公开(公告)号：US20130280511A1

公开(公告)日：2013-10-24

申请号：US13825926

申请日：2011-09-16

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: C08K3/08

CPC classification number: C08K3/08 ,  B29B15/08 ,  B29D30/38 ,  B29D2030/383 ,  Y10T428/294

Abstract: Pneumatic tire comprising a composite reinforcer (R-2) that is self-adhesive by curing to a diene rubber matrix, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising on the one hand a thermoplastic polymer, the glass transition temperature of which is positive, on the other hand an unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative.

Abstract translation: 包括通过固化至二烯橡胶基体而自粘的复合增强件（R-2）的气动轮胎，包括：一个或多个加强丝（20），例如碳钢帘线; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，一层热塑性聚合物组合物，一方面包括玻璃化转变温度为正的热塑性聚合物，另一方面包含不饱和热塑性塑料弹性体，玻璃化转变 温度为负。

公开(公告)号：US09010079B2

公开(公告)日：2015-04-21

申请号：US13699299

申请日：2011-05-06

Applicant: Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

IPC: D02G3/48 ,  D07B7/14 ,  D02G3/12 ,  D07B1/06

CPC classification number: D02G3/48 ,  D02G3/12 ,  D07B1/0626 ,  D07B1/0633 ,  D07B1/0646 ,  D07B1/0653 ,  D07B7/145 ,  D07B2201/2011 ,  D07B2201/2028 ,  D07B2201/2037 ,  D07B2201/2046 ,  D07B2201/2048 ,  D07B2201/2059 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2207/205 ,  D07B2207/4072 ,  D07B2401/208 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/18 ,  D07B2801/16

Abstract: Method for manufacturing a metal cord with three concentric layers including a first layer of diameter dc made up of M wire(s) of diameter d1, around which layer are wound together as a helix at a pitch p2, as a second layer, N wires of diameter d2, around which are wound as a helix at pitch p3, as a third layer, P wires of diameter d3. The N wires of the second layer are assembled around the layer to form, at a point called “assembling point”, an intermediate cord called “core strand” of M+N construction; upstream and/or downstream of the assembling point, the layer and/or the core strand is sheathed with a rubber or rubber composition by passing through at least one extrusion head; then the P wires of the third layer are assembled around the core strand to form a cord of M+N+P construction thus rubberized from the inside.

Abstract translation: 用于制造具有三个同心层的金属帘线的方法，所述金属帘线包括由直径为d1的M线构成的直径为直径为d的第一直径直径为d的层，以层间距p2作为螺旋缠绕在一起作为第二层，N线 直径为d2，以间距p3作为螺旋缠绕，作为第三层，直径为d3的P线。 第二层的N根线被组装在层上，在称为“组装点”的点形成称为M + N结构的“芯线”的中间线; 在组装点的上游和/或下游，通过穿过至少一个挤出头，用橡胶或橡胶组合物包裹层和/或芯股线; 那么第三层的P线组装在芯股线周围，形成一个M + N + P结构的绳索，从而从里面涂上橡胶。

公开(公告)号：US08790788B2

公开(公告)日：2014-07-29

申请号：US13322235

申请日：2010-05-20

Applicant: Emmanuel Custodero ,  Sébastien Rigo ,  Vincent Abad

Inventor： Emmanuel Custodero ,  Sébastien Rigo ,  Vincent Abad

IPC: B32B27/00

CPC classification number: D07B1/0666 ,  B29D30/38 ,  D02G3/48 ,  D07B2201/2012 ,  D07B2201/2013 ,  D07B2201/2044 ,  D07B2201/2045 ,  D07B2201/2046 ,  D07B2205/2017 ,  D07B2205/2046 ,  D07B2501/2046 ,  D07B2501/2053 ,  Y10T156/10 ,  Y10T428/269 ,  Y10T428/2947 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31855 ,  D07B2801/18

Abstract: Composite reinforcement (R-2) that is self-adhesive by curing to a diene rubber matrix, which can be used as reinforcing element for a tire, having one or more reinforcing thread(s) (20), for example a carbon steel cord; a first layer (21) of a thermoplastic polymer, the glass transition temperature of which is positive, for example 6,6 polyamide, covering the thread or the threads; and a second layer (22) having a functionalized unsaturated thermoplastic styrene elastomer, the glass transition temperature of which is negative, for example an epoxidized SBS elastomer, covering the first layer (21), the elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcement and rubber article or semi-finished product, especially a tire, incorporating such a composite reinforcement.

