公开(公告)号：US08735513B2

公开(公告)日：2014-05-27

申请号：US13505852

申请日：2010-11-05

Applicant: Takanori Nakashima ,  Katsuhiko Oono ,  Kenji Mitsutani ,  Takao Tayano ,  Tomoyuki Yoshida ,  Shigeo Mizukami ,  Yusuke Yamada

Inventor： Takanori Nakashima ,  Katsuhiko Oono ,  Kenji Mitsutani ,  Takao Tayano ,  Tomoyuki Yoshida ,  Shigeo Mizukami ,  Yusuke Yamada

IPC: C08F2/00 ,  C08F210/00 ,  C08F110/06 ,  B01J19/18

CPC classification number: C08F10/06 ,  B01J8/003 ,  B01J8/1827 ,  B01J8/20 ,  B01J8/382 ,  B01J19/18 ,  B01J2208/00247 ,  B01J2208/00274 ,  B01J2219/00033 ,  B01J2219/0004 ,  B01J2219/182 ,  C08F110/06 ,  C08F210/06 ,  C08F2/001 ,  C08F2/01 ,  C08F4/6492 ,  C08F2/34 ,  C08F4/6548 ,  C08F2500/12 ,  C08F210/16

Abstract: A propylene polymerization reaction apparatus and a production method of a propylene-based polymer are capable of producing a continuous multi-stage polymer in low cost, high productivity and stably, and significantly reducing generation amount of an off-specification product accompanying change of polymerization condition, in multi-stage continuous vapor phase polymerization method of a propylene-based polymer using a catalyst for olefin polymerization. A reaction apparatus for producing a propylene-based polymer by a multi-stage continuous vapor phase polymerization method is used. One or more reactor of a horizontal-type reactor having inside a stirring machine which rotates around a horizontal axis, and a continuous stirred tank reactor to be connected to the horizontal-type reactor are provided, and a production method of a propylene-based polymer using the same.

Abstract translation: 丙烯聚合反应装置和丙烯类聚合物的制造方法能够以低成本，高生产率和稳定地制造连续多级聚合物，并且随着聚合条件的变化显着降低脱离规格产品的产生量 在使用烯烃聚合催化剂的丙烯类聚合物的多阶段连续气相聚合法中。 使用通过多级连续气相聚合法制造丙烯类聚合物的反应装置。 提供了一个或多个卧式反应器的反应器，该反应器具有围绕水平轴线旋转的搅拌机内部，以及连接到卧式反应器的连续搅拌釜式反应器，并提供了一种丙烯类聚合物 使用相同

公开(公告)号：US08658750B2

公开(公告)日：2014-02-25

申请号：US13577449

申请日：2010-03-09

Applicant: James R. Lattner ,  Michael W. Weber ,  Jimmy L. Tardy ,  Howard G. Large ,  Peter N. Loezos ,  Randy L. Foster ,  Jason D. Davis

Inventor： James R. Lattner ,  Michael W. Weber ,  Jimmy L. Tardy ,  Howard G. Large ,  Peter N. Loezos ,  Randy L. Foster ,  Jason D. Davis

IPC: C07C7/10 ,  C07C2/30 ,  C07C2/02 ,  C08F110/02 ,  C07C2/26 ,  C07C7/00 ,  B01J21/00

CPC classification number: C07C7/10 ,  B01J8/005 ,  B01J8/382 ,  B01J19/0066 ,  B01J19/18 ,  B01J2219/00006 ,  B01J2219/00094 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/30 ,  C07C7/05 ,  C07C2531/14 ,  C07C2531/34 ,  C07C11/107

Abstract: Disclosed herein is a method for separating from the reactor effluent of an olefin oligomerization procedure those catalyst materials and polymeric by-products which can cause difficulties in the downstream processing of such effluent. Polymer by-products and catalyst in the effluent are separated from reaction products by flash vaporization utilizing an in-situ hot solvent which is contacted with the effluent and serves as the heating medium to promote this flash vaporization step. Subsequent processing of a liquid portion of the effluent which is left after flash vaporization involves recovery of catalyst and polymeric by-products therefrom in a steam stripping vessel. Also disclosed is a multiple reactor system which can be used for continuous trimerization of ethylene to 1-hexene while at the same time washing polymeric by-products from one of the reactors in the series using a wash oil solvent.

Abstract translation: 本文公开了一种从烯烃低聚方法的反应器流出物中分离出可能在下游处理这些流出物中引起困难的那些催化剂材料和聚合副产物的方法。 流出物中的聚合物副产物和催化剂通过使用与流出物接触的原位热溶剂通过闪蒸蒸发与反应产物分离，并用作加热介质以促进该闪蒸步骤。 在闪蒸后残留的流出物的液体部分的后续处理涉及在蒸汽汽提容器中从其中回收催化剂和聚合副产物。 还公开了一种多反应器系统，其可用于将乙烯连续三聚至1-己烯，同时使用洗涤油溶剂从串联的反应器之一洗涤聚合物副产物。

