利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

205 条记录 (耗时 0.029 秒)

    POLYMERIZATION COMPOSITIONS AND METHODS
    97.
    发明公开
    POLYMERIZATION COMPOSITIONS AND METHODS 审中-公开
    聚合混合物和方法

    公开(公告)号：EP1259551A1

    公开(公告)日：2002-11-27

    申请号：EP00968537.1

    申请日：2000-09-29

    申请人： Noveon IP Holdings Corp.

    发明人： LAI, John, Ta-Yuan ,  FILLA, Deborah, S.

    IPC分类号： C08F4/00 ,  C08F2/38 ,  C08F293/00 ,  C07D265/32 ,  C07D241/08 ,  C07C239/20

    摘要： Improved polymerization agents and processes are disclosed. In particular, the nitrogen-containing free radicals and free radical precursors are used to effect efficient, controlled polymerization of polymeric materials, including monomers, to form polymers, including homopolymers, copolymers, and block polymers. In particular, nitroxide compounds, methods of making nitroxide compounds, methods of using the nitroxide compounds to polymerize monomer compositions, and polymer compositions made using the nitroxide compounds are disclosed.

    MONO AND MULTIFUNCTIONAL ALKOXYAMINES FOR THE PREPARATION OF FUNCTIONALIZED MACROMERS
    98.
    发明公开
    MONO AND MULTIFUNCTIONAL ALKOXYAMINES FOR THE PREPARATION OF FUNCTIONALIZED MACROMERS 有权
    单声道和多用于制备官能大分子功能烷氧基

    公开(公告)号：EP1189875A2

    公开(公告)日：2002-03-27

    申请号：EP00951302.9

    申请日：2000-06-26

    申请人： Ciba Specialty Chemicals Holding Inc.

    发明人： KRAMER, Andreas ,  NESVADBA, Peter ,  ZINK, Marie-Odile ,  WUNDERLICH, Wiebke

    IPC分类号： C07C239/20 ,  C07D211/94 ,  C08F4/00

    CPC分类号： C07D295/24 ,  C07D211/94 ,  C07F7/1856 ,  C07F9/4006 ,  C08F4/00

    摘要： The invention pertains to a compound of formula (I), (II) or (III) wherein R1 and R2 are independently of each other hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkinyl or phenyl which are unsubstituted or substituted by NO2, halogen, amino, hydroxy, cyano, carboxy, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylamino or di(C1-C4alkyl)amino; A is a group capable of forming a stable free nitroxyl radical A., which is bound via its oxygen atom to the carbon atom; Y is O, NR3 or CHR3-Xa, wherein Xa is O, S or NR3; R3 is hydrogen, C1-C18alkyl, C3-C18alkenyl, C3-C18alkinyl or phenyl which are unsubstituted or substituted by NO2, halogen, amino, hydroxy, cyano, carboxy, C1-C4alkoxy, C1-C4alkylthio, C1-C4alkylamino or di(C1-C4alkyl)amino; Q1 is an organic or inorganic radical, derived from a compound having at least one functional group being capable of reacting with a hydroxy group; Q2 is an organic radical derived from a mono or polyfunctional alcohol, mono or polyfunctional aminoalcohol, mono or polyfunctional amine mono or polyfunctional mercaptane, mono or polyfunctional phenol or mono or polyfunctional thiophenol; and n is a number from 1 to 20; with the provison that in formula (I) if n is 1, Q1 is not (a), or if n is 2, R1 is H, and R2 is -CH2-O-tert.butyl, A is not 2,2,6,6-tetramethylpiperidine or 2,2,6,6-tetramethylpiperidine-4-carboxylic acid. Further subjects of the invention are a composition comprising above compounds and at least one ethylenically unsaturated monomer, process for polymerization and the (co)polymers obtained therefrom.

    VINYLATED ALKOXYAMINE, USE THEREOF, AND PROCESS FOR PRODUCING THE SAME
    99.
    发明公开
    VINYLATED ALKOXYAMINE, USE THEREOF, AND PROCESS FOR PRODUCING THE SAME 有权
    VINYLIERTE ALKOXAMINE，IHRE VERWENDUNG UND EIN VERFAHREN ZU IHRER HERSTELLUNG

    公开(公告)号：EP1188742A1

    公开(公告)日：2002-03-20

    申请号：EP00927796.3

    申请日：2000-05-17

    申请人： NOF CORPORATION

    发明人： HAYASHI, Masaki ,  NAKAMURA, Tomoyuki ,  UJIKAWA, Norihisa

    IPC分类号： C07C239/20 ,  C07D211/94 ,  C08F257/00 ,  C08F4/00 ,  C08F12/14

    CPC分类号： C08F4/00 ,  C07C239/20 ,  C07D211/94 ,  C08F12/26 ,  C08F12/28 ,  C08F257/00 ,  C08F257/02 ,  C08F265/04 ,  C08F290/06 ,  C08F291/00

    摘要： Alkoxyamines containing a vinyl group as represented by the following general formula (1) are produced in a method which comprises a process of heating divinyl benzene, nitroxide compound and organic peroxide up to a temperature at which the organic peroxide decomposes thermally:
    (In the formula, R 1 represents an aryl group or an R 2 O group, wherein R 2 represents a linear or branched alkyl group having 1 - 12 carbon atoms or a cycloalkyl group. R 3 and R 4 are each tertiary alkyl group having 4 - 6 carbon atoms or of cyclic structure where R 3 and R 4 are connected with each other having a total carbon number of 8 - 16. In case of cyclic structure, they are optionally substituted either by an alkyl group, an oxo group, a hydroxyl group, an acyloxy group or an alkoxy group.) Furthermore, graft polymers can be produced by the use of high molecular radical polymerization initiators from which an alkoxyamine group suspends.

    摘要翻译： 以下述通式（1）表示的含有乙烯基的烷氧基胺是通过将二乙烯基苯，硝基氧化合物和有机过氧化物加热至有机过氧化物分解为热的温度的方法制备的：（ 在该式中，R 1表示芳基或R 2 O基，其中R 2表示具有1〜12个碳原子的直链或支链烷基或环烷基，R 3和R 3 每个具有4-6个碳原子的叔烷基或具有总碳数为8-16的R 3和R 4彼此连接的环状结构的叔烷基。在环状结构的情况下，它们 任选被烷基，氧代基，羟基，酰氧基或烷氧基取代。）此外，接枝聚合物可以通过使用烷氧基胺基团悬浮的高分子量聚合引发剂来制备。