯环戊二烯。

    Substituted polyhalogenated cyclopentadienes
    9.
    发明授权
    Substituted polyhalogenated cyclopentadienes 失效
    取代的多羟基环戊二烯

    公开(公告)号:US3799994A

    公开(公告)日:1974-03-26

    申请号:US13539171

    申请日:1971-04-19

    申请人: MONSANTO CO

    发明人: MARK V

    摘要: Compounds of the formula

    WHEREIN Y is independently selected from the group consisting of methyl, hydrogen and a halogen of atomic weight between 35 and 80 with at least four of the Y substituents being said halogen; each R is independently selected from the group consisting of alkyl having at least one and a maximum of 12 carbon atoms, alkenyl having at least two and a maximum of five carbon atoms, alkoxyalkyl having at least two and a maximum of six carbon atoms, and n is one of the integers one or two. These compounds possess insecticidal activity and are valuable intermediates for the preparation of insecticides having low mammalian toxicity.

    摘要翻译: 式WHYEINY的化合物独立地选自甲基,氢和原子量为35至80的卤素,其中至少四个Y取代基为所述卤素; 每个R独立地选自具有至少一个和最多12个碳原子的烷基,具有至少两个和最多五个碳原子的烯基,具有至少两个和最多六个碳原子的烷氧基烷基,以及 n是一个或两个整数之一。