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公开(公告)号：US11034776B2
公开(公告)日：2021-06-15
申请号：US16831904
申请日：2020-03-27
Applicant: Eastman Chemical Company
Inventor： Matthew Allen Boone , Christopher Harlan Burk , Peter Borden Mackenzie , Jennifer A. Fish , Eduardo Gallas Cervo , Elaine Beatrice Mackenzie , Robert Joseph Maleski , Wesley McConnell , David William Norman , Tabatha Stearns , Bin Wang
IPC: C08B3/16 , B32B27/24 , B32B27/08 , B32B27/36 , B32B7/12 , B32B27/28 , C08L1/14 , B32B23/08 , B32B27/32 , B32B27/18 , G02B5/30 , B32B27/22 , B32B27/06 , G02F1/13363 , H01L51/52 , C08L1/08 , C08L1/10
Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.
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2.发明授权公开(公告)号：US09861965B2
公开(公告)日：2018-01-09
申请号：US14509517
申请日：2014-10-08
Applicant: Eastman Chemical Company
Inventor： David William Norman , Greg Alan King
IPC: B01J27/199 , C07C51/353 , B01J37/03 , B01J37/08 , B01J21/06 , B01J23/00 , B01J27/198 , B01J35/00
CPC classification number: B01J27/199 , B01J21/063 , B01J23/002 , B01J27/198 , B01J35/002 , B01J37/03 , B01J37/086 , B01J2523/00 , B01J2523/13 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C51/353 , C07C57/04
Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus modified with alkali metal. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed.
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公开(公告)号：US09828322B2
公开(公告)日：2017-11-28
申请号：US15008721
申请日：2016-01-28
Applicant: EASTMAN CHEMICAL COMPANY
CPC classification number: C07C45/75 , B01J21/063 , B01J21/20 , B01J35/002 , B01J38/02 , Y02P20/584 , C07C47/22
Abstract: A commercially available anatase titania catalyst is shown to be catalytically active towards the formation of methacrolein from formaldehyde and propionaldehyde with conversions and selectivities close to 90%. This titania catalyst is readily available, non-toxic, and can be used with formaldehyde and a variety of other aldehyde compounds to make α,β-unsaturated aldehyde compounds. This process benefits from low raw material costs and is economically advantaged due to the elimination of catalyst separation. An additional advantage of this method involves the ability of the catalyst to be fully regenerated after a calcination step at 450° C. in air. This process shows promising stability and selectivity during lifetime studies, particularly when performed in the presence of a hydrogen carrier gas.
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4.发明授权Catalyst and method having selectivity to isobutyraldehyde via catalyst induction 有权通过催化剂诱导对异丁醛具有选择性的催化剂和方法公开(公告)号：US08921608B2
公开(公告)日：2014-12-30
申请号：US13837694
申请日：2013-03-15
Applicant: Eastman Chemical Company
Inventor： David William Norman , Elaine Beatrice Mackenzie
CPC classification number: C07C45/505 , B01J31/183 , B01J31/189 , B01J31/2404 , B01J31/2447 , B01J2231/321 , B01J2531/0205 , B01J2531/025 , B01J2531/0291 , B01J2531/22 , B01J2531/822 , C07C45/50 , C07C47/02
Abstract: Industrially relevant product selectivities and reaction rates are obtained from rhodium catalyzed hydroformylation of propylene via the use of a novel induction period in which the supramolecular ligand assembly, the rhodium precatalyst and an initial substrate are allowed to form a hydroformylation catalyst that is more selective toward branched aldehydes. Upon heating this incubated mixture and addition of propylene, iso-butyraldehyde is obtained in higher concentrations and rates that are otherwise unattainable.
