Abstract:
Methods are provided to make acid functional fluoropolymers by: a) dehydrofluorinating a starting fluoropolymer with a dehydrofluorinating agent to form an unsaturated fluoropolymer; b) adding an acidifiable nucleophilic functionalizing agent to a double bond of the unsaturated fluoropolymer; and c) acidifying the added acidifiable function. Acid functional fluoropolymers and ion conducting membranes thereof are also provided, including acid functional fluoropolymer having pendent groups according to the formula: —X—Ar—An, wherein X is selected from O, S or NR, where R is selected from H and C1-C30 alkyl or aryl, which are optionally substituted, wherein Ar is a C6-C30 aromatic group, which is optionally substituted, wherein A is an acidic function or salt thereof, wherein a can be independently chosen to be 1, 2 or 3.
Abstract:
A coating composition is described comprising:(i) a zwitterionic compound comprising sulfonate-functional groups and alkoxysilane groups and/or silanol-functional groups; (ii) alcohol and/or water; and (iii) a tetraalkoxysilane, oligomers thereof, lithium silicate, sodium silicate, potassium silicate, silica, or combinations thereof, along with coated articles and methods of making and using.
Abstract:
A method of making a coatable composition includes: providing a first composition comprising silica nanoparticles dispersed in an aqueous liquid vehicle, wherein the silica nanoparticles have an average particle size of less than or equal to 100 nanometers, wherein the first composition has a pH greater than 6; acidifying the first composition to a pH of less than or equal to 4 using inorganic acid to provide a second composition; and dissolving at least one metal compound in the second composition to form the coatable composition, wherein said at least one metal compound comprises a titanium compound. Coatable compositions and photocatalytic compositions, preparable by the method, are also disclosed. Photocatalytic articles including the photocatalytic compositions are also disclosed.
Abstract:
Described herein is a method of coagulating a fluoropolymer latex comprising: providing an amorphous fluoropolymer latex; providing unmodified inorganic nanoparticles; contacting the amorphous fluoropolymer latex with a sufficient amount of unmodified inorganic nanoparticles to coagulate the amorphous fluoropolymer.
Abstract:
The disclosure provides polymers having antimicrobial activity and articles with the polymers coated thereon. The polymers include a first pendant group comprising a first cationic component, a second pendant group comprising a nonpolar component, and a third pendant group comprising an organosilane component. The disclosure also includes methods of coating medical device articles and body fluid-receiving substrates with the antimicrobial polymers. The methods further include the use of adhesion-promoting components.
Abstract:
Functionalized solid support material with biomolecule-binding groups and uses thereof, wherein the biomolecule-binding groups include a plurality of aromatic groups, an amine group which bonds to a biomolecule through an aldehyde group, a hydrazine group which bonds to a biomolecule through an aldehyde group, or an alpha,beta-ethylenically or acetylenically unsaturated group with an electron withdrawing group.
Abstract:
Described herein is a method of coagulating a fluoropolymer latex comprising: providing an amorphous fluoropolymer latex; providing unmodified inorganic nanoparticles; contacting the amorphous fluoropolymer latex with a sufficient amount of unmodified inorganic nanoparticles to coagulate the amorphous fluoropolymer.
Abstract:
Methods and devices for evaluating the quality of oils are disclosed. The methods and devices can provide an indication of the oil quality based on the Total Polar Content of the oil. The methods rely on a reusable capacitive sensing element that comprises a fluorinated barrier coating, as disclosed herein.
Abstract:
Provided are compositions comprising a) a fluoroplastic; b) an aromatic material having exactly one hydroxyl group, wherein the aromatic material is free of thiol groups, and wherein the hydroxyl group is bonded to an aromatic carbon; c) a salt former compound capable of forming a salt with the aromatic material; and d) optionally a phase transfer catalyst. Also provided are reaction products of the described compositions, multi-layer articles comprising the compositions and reaction products, and methods for making the compositions, reaction products, and articles.