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公开(公告)号:US20250074927A1
公开(公告)日:2025-03-06
申请号:US18809639
申请日:2024-08-20
Applicant: ENTEGRIS, INC.
Inventor: Drew Michael Hood , Thomas M. Cameron , Bryan C. Hendrix
IPC: C07F7/02 , C07F7/18 , C23C16/40 , C23C16/455
Abstract: Precursors for selective deposition of silicon-containing films are provided. A precursor comprises a compound of the formula: R(HO)Si(OR1)(OR2), where: R is or comprises an alkyl, an alkenyl, or an alkoxy; and R1 and R2 are independently a hydrogen, an alkoxyl, or R1 and R2 are bonded to form a heterocycle. Devices comprising silicon-containing films are also provided, wherein the silicon-containing film comprises a reaction product of the precursor and another reactive species. Methods of depositing silicon-containing films are also provided, among other things.
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公开(公告)号:US20230279545A1
公开(公告)日:2023-09-07
申请号:US18117183
申请日:2023-03-03
Applicant: ENTEGRIS, INC.
Inventor: Philip S. H. Chen , Shawn Duc Nguyen , Bryan C. Hendrix
IPC: C23C16/455 , H01L21/02 , C23C16/34
CPC classification number: C23C16/45553 , H01L21/0217 , H01L21/02211 , H01L21/02271 , C23C16/45536 , C23C16/345
Abstract: In summary, the invention provides a process for depositing a silicon nitride film onto a microelectronic device substrate. The process utilizes precursors and co-reactants chosen from a halosilane compound, a compound of the formula R2NH, an amino-silane, and hydrogen. The silicon nitride films so formed have increased proportions of silicon, while providing uniform thickness films, i.e., high conformality, even in high aspect 3D NAND structures.
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公开(公告)号:US20220359192A1
公开(公告)日:2022-11-10
申请号:US17726079
申请日:2022-04-21
Applicant: ENTEGRIS, INC.
Inventor: Sungsil Cho , DaHye Kim , HwanSoo Kim , SooJin Lee , Bryan C. Hendrix
IPC: H01L21/02 , C23C16/40 , C23C16/455
Abstract: Provided are certain silicon precursor compounds which are useful in the formation of silicon-containing films in the manufacture of semiconductor devices, and more specifically to compositions and methods for forming such silicon-containing films, such as films comprising silicon dioxide.
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公开(公告)号:US11371138B2
公开(公告)日:2022-06-28
申请号:US16673470
申请日:2019-11-04
Applicant: ENTEGRIS, INC.
Inventor: Philip S. H. Chen , Bryan C. Hendrix , Thomas H. Baum
Abstract: Chemical vapor deposition (CVD) processes which use a ruthenium precursor of formula R1R2Ru(0), wherein R1 is an aryl group-containing ligand, and R2 is a diene group-containing ligand and a reducing gas a described. The CVD can include oxygen after an initial deposition period using the ruthenium precursor and reducing gas. The method can provide selective Ru deposition on conductive materials while minimizing deposition on non-conductive or less conductive materials. Further, the subsequent use of oxygen can significantly improve deposition rate while minimizing or eliminating oxidative damage of the substrate material. The method can be used to form Ru-containing layers on integrated circuits and other microelectronic devices.
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公开(公告)号:US10895347B2
公开(公告)日:2021-01-19
申请号:US16162560
申请日:2018-10-17
Applicant: Entegris, Inc.
Inventor: Bryan C. Hendrix , Scott L. Battle , John N. Gregg
IPC: C23C16/448 , F17C7/04 , F28D21/00
Abstract: The invention is directed to a vaporizer or ampoule assembly with improved heat transfer between a vaporizer vessel body and at least one support tray located therein. In particular, there is provided a heat transfer enhancing member that is disposed between a vessel body and support tray. In one example of a heat transfer enhancing member or assembly there is included a heat conductive mesh or liner around totally or partially around the support tray that is wedged in between the support tray and the interior diameter or wall of the vessel body. In a related embodiment, the heat transfer enhancing member includes an expandable support tray sidewall to increase physical contact between the support tray and the vessel body interior wall.
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公开(公告)号:US10002772B2
公开(公告)日:2018-06-19
申请号:US15613773
申请日:2017-06-05
Applicant: Entegris, Inc.