Abstract translation: 通过使用新的诱导期，从铑催化的丙烯加氢甲酰化获得工业相关的产物选择性和反应速率，其中超分子配体组合，铑预催化剂和初始底物被允许形成对分支更具选择性的加氢甲酰化催化剂 醛。 加热该温育混合物并加入丙烯后，以更高的浓度和速率获得异丁醛，否则无法实现。
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公开(公告)号：US08809594B2
公开(公告)日：2014-08-19
申请号：US13624035
申请日：2012-09-21
Applicant: Eastman Chemical Company
Inventor： David William Norman , Damon Ray Billodeaux , Melissa Dawn Page
IPC: C07C45/45 , C07C29/141
CPC classification number: C07C29/175 , C07C45/002 , C07C45/45 , C07C45/74 , C07C51/02 , C07C47/06 , C07C47/02 , C07C47/21 , C07C31/125
Abstract: Disclosed is a process for the production of higher aldehydes from lower alcohols using a two-stage vapor phase heterogeneous catalyst system. Ethanol feeds afford aldehydes such as butyraldehyde and crotonaldehyde while butanol feeds yield 2-ethylhexanal and 2-ethylhexenal. Higher product selectivities are obtained when the alcohol is first dehydrogenated in the upper catalyst stage followed by aldol condensation of the resulting lower aldehyde to a higher aldehyde.
Abstract translation: 公开了一种使用两级气相多相催化剂体系从低级醇生产较高级醛的方法。 乙醇进料得到醛类如丁醛和巴豆醛，而丁醇进料产生2-乙基己醛和2-乙基己烯醛。 当醇在上部催化剂阶段首先被脱氢，然后将所得到的低级醛醛醛缩合成高级醛时，获得较高的产物选择性。
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Patent Agency Ranking
公开(公告)号：US11643477B2
公开(公告)日：2023-05-09
申请号：US17302463
申请日：2021-05-04
Applicant: Eastman Chemical Company
Inventor： Matthew Allen Boone , Christopher Harlan Burk , Peter Borden Mackenzie , Jennifer A. Fish , Eduardo Gallas Cervo , Elaine Beatrice Mackenzie , Robert Joseph Maleski , Wesley Wayne McConnell , David William Norman , Tabatha Stearns , Bin Wang
IPC: C08B3/16 , B32B27/24 , B32B27/08 , B32B27/36 , B32B7/12 , B32B27/28 , C08L1/14 , B32B23/08 , B32B27/32 , B32B27/18 , G02B5/30 , B32B27/22 , B32B27/06 , G02F1/13363 , H01L51/52 , C08L1/08 , C08L1/10
CPC classification number: C08B3/16 , B32B7/12 , B32B23/08 , B32B27/06 , B32B27/08 , B32B27/18 , B32B27/22 , B32B27/24 , B32B27/281 , B32B27/325 , B32B27/36 , B32B27/365 , C08L1/14 , G02B5/305 , G02B5/3033 , G02B5/3083 , G02F1/13363 , H01L51/5259 , H01L51/5281 , B32B2307/40 , B32B2307/516 , B32B2307/518 , B32B2307/546 , B32B2307/732 , B32B2309/105 , B32B2457/202 , B32B2457/206 , C08L1/08 , C08L1/10 , C09K2323/03 , C09K2323/035 , G02F1/133638 , G02F2413/13
Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.
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公开(公告)号：US20200223946A1
公开(公告)日：2020-07-16
申请号：US16831904
申请日：2020-03-27
Applicant: Eastman Chemical Company
Inventor： Matthew Allen Boone , Christopher Harlan Burk , Peter Borden Mackenzie , Jennifer A. Fish , Eduardo Gallas Cervo , Elaine Beatrice Mackenzie , Robert Joseph Maleski , Wesley McConnell , David William Norman , Tabatha Stearns , Bin Wang
IPC: C08B3/16 , B32B27/24 , B32B27/08 , B32B27/36 , B32B7/12 , B32B27/28 , C08L1/14 , B32B23/08 , B32B27/32 , B32B27/18 , G02B5/30 , B32B27/22 , B32B27/06 , G02F1/13363 , H01L51/52
Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.