公开(公告)号：US08536234B2

公开(公告)日：2013-09-17

申请号：US12897584

申请日：2010-10-04

Applicant: Valerii Kukhar ,  Valeriy Bortyshevskyy ,  Nataliia Khimach ,  Viktor Burdeynyy ,  Rayisa Korzh ,  Svitlana Melnykova ,  Dmytro Kamens'kyh

Inventor： Valerii Kukhar ,  Valeriy Bortyshevskyy ,  Nataliia Khimach ,  Viktor Burdeynyy ,  Rayisa Korzh ,  Svitlana Melnykova ,  Dmytro Kamens'kyh

IPC: C07C27/00

CPC classification number: B01J8/0005 ,  B01J8/0045 ,  B01J8/20 ,  B01J8/26 ,  B01J8/382 ,  B01J8/386 ,  B01J8/42 ,  B01J2219/00006 ,  B01J2219/0004 ,  B01J2219/00103 ,  C10L1/02 ,  C10L9/086

Abstract: A method and apparatus for the generation of synthetic motor fuels and additives to oil fuels, C1-C4 alcohols, hydrogen, methane, synthesized gas (H2+CO2) by hydrothermal treatment of carbonaceous compounds by providing a two-stage carbon gasification process operated under the supercritical conditions of H2O and CO2, including a first stage gasification reactor having a reaction zone for the conversion of carbonaceous compounds and a second stage reactor for the conversion of the products of the first stage reactor; feeding a aqueous suspension of carbonaceous compound in an amount of at least 30% by weight and an alkali metal or alkaline-earth metal catalyst or reactive OH-species from an electrolyzer through said first stage gasification reactor as a supercritical fluid at a volume velocity of 0.01-0.05 g of carbon per 1 cm3 per hour, at a carbon/catalyst mole ratio of between about 70/1 and 90/1, at a temperature of 390-450° C., and under a pressure of about 225 to 500 bars; feeding the reaction products from the first stage reactor to the second stage reactor over a copper-zinc catalyst at the temperature of 200-280° C. and under a pressure of at least about 100 bars so that any gases generated in the first stage are converted into C1-C4 alcohols with the weight ratio of C1-C2 to C3-C4 between about 0-35% to 100-65%.

Abstract translation: 一种通过提供在二氧化碳气化过程中运行的碳酸化合物的水热处理来生成合成汽油燃料和添加剂的方法和装置，用于生产油燃料，C 1 -C 4醇，氢气，甲烷，合成气体（H 2 + CO 2） H 2 O和CO 2的超临界条件，包括具有用于转化碳质化合物的反应区的第一级气化反应器和用于转化第一级反应器产物的第二级反应器; 将至少30重量％的含碳化合物的水悬浮液和来自电解槽的碱金属或碱土金属催化剂或反应性OH-物质作为超临界流体通过所述第一级气化反应器以体积速度 0.01-0.05g碳/ 1cm 3 /小时，碳/催化剂摩尔比为约70/1至90/1之间，温度为390-450℃，压力为约225至500 酒吧 在200-280℃的温度和至少约100巴的压力下通过铜 - 锌催化剂将反应产物从第一阶段反应器进料到第二阶段反应器，使得在第一阶段中产生的任何气体为 转化为C 1 -C 4醇，其中C 1 -C 2至C 3 -C 4的重量比在约0-35％至100-65％之间。

公开(公告)号：US08496898B2

公开(公告)日：2013-07-30

申请号：US13023569

申请日：2011-02-09

Applicant: Michael John Mooney

Inventor： Michael John Mooney

IPC: B01D53/12 ,  B01D53/62 ,  B01J8/18

CPC classification number: B01J8/1818 ,  B01D53/508 ,  B01D53/62 ,  B01D53/83 ,  B01D2251/404 ,  B01D2257/504 ,  B01J8/003 ,  B01J8/006 ,  B01J8/1809 ,  B01J8/1827 ,  B01J8/24 ,  B01J8/382 ,  B01J2208/0061 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/08

Abstract: A pneumatic conveying system for conveying hydrated lime is provided with ambient air for the pneumatic conveying system from a scrubber that removes carbon dioxide from the ambient air used in the conveying system. The scrubber includes a bed of hydrated lime through which ambient air is passed, to react carbon dioxide in the air with the hydrated lime in a reaction that forms limestone and water. The air that has passed through the fluidized bed, which is essentially carbon dioxide free, is also passed through a filter to remove particles suspended in the carbon dioxide free air. The carbon dioxide free air from the filter is provided to the pneumatic conveying system. The use of carbon dioxide free air ensures that the hydrated lime being transported in the conveying system will not react in the various conduits and ducts of the pneumatic conveying system to cause problems.