Inventor: Bryan C. Hendrix
IPC: B44C1/22 , C03C15/00 , C03C25/68 , C23F1/00 , H01L21/311
CPC classification number: H01L21/31122
Abstract: A method is described for vapor phase etching of oxide material including at least one of hafnia (HfO2) and zirconia (ZrO2), in the absence of plasma exposure of the oxide material. The method involves contacting the oxide material with an etching medium including at least one of phosphorus chloride and tungsten chloride under conditions producing a removable fluid reaction product, and removing the removable fluid reaction product. The etching process may be controllably carried out by use of pressure swings, temperature swings, and/or modulation of partial pressure of Hf or Zr chloride in the reaction, e.g., to achieve precision etch removal in the manufacture of semiconductor devices such as 3D NAND, sub-20 nm DRAMs, and finFETs.
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公开(公告)号:US20170103888A1
公开(公告)日:2017-04-13
申请号:US15292760
申请日:2016-10-13
Applicant: Entegris, Inc.
Inventor: Dingkai Guo , Bryan C. Hendrix , Yuqi Li , Susan V. DiMeo , Weimin Li , William Hunks
IPC: H01L21/02 , C23C16/455 , C23C16/40
CPC classification number: H01L21/02211 , C23C16/402 , C23C16/45523 , C23C16/45534 , H01L21/02164 , H01L21/0228
Abstract: A precursor composition is described, useful for low temperature (
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公开(公告)号:US20160225615A1
公开(公告)日:2016-08-04
申请号:US15093865
申请日:2016-04-08
Applicant: Entegris, Inc.
Inventor: William Hunks , Chongying Xu , Bryan C. Hendrix , Jeffrey F. Roeder , Steven M. Bilodeau , Weimin Li
CPC classification number: H01L21/02211 , H01L21/02123 , H01L21/02164 , H01L21/02216 , H01L21/02222 , H01L21/02263 , H01L21/31604 , H01L21/31608 , H01L29/0649
Abstract: A full fill trench structure is described, including a microelectronic device substrate having a high aspect ratio trench therein and filled with silicon dioxide of a substantially void-free character and substantially uniform density throughout its bulk mass. A method of manufacturing a semiconductor product also is described, involving use of specific silicon precursor compositions for forming substantially void-free and substantially uniform density silicon dioxide material in the trench. The precursor fill composition may include silicon and germanium, to produce a microelectronic device structure including a GeO2/SiO2 trench fill material. A suppressor component may be employed in the precursor fill composition, to eliminate or minimize seam formation in the cured trench fill material.
Abstract translation: 描述了一种全填充沟槽结构,其包括其中具有高纵横比沟槽的微电子器件衬底,并填充了其整个整体质量基本上无空隙特征和基本均匀密度的二氧化硅。 还描述了制造半导体产品的方法,其涉及使用特定的硅前体组合物,用于在沟槽中形成基本上无空隙且基本均匀的密度二氧化硅材料。 前体填充组合物可以包括硅和锗,以产生包括GeO 2 / SiO 2沟槽填充材料的微电子器件结构。 可以在前体填充组合物中使用抑制剂组分,以消除或最小化固化沟槽填充材料中的接缝形成。
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公开(公告)号:US12264392B2
公开(公告)日:2025-04-01
申请号:US17356252
申请日:2021-06-23
Applicant: ENTEGRIS, INC.
Inventor: Sungsil Cho , DaHye Kim , SooJin Lee , Jae Eon Park , Bryan C. Hendrix , Philip S. H. Chen , Shawn D. Nguyen
IPC: C23C16/00 , C23C16/34 , C23C16/36 , C23C16/455 , C23C16/52
Abstract: Provided are certain silicon precursor compounds which are useful in the formation of silicon-containing films in the manufacture of semiconductor devices, and more specifically to compositions and methods for forming such silicon-containing films, such as films comprising silicon dioxide or silicon nitride.
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公开(公告)号:US12252787B2
公开(公告)日:2025-03-18
申请号:US18229077
申请日:2023-08-01
Applicant: ENTEGRIS, INC.
Inventor: Robert Wright, Jr. , Thomas H. Baum , Bryan C. Hendrix , Shawn D. Nguyen , Han Wang , Philip S. H. Chen
IPC: C23C16/455 , C23C16/18 , C23C16/56 , H01L21/02
Abstract: Described are vapor deposition methods for depositing metal films or layers onto a substrate, wherein the metal is molybdenum or tungsten; the methods involve organometallic precursor compounds that contain the metal and one or more carbon-containing ligands, and include depositing a metal layer formed from the metal of the precursor, onto a substrate, followed by introducing oxidizer to the formed metal layer.
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