摘要:
A method for producing a metal film composed of an alloy having more than 50% nickel (a) melts the alloy in amounts of more than one ton in a vacuum induction furnace, or openly in an induction or arc furnace, followed by treatment in a VOD or VLF installation, (b) the alloy is cast into blocks, electrodes or as continuous casting to form a pre-product, (c) the pre-product is annealed if necessary at temperatures between 800° C.-1350° C. for 1-300 hours under air or protective gas, and (d) hot rolled between 1300° C.-600° C. to reduce the thickness of the starting material by a factor of 1.5-200, such that the pre-product has a thickness of 1-100 mm after the rolling and is not recrystallized, recovered, and/or is (dynamically) recrystallized having a grain size less than 300 μm, (e) the pre-product is pickled, (f) then cold worked to produce a film with a degree of deformation greater than 90% to a final thickness of 10-600 μm, (g) the film is cut into strips of 5-300 mm after the cold working, (h) the film strips are coated with a ceramic powder loosely or by an adhesive or by an oxide dissolved in alcohol or covered with a separating film and, if necessary, dried, (i) the film strips are wound annularly onto one or more mandrels or one or more sleeves, wherein the inner and the outer end are each spot-welded or clamped, (j) the annularly wound film strips are annealed under protective gas at temperatures between 600° C.-1200° C. for 1 min to 300 h, (k) wherein the annealed film-like material is recrystallized after the annealing and has a large proportion of cubic texture.
摘要:
A tape-shaped superconducting film-forming substrate is disclosed, which includes a film-forming face for forming a laminate including a superconducting layer thereon, a rear face that is a face at a side opposite to the film-forming face, a pair of end faces connected to the film-forming face and the rear face, and a pair of side faces connected to the film-forming face, the rear face, and the pair of end faces, in which each of the pair of side faces includes a spreading face that spreads toward an outer side in an in-plane direction of the film-forming face from an edge part of the film-forming face toward the rear face side. A superconducting wire and a superconducting wire manufacturing method are also disclosed.
摘要:
A method for manufacturing a superconducting wire includes the following steps. A laminate metal having a first metal layer and a Ni layer formed on the first metal layer is prepared. An intermediate layer (20) is formed on the Ni layer of the laminate metal. A superconducting layer (30) is formed on the intermediate layer (20). By subjecting the laminate metal to a heat treatment after at least either of the step of forming a intermediate layer (20) and the step of forming a superconducting layer (30), a nonmagnetic Ni alloy layer (12) is formed from the laminate metal.
摘要:
A metal laminated substrate for an oxide superconducting wire is produced by removing, in a state where a copper foil to which rolling is applied at a draft of 90% or more is held at a temperature below a recrystallization temperature, an absorbed material on a surface of the copper foil by applying sputter etching to the surface of the copper foil; removing an absorbed material on a surface of a nonmagnetic metal sheet by applying sputter etching to the surface of the nonmagnetic metal sheet; bonding the copper foil and the metal sheet to each other by reduction rolls at an applied pressure of 300 MPa to 1500 MPa; orienting crystals of the copper by heating a laminated body obtained by bonding at a crystal orientation temperature of copper or above; and forming a protective layer on a copper-side surface of the laminated body by coating.
摘要:
The films of this invention are high temperature superconducting (HTS) thin films specifically optimized for microwave and RF applications. In particular, this invention focuses on compositions with a significant deviation from the 1:2:3 stoichiometry in order to create the films optimized for microwave/RF applications. The RF/microwave HTS applications require the HTS thin films to have superior microwave properties, specifically low surface resistance, Rs, and highly linear surface reactance, Xs, i.e. high JIMD. As such, the invention is characterized in terms of its physical composition, surface morphology, superconducting properties, and performance characteristics of microwave circuits made from these films.
摘要:
An article includes a substrate having a surface and a nanofence supported by the surface. The nanofence includes a multiplicity of primary nanorods and branch nanorods, each of the primary nanorods being attached to said substrate, and each of the branch nanorods being attached to a primary nanorods and/or another branch nanorod. The primary and branch nanorods are arranged in a three-dimensional, interconnected, interpenetrating, grid-like network defining interstices within the nanofence. The article further includes an enveloping layer supported by the nanofence, disposed in the interstices, and forming a coating on the primary and branch nanorods. The enveloping layer has a different composition from that of the nanofence and includes a radial p-n single junction solar cell photovoltaic material and/or a radial p-n multiple junction solar cell photovoltaic material.
摘要:
A method of forming a composite sheet includes disposing an untextured metal or alloy first sheet in contact with a second sheet in an aligned opposing position; bonding the first sheet to the second sheet by applying an oscillating ultrasonic force to at least one of the first sheet and the second sheet to form an untextured intermediate composite sheet; and annealing the untextured intermediate composite sheet at a temperature lower than a primary re-crystallization temperature of the second sheet and higher than a primary re-crystallization temperature of the first sheet to convert the untextured first sheet into a cube textured sheet, wherein the cube texture is characterized by a φ-scan having a FWHM of no more than 15° in all directions, the second sheet remaining untextured, to form a composite sheet.
摘要:
Provided are a substrate for a superconducting compound and a method for manufacturing the substrate which can realize the excellent adhesive strength simultaneously with high orientation of copper. An absorbed material on a surface of a copper foil to which rolling is applied at a draft of 90% or more is removed by applying sputter etching to the surface of the copper foil, sputter etching is applied to a nonmagnetic metal sheet, the copper foil and the metal sheet are bonded to each other by applying a pressure to the copper foil and the metal sheet using reduction rolls, crystals of the copper in the copper foil are oriented by heating a laminated body formed by such bonding, copper is diffused into the metal sheet by heating with a copper diffusion distance of lOnm or more, and a protective layer is laminated to a surface of the copper foil of the laminated body.
摘要:
The present invention relates to a superconducting film having a substrate and a superconductor layer formed on the substrate, in which nano grooves are formed parallel to a current flowing direction on a substrate surface on which the superconductor layer is formed and two-dimensional crystal defects are introduced in the superconductor layer on the nano grooves, and a method of manufacturing this superconducting film. A superconducting film of the invention, which is obtained at low cost and has very high Jc, is useful in applications such as cables, magnets, shields, current limiters, microwave devices, and semifinished products of these articles.
摘要:
A tape-type superconductor (1), comprising an elongated substrate (2), in particular a metal tape, and a continuous superconducting layer (3), in particular of a HTS type material, deposited on the substrate (2), is characterized in that Ic∥/Ic⊥≧1.5, with Ic∥ being the width density of critical current of the continuous superconducting layer (3) in parallel to the substrate (2) and in parallel to the elongated direction of the substrate (2), and with Ic⊥ being the width density of critical current of the continuous superconducting layer (3) in parallel to the substrate (2) and perpendicular to the elongated direction of the substrate (2). The tape-type superconductor has reduced ac losses.