Abstract translation: 通过固化到二烯橡胶基质上的可自动粘合的复合增强材料（R-2），其可用作轮胎的增强元件，其具有一个或多个增强线（20），例如碳钢绳 ; 热塑性聚合物的第一层（21），其玻璃化转变温度为正，例如6,6聚酰胺，覆盖线或线; 和具有官能化的不饱和热塑性苯乙烯弹性体的第二层（22），其玻璃化转变温度为负，例如覆盖第一层（21）的环氧化SBS弹性体，含有选自环氧化物，羧基和 酸酐或酯基。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是掺入这种复合增强件的轮胎。

公开(公告)号：US20130232936A1

公开(公告)日：2013-09-12

申请号：US13699299

申请日：2011-05-06

Applicant: Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Emmanuel Custodero ,  Sébastien Rigo ,  Jérémy Toussain

IPC: D02G3/48 ,  D02G3/12

CPC classification number: D02G3/48 ,  D02G3/12 ,  D07B1/0626 ,  D07B1/0633 ,  D07B1/0646 ,  D07B1/0653 ,  D07B7/145 ,  D07B2201/2011 ,  D07B2201/2028 ,  D07B2201/2037 ,  D07B2201/2046 ,  D07B2201/2048 ,  D07B2201/2059 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2207/205 ,  D07B2207/4072 ,  D07B2401/208 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/18 ,  D07B2801/16

Abstract: Method for manufacturing a metal cord with three concentric layers including a first layer of diameter dc made up of M wire(s) of diameter d1, around which layer are wound together as a helix at a pitch p2, as a second layer, N wires of diameter d2, around which are wound as a helix at pitch p3, as a third layer, P wires of diameter d3. The N wires of the second layer are assembled around the layer to form, at a point called “assembling point”, an intermediate cord called “core strand” of M+N construction; upstream and/or downstream of the assembling point, the layer and/or the core strand is sheathed with a rubber or rubber composition by passing through at least one extrusion head; then the P wires of the third layer are assembled around the core strand to form a cord of M+N+P construction thus rubberized from the inside.

Abstract translation: 用于制造具有三个同心层的金属帘线的方法，所述金属帘线包括由直径为d1的M线构成的直径为直径为d的第一直径直径为d的层，以层间距p2作为螺旋缠绕在一起作为第二层，N线 直径为d2，以间距p3作为螺旋缠绕，作为第三层，直径为d3的P线。 第二层的N根线被组装在层上，在称为“组装点”的点形成称为M + N结构的“芯线”的中间线; 在组装点的上游和/或下游，通过穿过至少一个挤出头，用橡胶或橡胶组合物包裹层和/或芯股线; 那么第三层的P线组装在芯股线周围，形成一个M + N + P结构的绳索，从而从里面涂上橡胶。

公开(公告)号：US20130220506A1

公开(公告)日：2013-08-29

申请号：US13699291

申请日：2011-05-06

Applicant: Thibaud Pottier ,  Sébastien Rigo ,  Jérémy Toussain

Inventor： Thibaud Pottier ,  Sébastien Rigo ,  Jérémy Toussain

IPC: B60C9/00

CPC classification number: B60C9/005 ,  B60C2009/0014 ,  D07B1/0613 ,  D07B1/0626 ,  D07B1/0633 ,  D07B7/145 ,  D07B2201/2011 ,  D07B2201/2028 ,  D07B2201/2046 ,  D07B2201/2062 ,  D07B2201/2082 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2207/205 ,  D07B2207/4072 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/18 ,  D07B2801/16

Abstract: Metal cord with three concentric layers including a first layer of diameter dc made up of M wire(s) of diameter d1, around which are wound as a helix at a pitch p2, as a second layer, N wires of diameter d2, around which are wound as a helix at pitch p3, as a third layer, P wires of diameter d3. Some gaps or capillaries in the cord situated between the core and the second layer and between the core wires themselves when M is greater than 1 and between the N wires of the second layer and the P wires of the third layer, contain a filling rubber based on an unsaturated thermoplastic elastomer

Abstract translation: 具有三个同心层的金属线，包括由直径为d1的M线组成的第一直径直径的直径为d的绕组，以间距p2作为螺旋缠绕，作为第二层，N直径为d2的线 以间距p3作为螺旋缠绕，作为第三层，直径为d3的P线。 当M大于1且在第二层的N线和第三层的P线之间时，位于芯和第二层之间以及芯线本身之间的线中的一些间隙或毛细管包含基于 在不饱和热塑性弹性体上