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公开(公告)号：US09718754B2
公开(公告)日：2017-08-01
申请号：US15153827
申请日：2016-05-13
Applicant: Eastman Chemical Company
Inventor： Jonathan Michael Penney , David William Norman , Andrew James Vetter
CPC classification number: C07C45/49 , B01J27/128 , B01J31/0239 , B01J31/0268 , B01J31/20 , B01J2231/321 , B01J2531/821 , C07C29/32 , C07C51/12 , C07C31/08 , C07C47/06 , C07C53/08
Abstract: Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a single component catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 without additional promoters. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.
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9.发明授权Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids 有权制备用于合成2,3-不饱和羧酸的V-Ti-P催化剂的方法公开(公告)号：US09573119B2
公开(公告)日：2017-02-21
申请号：US14859751
申请日：2015-09-21
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： Liu Deng , David William Norman , Gerald Charles Tustin , Bharat Venkata Boppana , Melissa Page Steffey
IPC: C07C51/377 , B01J27/198 , B01J37/03 , B01J21/06 , B01J35/00 , C07C51/09
CPC classification number: B01J27/198 , B01J21/063 , B01J35/002 , B01J37/031 , B01J2523/00 , C07C51/09 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed. Additionally, the catalyst composition is catalytically active towards the formation of acrylic acid from methylene diacetate and methacrylic acid from methylene dipropionate; both reactions are carried out with high space time yields.
Abstract translation: 本发明涉及包含钒，钛和磷的混合氧化物的催化剂组合物。 钛组分衍生自水溶性，氧化还原活性有机钛化合物。 催化剂组合物在促进甲醛与乙酸的气相缩合以产生丙烯酸方面是非常有效的，特别是使用工业上相关的水性液体进料。 此外，催化剂组合物对于从亚甲基二乙酸酯和甲基丙烯酸由二丙酸亚丙酯形成丙烯酸具有催化活性; 两个反应均以高空时产率进行。
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公开(公告)号：US09266807B1
公开(公告)日：2016-02-23
申请号：US14586094
申请日：2014-12-30
Applicant: Eastman Chemical Company
Inventor： David William Norman , Gerald Charles Tustin , Jonathan Michael Penney , Andrew James Vetter , Venkata Bharat Ram Boppana
IPC: C07C45/49 , C07C41/56 , C07C29/16 , B01J23/22 , B01J23/44 , B01J23/80 , B01J27/128 , B01J31/22 , B01J31/24 , C07C41/50 , C07C29/34
CPC classification number: C07C45/49 , B01J21/04 , B01J21/063 , B01J23/22 , B01J23/44 , B01J23/80 , B01J27/128 , B01J31/2282 , B01J31/24 , B01J35/0006 , B01J37/0201 , B01J2531/845 , B01J2540/40 , B01J2540/50 , C07C29/16 , C07C41/50 , C07C47/02 , C07C31/12 , C07C43/303
Abstract: Processes are provided for contacting at least one Cn alcohol equivalent having n carbon atoms and at least one Cn+1 alcohol equivalent having (n+1) carbon atoms with a Guerbet catalyst to form a product composition comprising a product compound having the structure: wherein: C is a carbon atom; H is a hydrogen atom; Q is an alcohol or aldehyde group having one carbon; R is a linear alkyl group having n carbon atoms; and T is an alkyl group having (n−1) carbon atoms, except that when n=1, T is methyl.
Abstract translation: 提供了使具有n个碳原子和至少一个具有（n + 1）个碳原子的至少一个Cn + 1醇当量的至少一个Cn醇当量与格尔贝特催化剂接触以形成包含具有以下结构的产物化合物的产物组合物的方法：其中 C是碳原子; H是氢原子; Q是具有一个碳的醇或醛基; R是具有n个碳原子的直链烷基; 并且T是具有（n-1）个碳原子的烷基，除了当n = 1时，T是甲基。
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