Abstract:
1,189,848. Organic metal-hydroxylamino compounds. STAUFFER CHEMICAL CO. 4 July, 1967 [5 July, 1966], No. 30732/67. Heading C2C. Novel compounds of formula in which X is halo or alkoxy; M is a metal from groups I-IV of the Periodic Table; R is alkyl, alkenyl or aryl; y is 1-4; n is 0 when M has a valency of 1, 0 or 1 when M has a valency of 2, 0-2 when M has a valency of 3 and 0-3 when M has a valency of 4 are prepared by reacting an appropriate metal halide or alkoxide with the requisite N,N-disubstituted hydroxylamine.
Abstract:
1,135,261. Metal organoorthophosphates; organometallic compounds. CITIES SERVICE OIL CO. 5 Jan., 1966, No. 542/66. Headings C2C and C2J. [Also in Division C5] Metal organo orthophosphates including compounds having metal-carbon bonds are prepared by contacting, in an inert organic solvent, (a) phosphorus pentoxide, and (b) a polyvalent metal halide, which may contain organic groups, with (c) an organic hydroxyl compound having from 1 to 30 carbon atoms at a temperature of between 10‹ and 120‹ C. The products suitably have one of the following general formulµ where M is a polyvalent metal suitably of Groups II, IV, VI and VIII, and R is a hydrocarbon group of 1 to 30 atoms. Products having a free hydroxy group may be neutralized with an amine. In the examples the following reactants and products are described: (1) P 2 O 5 , TiCl 4 and C 8 H 17 OH to give [(C 8 H 17 O) 2 OPO] 2 Ti[OPO(OH)(OC 8 H 17 )] 2 (2) P 2 O 5 , ZrC1 4 , C 8 H 17 OH and CH 3 OH to give [(C8H 17 O)(CH 3 O)OPO] 2 Zr[OPO(OH)(OC 8 H 17 )] 2 (3) P 2 O 5 , NiC1 2 and C 8 H 17 OH to give [(C 8 H 17 O) 2 OPO]Ni[OPO(OH)(OC 8 H 17 )] (4) P 2 O 5 , SnCl 4 , ocyl phenol and iso-butyl alcohol, to give [(RO) 2 OPO] 2 Sn[OPO(OR)(OH)] 2 where 2 of the Rs are isobutyl and 4 of the Rs are octyl-phenyl groups, (5) P 2 O 5 , [C 6 H 5 CH 2 ] 2 SnCl 2 and isopropyl alcohol to give (6) as in (1), but replacing 2-ethylhexanol (C 8 H 17 OH) with phenol, benzylalcohol or cyolohexanol. The orthophosphates are useful as additives in fuels and lubricants.