摘要:
The invention concerns a process for the selective hydroisomerisation of compounds containing at least one n-alkane chain containing more than 10 carbon atoms, in which the compound to be treated is brought into contact with a catalyst comprising at least one hydro-dehydrogenating element and at least one molecular sieve with a mono- or bidimensional pore network in which the openings of the accessible pores are delimited by 10 oxygen atoms, and the distance termed the bridge width between the pores is less than 0.70 nm, and in which the catalyst, when subjected to a standard n-heptadecane isomerization test, has a selectivity of at least 70% towards isomerized products for a conversion of 95%.The sieve is preferably a NU-10, NU-23, NU-87, EU-13 or Theta-1 zeolite.
摘要:
The invention relates to a process for improving the pour point of a feedstock that comprises paraffins of more than 10 carbon atoms, in which the feedstock that is to be treated is brought into contact with a catalyst that comprises the IM-5 zeolite and at least one hydro-dehydrogenating element, at a temperature of between 170 and 500.degree. C., a pressure of between 1 and 250 bar, and an hourly volume velocity of between 0.05 and 100 h.sup.-1, in the presence of hydrogen at a ratio of 50 to 2000 l/l of feedstock. The oils that are obtained have good pour points and high viscosity indices (VI). The process can also be applied to gas-oils and other feedstocks whose pour points need to be lowered.
摘要:
The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which process the feed to be treated is brought into contact with a catalyst comprising NU-86 zeolite, preferably dealuminated, and at least one hydro-dehydrogenating element, at a temperature which is in the range 170.degree. C. to 500.degree. C., a pressure in the range 1 to 250 bar and an hourly space velocity in the range 0.05 to 100 h.sup.-1, in the presence of hydrogen in a proportion of 50 to 2000 l/l of feed. The product from heavy feeds is fractionated to produce at least one cut including at least one middle distillate with a reduced pour point, and a residue including oil bases with a reduced pour point and a high viscosity index.
摘要:
The invention concerns the use of a catalyst for the dismutation of alkylaromatic hydrocarbons, preferably for the dismutation of toluene to produce benzene and xylenes, and/or for the transalkylation of alkylaromatic hydrocarbons, preferably for the transalkylation of toluene and trimethylbenzenes to produce xylenes. The catalyst is a composite comprising at least one zeolite with structure type mazzite, at least partially in its acid form, at least one zeolite with structure type mordenite, at least partially in its acid form, at least one matrix and, optionally, at least one element selected from the group formed by groups IB and VIII of the periodic classification of the elements.
摘要:
The invention concerns a composition comprising at least one matrix, at least one faujasite type zeolite and at least one TON type zeolite. The TON type zeolite can be Nu-10, THETA-1, KZ-2, or ISI-1. The catalyst also contains at least one hydrogenating element from groups VIII and VI. The catalyst is particularly for use for hydrocracking to maximize the yield of middle distillates (kerosine and gas oil).
摘要:
For the at least partial separation of aliphatic paraffins into at least one effluent comprising the least branched paraffins and at least one effluent comprising the most branched paraffins, use is made of at least one adsorbent bed comprising at least one grafted microporous solid. A preferred use of the invention relates to the treatment of a charge obtained from an isomerization zone, whereby at least one adsorbent bed makes it possible to separate the charge into a first effluent comprising the normal paraffins and a second effluent, and at least one adsorbent bed on which passes the second effluent, comprising at least one grafted microporous solid, making it possible to obtain a third effluent comprising the monomethyl branched paraffins and a fourth effluent comprising the polymethyl branched paraffins.
摘要:
A process for preparation of synthetic crude from a deposit of heavy crude, comprises: (a) the extraction of heavy crude by technology using steam; (b) the separation of crude extract and water; (c) the separation of crude into at least one light fraction and one heavy fraction; (d) the conversion of the heavy fraction of separation into a lighter product, said converted product, and a residue; (e) optionally, the partial or total hydrotreatment of the converted product and/or the light fraction (or fractions) obtained during the separation c), (f) the combustion and/or gasification of the conversion residue; the converted product and the light fraction (or fractions) for separation, optionally having been subjected to a hydrotreatment e), constituting the synthetic crude; said combustion allowing the generation of steam and/or electricity and said gasification allowing the generation of hydrogen; the steam and/or electricity thus generated being used for the extraction a) and/or the electricity and/or hydrogen thus generated being used for the conversion d) and/or the hydrotreatment e).
摘要:
A hydrocracking catalyst containing at least one matrix, at least one zeolite chosen from the group formed by the zeolites ZBM-30, ZSM-48, EU-2, and EU-11, at least one Y zeolite, at least one hydro-dehydrogenating metal chosen from the group formed by the metals from Group VIB and Group VIII of the periodic table, optionally at least one element chosen from the group formed by phosphorus, boron and silicon, optionally at least one element from Group VIIA, and optionally at least one element from Group VIIB is used in a process of hydrocracking/hydroconversion of hydrocarbon charges.
摘要:
The invention concerns a process for producing middle distillates from an effluent produced by a Fischer-Tropsch unit, comprising optional fractionation to obtain at least one heavy fraction with an initial boiling point in the range 120-200° C., said heavy fraction or said effluent optionally being hydrotreated, then bringing it into contact with a first amorphous hydrocracking/hydroisomerization catalyst that contains at least one noble group VIII metal, the effluent obtained is distilled, then the residual fraction boiling above the middle distillates and/or a portion of the middle distillates is brought into contact with a second amorphous hydrocracking/hydroisomerization catalyst containing at least one noble group VIII metal. The invention also concerns a unit.
摘要:
An improved hydrocracking process of hydrocarbon charges, in two stages with an intermediate separation, in which the second-stage of hydrocracking is carried out in the presence of an added nitrogen content which is greater than 150 ppm by weight, preferably about 500 ppm by weight, and preferably in the presence of a Y zeolite catalyst, produces high yields of middle distillate.