公开(公告)号：US20120128972A1

公开(公告)日：2012-05-24

申请号：US13322235

申请日：2010-05-20

Applicant: Emmanuel Custodero ,  Sébastien Rigo ,  Vincent Abad

Inventor： Emmanuel Custodero ,  Sébastien Rigo ,  Vincent Abad

IPC: D07B1/16 ,  B32B37/14 ,  D07B1/06 ,  B32B5/28 ,  D02G3/48

CPC classification number: D07B1/0666 ,  B29D30/38 ,  D02G3/48 ,  D07B2201/2012 ,  D07B2201/2013 ,  D07B2201/2044 ,  D07B2201/2045 ,  D07B2201/2046 ,  D07B2205/2017 ,  D07B2205/2046 ,  D07B2501/2046 ,  D07B2501/2053 ,  Y10T156/10 ,  Y10T428/269 ,  Y10T428/2947 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31855 ,  D07B2801/18

Abstract: Composite reinforcement (R-2) that is self-adhesive by curing to a diene rubber matrix, which can be used as reinforcing element for a tire, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; a first layer (21) of a thermoplastic polymer, the glass transition temperature of which is positive, for example 6,6 polyamide, covering said thread or said threads; and a second layer (22) comprising a functionalized unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative, for example an epoxidized SBS elastomer, covering the first layer (21), said elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcement and rubber article or semi-finished product, especially a tire, incorporating such a composite reinforcement.

Abstract translation: 通过固化可以用作轮胎的增强元件的二烯橡胶基体，其是自粘合的复合增强材料（R-2），包括：一个或多个增强线（20），例如碳钢 绳子 热塑性聚合物的第一层（21），其玻璃化转变温度为正，例如6,6聚酰胺，覆盖所述螺纹或所述螺纹; 和包含官能化的不饱和热塑性塑料弹性体的第二层（22），其玻璃化转变温度是负的，例如覆盖第一层（21）的环氧化SBS弹性体，所述弹性体含有选自环氧化物，羧基和 酸酐或酯基。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是掺入这种复合增强件的轮胎。

公开(公告)号：US20140051312A1

公开(公告)日：2014-02-20

申请号：US13981677

申请日：2012-01-31

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: B32B27/04 ,  B29D30/06 ,  C09J7/04

CPC classification number: B60C9/0057 ,  B29B15/125 ,  B29D30/0601 ,  B29D30/40 ,  B29K2009/06 ,  B29K2021/003 ,  B29K2071/12 ,  B29L2030/00 ,  B60C9/0042 ,  C08L53/02 ,  C09J7/21 ,  C09J7/30 ,  C09J7/35 ,  C09J153/02 ,  C09J171/12 ,  C09J2425/00 ,  C09J2465/00 ,  D06M15/227 ,  D06M15/233 ,  D06M15/53 ,  Y10T442/2738

Abstract: Rubber composite, and in particular tyre, reinforced with a sized textile material, such as a fibre or a film, at least one portion of which is coated with an adhesive layer, capable of adhering directly via curing (crosslinking) to an unsaturated rubber matrix, such as a natural rubber matrix, characterized in that said layer comprises an adhesive composition or thermoplastic adhesive, in the liquid or solid state, which is based on at least one unsaturated thermoplastic styrene (TPS) elastomer and a poly(p-phenylene ether) (PPE).Such an adhesive based on unsaturated TPS and PPE advantageously makes it possible to replace a conventional textile adhesive of RFL type. Use of such an adhesive for the adhesive bonding of a textile material to an unsaturated, in particular diene, rubber. Process for obtaining such a composite.

Abstract translation: 橡胶复合材料，特别是轮胎，用诸如纤维或薄膜的尺寸的纺织材料增强，其至少一部分涂覆有粘合剂层，其能够通过固化（交联）直接粘附到不饱和橡胶基体 ，例如天然橡胶基质，其特征在于所述层包含基于至少一种不饱和热塑性苯乙烯（TPS）弹性体和聚（对亚苯基醚）的液体或固体状态的粘合剂组合物或热塑性粘合剂 ）（PPE）。 基于不饱和TPS和PPE的这种粘合剂有利地可以替代RFL型的常规纺织粘合剂。 使用这种粘合剂将纺织材料粘合到不饱和的，特别是二烯的橡胶上。 获得这种复合材料的方法。

公开(公告)号：US20140045984A1

公开(公告)日：2014-02-13

申请号：US13989017

申请日：2011-11-16

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: C09D109/06 ,  D07B1/06 ,  C09D177/02

CPC classification number: C09D109/06 ,  C09D177/02 ,  D02G3/48 ,  D07B1/0606 ,  D07B1/062 ,  D07B1/0666 ,  D07B2201/2012 ,  D07B2201/2044 ,  D07B2201/2046 ,  D07B2205/2017 ,  D07B2205/2039 ,  D07B2205/2046 ,  D07B2205/2082 ,  D07B2207/4068 ,  D07B2501/2046 ,  D07B2501/2053 ,  Y10T428/2938 ,  Y10T428/294 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/18 ,  D07B2801/16

Abstract: Composite reinforcer (R-2) that is self-adhesive by curing to a diene rubber matrix, which can be used as reinforcing element for a pneumatic tire, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising on the one hand a thermoplastic polymer, the glass transition temperature of which is positive, on the other hand a functionalized unsaturated thermoplastic stirene elastomer, the glass transition temperature of which is negative, said elastomer containing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tire, incorporating such a composite reinforcer.

