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    GEOMETRICAL ISOMER OF ACRYLONITRILE COMPOUND, MIXTURE THEREOF, AND PROCESS FOR PRODUCING THESE
    1.
    发明申请
    GEOMETRICAL ISOMER OF ACRYLONITRILE COMPOUND, MIXTURE THEREOF, AND PROCESS FOR PRODUCING THESE 审中-公开
    丙烯腈化合物的几何异构体，其混合物及其生产方法

    公开(公告)号：WO01009086A1

    公开(公告)日：2001-02-08

    申请号：PCT/JP2000/004996

    申请日：2000-07-26

    IPC: C07C255/34 ,  C07C255/38 ,  C07C329/04 ,  C07C329/06 ,  C07C329/16 ,  C07C255/15 ,  A01N37/34 ,  C07C253/30

    CPC classification number: C07C329/16 ,  C07B2200/09 ,  C07C255/34 ,  C07C255/38 ,  C07C329/04 ,  C07C329/06

    Abstract: A geometrical isomer of an acrylonitrile compound represented by formula (I) or of a salt of the compound; or a mixture of the isomer [wherein T is phenyl or pyridyl each substituted by R2; Q is phenyl, thienyl, pyridyl, or benzyl each optionally substituted by R3; R1 is -C(=O)R4 or -C(=S)R4; and R4 is optionally substituted alkyl, alkenyl, alkynyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, alkenylthio, alkynylthio, cycloalkyl, cycloalkyloxy, cycloalkylthio, -N(R5)R6, phenyl, phenoxy, phenylthio, benzyl, benzyloxy, benzylthio, -J, -O-J, or -S-J]. The geometrical isomer has a longer retention time when analyzed by reversed-phase liquid chromatography in which a packing comprising silica having chemically bonded thereto an alkyl selected among trimethyl, octyl, and octadecyl is used as the stationary phase and a polar solvent selected among water, methanol, and acetonitrile is used as the mobile phase. The geometrical-isomer mixture comprises the geometrical isomer in a larger proportion.

    Abstract translation: 由式（I）表示的丙烯腈化合物或该化合物的盐的几何异构体; 或异构体的混合物[其中T为苯基或吡啶基，各自被R 2取代; Q是各自任选被R 3取代的苯基，噻吩基，吡啶基或苄基; R 1是-C（= O）R 4或-C（= S）R 4; 烷氧基，链烯硫基，炔硫基，环烷基，环烷氧基，环烷硫基，-N（R5）R6，苯基，苯氧基，苯硫基，苄基，苄氧基，苄硫基，-J ，-OJ或-SJ]。 当通过反相液相色谱分析时，几何异构体具有更长的保留时间，其中使用化学键合有选自三甲基，辛基和十八烷基的烷基的二氧化硅的填料作为固定相，并且极性溶剂选自水， 甲醇和乙腈作为流动相。 几何异构体混合物包含较大比例的几何异构体。

    SYNTHESIS OF VINYL CARBONATES FOR USE IN PRODUCING VINYL CARBAMATES
    4.
    发明申请
    SYNTHESIS OF VINYL CARBONATES FOR USE IN PRODUCING VINYL CARBAMATES 审中-公开
    用于生产乙烯基碳酸酯的乙烯基碳酸酯的合成

    公开(公告)号：WO01000634A1

    公开(公告)日：2001-01-04

    申请号：PCT/US2000/017820

    申请日：2000-06-28

    IPC: C07C68/02 ,  C07C68/06 ,  C07C269/04 ,  C07F7/08 ,  C07F7/18 ,  C07C69/96 ,  C07C329/04

    CPC classification number: C07F7/0889 ,  C07C68/02 ,  C07C68/06 ,  C07C269/04 ,  C07C69/96

    Abstract: A method for making a vinyl carbonate represented by the formula (I): CH2=CHOC(O)X1R1, wherein X1 is oxygen or sulfur and R1 is a substituted or an unsubstituted aliphatic alkyl, aryl, aryl alkyl, olefinic, vinyl, or cycloaliphatic group comprises: (a) reacting a compound represented by the formula (II): X2C(O)X1R1, wherein X2 is a halogen other than fluorine, with a compound represented by the formula (III): M1-F, wherein M1 is selected from a Group IA metal, in the presence of a first phase transfer catalyst and a first organic solvent, to form a compound represented by the formula (IV): FC(O)X1R1; and (b) reacting a compound represented by the formula (IV) with a compound represented by the formula (V): CH2=CHOSi(R2)3, wherein R2 is a substituted or an unsubstituted aliphatic alkyl, aryl, aryl alkyl olefinic, vinyl, or cycloaliphatic group, or any combination thereof, in the presence of a metal salt represented by the formula M2-F wherein M2 is a Group IA metal, a second phase transfer catalyst, and a second organic solvent, to form the compound represented by formula (I).

    Abstract translation: 一种制备由式（I）表示的乙烯基碳酸酯的方法：CH2 = CHOC（O）X1R1，其中X1是氧或硫，R1是取代或未取代的脂族烷基，芳基，芳基烷基，烯属，乙烯基或 脂环族基团包括：（a）使由式（II）表示的化合物：X2C（O）X1R1（其中X2是氟以外的卤素）与式（III）表示的化合物：M1-F，其中M1 选自IA族金属，在第一相转移催化剂和第一有机溶剂的存在下，形成由式（IV）表示的化合物：FC（O）X1R1; 和（b）使由式（Ⅳ）表示的化合物与式（Ⅴ）表示的化合物反应：CH2 = CHOSi（R2）3，其中R2是取代或未取代的脂族烷基，芳基，芳基烷基烯属， 乙烯基或脂环族基团，或其任何组合，在由式M2-F表示的金属盐的存在下，其中M2为IA族金属，第二相转移催化剂和第二有机溶剂，以形成所述化合物 由式（I）表示。

    PROCESS FOR THE PREPARATION OF THIONO COMPOUNDS
    5.
    发明申请
    PROCESS FOR THE PREPARATION OF THIONO COMPOUNDS 审中-公开
    制备化合物的方法

    公开(公告)号：WO00005202A1

    公开(公告)日：2000-02-03

    申请号：PCT/GB1999/002018

    申请日：1999-06-28

    IPC: C07C329/02 ,  C07C329/04 ,  C07C329/20 ,  C07C333/08 ,  C07C337/02

    CPC classification number: C07C337/02 ,  C07C329/02 ,  C07C329/04 ,  C07C329/20 ,  C07C333/08

    Abstract: A method of preparing a compound of formula (I) where R , R , R , R and R are independently selected from hydrogen or specified substitutents, X is -O-, -S-, -NR -, -C=N-, -C=N-O-, -NR -NR -, where R , R and R are independently selected from hydrogen or alkyl; and R is an alkyl; which process comprises reacting a compound of formula (II) with a compound of formula (III) where R is as defined in relation to formula (I) and Y is a leaving group other than a group SR where R is CH2COOH or C1-4alkyl. Compounds of formula (III) are suitably prepared in situ by a method which forms a further aspect of the invention.

    Abstract translation: 制备式（I）化合物的方法，其中R 1，R 2，R 3，R 4和R 5独立地选自氢或指定的取代基，X是-O- ，-S - ， - NR 7 - ， - C = N - ， - C = NO - ， - NR 8 -NR 9 - ，其中R 7，R 8和R 9 >独立地选自氢或烷基; 和R 6是烷基; 该方法包括使式（II）的化合物与式（III）化合物反应，其中R 6如关于式（I）所定义，Y是除SR x之外的离去基团，其中R X是CH 2 COOH或C 1-4烷基。 式（III）的化合物通过形成本发明的另一方面的方法适当地制备。

    CARBONDISULFIDE DERIVED ZWITTERIONS
    6.
    发明申请
    CARBONDISULFIDE DERIVED ZWITTERIONS 审中-公开

    公开(公告)号：WO2019183645A1

    公开(公告)日：2019-09-26

    申请号：PCT/US2019/027421

    申请日：2019-04-14

    Applicant: DALY, Thomas, P.

    Inventor： DALY, Thomas, P.

    IPC: C07C329/04 ,  C07C333/14

    Abstract: Amines and amine derivatives that improve the buffering range, and/or reduce the chelation and other negative interactions of the buffer and the system to be buffered. The reaction of amines or polyamines with various molecules to form polyamines with differing pKa's will extend the buffering range, derivatives that result in polyamines that have the same pKa yields a greater buffering capacity. Derivatives that result in zwitterionic buffers improve yield by allowing a greater range of stability.

    PHOSPINE LIGAND PROMOTED SYNTHESIS OF TETRAARYLOXYALKANE AND DIARYLCARBONATES
    8.
    发明申请
    PHOSPINE LIGAND PROMOTED SYNTHESIS OF TETRAARYLOXYALKANE AND DIARYLCARBONATES 审中-公开
    磷酸二氢吡啶酮和二磺酸的促进合成

    公开(公告)号：WO00009466A1

    公开(公告)日：2000-02-24

    申请号：PCT/US1999/011835

    申请日：1999-05-27

    IPC: C07B61/00 ,  C07C41/60 ,  C07C43/32 ,  C07C68/00 ,  C07C69/96 ,  C07C329/04

    CPC classification number: C07C68/00 ,  C07C41/60 ,  C07C69/96 ,  C07C43/32

    Abstract: Addition of phosphine ligands can produce high yields of tetraphenoxymethane, TPM, and diphenylcarbonate, DPC, in short reaction times and improved reaction rates by a copper-induced condensation of phenol and carbon disulfide, CS2. Either aromatic or aliphatic substituted phosphine ligands can be employed. The copper (I) oxide utilization is significantly improved in reactions containing phosphine ligands, such that yields exceeding 100 % tetraphenoxymethane are observed. Some of the sulfur-containing byproduct is transferred to the phosphine in the form of phosphine sulfide.

    Abstract translation: 膦配体的添加可以在短的反应时间内产生高产率的四苯氧基甲烷，TPM和二苯基碳酸酯DPC，并且通过苯酚和二硫化碳CS2的铜诱导缩合来提高反应速率。 可以使用芳族或脂族取代的膦配体。 在含有膦配体的反应中，氧化铜（I）利用率显着提高，从而观察到产率超过100％的四苯氧基甲烷。 一些含硫​​副产物以硫化磷的形式转移到磷化氢。

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