Abstract translation: 通过固化成可以用作充气轮胎的增强元件的二烯橡胶基质而具有自粘性的复合增强件（R-2），包括：一个或多个增强线（20），例如碳 钢丝绳; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，一层热塑性聚合物组合物，一方面包括玻璃化转变温度为正的热塑性聚合物，另一方面包括官能化的不饱和热塑性塑料弹性体，玻璃 其转变温度为负，所述弹性体含有选自环氧化物，羧基和酸酐或酯基的官能团。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。

公开(公告)号：US20140045983A1

公开(公告)日：2014-02-13

申请号：US13981769

申请日：2012-01-31

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: C08K3/08

CPC classification number: B60C9/0042 ,  B29D30/38 ,  B29D2030/383 ,  B60C2009/0021 ,  D02G3/48 ,  D07B1/0666 ,  D07B2201/2012 ,  D07B2201/2044 ,  D07B2201/2046 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2501/2046 ,  Y10T428/2938 ,  Y10T428/2967 ,  Y10T428/2969 ,  D07B2801/16 ,  D07B2801/18

Abstract: Composite reinforcer (R-2) capable of adhering directly to a diene rubber matrix, which can be used as a reinforcing element for a pneumatic tyre, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising at least one thermoplastic polymer, the glass transition temperature of which is positive, a poly(p-phenylene ether) (PPE) and a functionalized unsaturated thermoplastic styrene (TPS) elastomer, the glass transition temperature of which is negative, said TPS elastomer bearing functional groups selected from epoxide, carboxyl and acid anhydride or ester groups. Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tyre, incorporating such a composite reinforcer.

Abstract translation: 能够直接粘附到可用作充气轮胎的增强元件的二烯橡胶基体上的复合增强件（R-2）包括：一个或多个加强丝（20），例如碳钢绳 ; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，一层热塑性聚合物组合物，其包含至少一种热塑性聚合物，其玻璃化转变温度为正，聚（对亚苯基醚）（PPE）和官能化不饱和 热塑性苯乙烯（TPS）弹性体，其玻璃化转变温度为负，所述TPS弹性体带有官能团，选自环氧化物，羧基和酸酐或酯基。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。

公开(公告)号：US20140044964A1

公开(公告)日：2014-02-13

申请号：US13981762

申请日：2012-01-31

Applicant: Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

Inventor： Vincent Abad ,  Sébastien Rigo ,  Emmanuel Custodero

IPC: C09D177/02

CPC classification number: C09D177/02 ,  B29D30/38 ,  B29D2030/383 ,  B60C9/005 ,  B60C2009/0021 ,  D02G3/48 ,  D07B1/0666 ,  D07B2201/2012 ,  D07B2201/2044 ,  D07B2201/2046 ,  D07B2205/2003 ,  D07B2205/2082 ,  D07B2501/2046 ,  Y10T428/2933 ,  Y10T428/2938 ,  D07B2801/16 ,  D07B2801/18

Abstract: Composite reinforcer (R-2) capable of adhering directly to a diene rubber matrix, which can be used as a reinforcing element for a pneumatic tyre, comprising: one or more reinforcing thread(s) (20), for example a carbon steel cord; covering said thread, individually each thread or collectively several threads, a layer of a thermoplastic polymer composition comprising at least one thermoplastic polymer, the glass transition temperature of which is positive, an unsaturated thermoplastic styrene (TPS) elastomer, the glass transition temperature of which is negative, and a poly(p-phenylene ether) (“PPE”). Process for manufacturing such a composite reinforcer and rubber article or semi-finished product, especially a pneumatic tyre, incorporating such a composite reinforcer.

Abstract translation: 能够直接粘附到可用作充气轮胎的增强元件的二烯橡胶基体上的复合增强件（R-2）包括：一个或多个增强线（20），例如碳钢绳 ; 覆盖所述螺纹，单独地每个螺纹或共同的几个螺纹，包含至少一种热塑性聚合物的热塑性聚合物组合物层，玻璃化转变温度为正的玻璃化转变温度，不饱和热塑性苯乙烯（TPS）弹性体，其玻璃化转变温度 是负的（聚对苯醚）（“PPE”）。 用于制造这种复合增强件和橡胶制品或半成品的方法，特别是包含这种复合增强件的充气轮胎。