Abstract translation: 用于输送熟石灰的气动输送系统设置有用于气动输送系统的环境空气，该洗涤器将二氧化碳从用于输送系统的环境空气中除去。 洗涤器包括一个熟石灰床，环境空气通过该床通过，使空气中的二氧化碳与形成石灰石和水的反应中的熟石灰反应。 通过基本上不含二氧化碳的流化床的空气也通过过滤器以除去悬浮在无二氧化碳空气中的颗粒。 来自过滤器的无二氧化碳的空气被提供给气动输送系统。 使用无二氧化碳的空气确保在输送系统中输送的熟石灰不会在气动输送系统的各种管道和管道中发生反应，从而引起问题。

公开(公告)号：US08383740B1

公开(公告)日：2013-02-26

申请号：US13136865

申请日：2011-08-12

Applicant: Dirk Poesen

Inventor： Dirk Poesen

IPC: C08F2/00 ,  C08F210/00 ,  B01J10/00

CPC classification number: B01J8/382 ,  B01F7/18 ,  B01F15/00545 ,  B01J19/18 ,  C08F10/00 ,  C08F4/6592

Abstract: The invention is an improved apparatus for continuously stirring polymer particles in reactive gas-filled polymerization reactors incorporating contiguous paddle stations on a coaxial drive shaft wherein the drive shaft is driven by a hydraulic motor.

公开(公告)号：US20130041118A1

公开(公告)日：2013-02-14

申请号：US13136865

申请日：2011-08-12

Applicant: Dirk Poesen

Inventor： Dirk Poesen

IPC: C08F2/01 ,  B01J19/18

CPC classification number: B01J8/382 ,  B01F7/18 ,  B01F15/00545 ,  B01J19/18 ,  C08F10/00 ,  C08F4/6592

Abstract: The invention is an improved apparatus for continuously stirring polymer particles in reactive gas-filled polymerization reactors incorporating contiguous paddle stations on a coaxial drive shaft wherein the drive shaft is driven by a hydraulic motor.

Abstract translation: 本发明是一种改进的装置，用于在同轴驱动轴上连续搅拌聚合物颗粒的反应性气体填充聚合反应器中，其中驱动轴由液压马达驱动。

公开(公告)号：US20130035271A1

公开(公告)日：2013-02-07

申请号：US13519987

申请日：2010-12-30

Applicant: Peter Daute ,  Wilhelm Reiners ,  Martin Schäfer ,  Udo Frerichs ,  Hinrich Hildebrandt ,  Joern Ellerbrake

Inventor： Peter Daute ,  Wilhelm Reiners ,  Martin Schäfer ,  Udo Frerichs ,  Hinrich Hildebrandt ,  Joern Ellerbrake

IPC: C07C67/08 ,  C09K3/22 ,  C09K8/32 ,  C09K3/00 ,  C07C69/602 ,  C10M105/38

CPC classification number: B01J8/006 ,  B01J8/1836 ,  B01J8/20 ,  B01J8/382 ,  B01J2208/00176 ,  B01J2208/00212 ,  B01J2208/00247 ,  B01J2208/00283 ,  B01J2208/0084 ,  B01J2208/00867 ,  B01J2208/025 ,  C07C67/08 ,  C07C69/58

Abstract: The present invention relates to a process for the preparation of an ester from a polyol which is solid at 25° C. and a carboxylic acid component which contains at least 50 wt. % of at least one mono- or polyunsaturated aliphatic carboxylic acid, based on the total weight of the carboxylic acid component, in a reactor under reduced pressure. The invention also provides a device, a process for the preparation of a thermoplastic composition comprising the ester prepared according to the invention, a process for the production of a shaped article comprising the ester according to the invention or the thermoplastic composition according to the invention, a process for the production of a packed product, a process for the production of an at least partly coated object, and uses of the esters according to the invention as an additive in various compositions.

Abstract translation: 本发明涉及一种由25℃下为固体的多元醇制备酯的方法和含有至少50wt。％的羧酸组分的方法。 ％的至少一种单或多不饱和脂肪族羧酸，基于羧酸组分的总重量，在减压下在反应器中。 本发明还提供了一种装置，一种制备包含根据本发明制备的酯的热塑性组合物的方法，一种生产包含根据本发明的酯或根据本发明的热塑性组合物的成型制品的方法， 用于生产包装产品的方法，用于生产至少部分涂覆的物体的方法，以及根据本发明的酯作为各种组合物中的添加剂的用途。

公开(公告)号：US08241584B2

公开(公告)日：2012-08-14

申请号：US12738426

申请日：2008-10-20

Applicant: Tatsuo Kitamura ,  Yoshihide Kitamura ,  Itsushi Kashimoto

Inventor： Tatsuo Kitamura ,  Yoshihide Kitamura ,  Itsushi Kashimoto

IPC: B01J19/18 ,  B01J19/00 ,  B01J8/00 ,  B01J8/08 ,  B01J8/18 ,  B01J8/02 ,  B01J35/02 ,  B01J29/70 ,  F27B15/00 ,  F27B15/08

CPC classification number: B09B3/0075 ,  B01J8/10 ,  B01J8/12 ,  B01J8/16 ,  B01J8/382 ,  B01J8/388 ,  B01J2208/00814 ,  B29B17/02 ,  B29B17/04 ,  B29B2017/0268 ,  B29B2017/0293 ,  B29K2027/06 ,  B29K2027/18 ,  B29K2105/0035 ,  B29L2031/753 ,  C08J11/16 ,  C10G1/10 ,  C10G2300/1003 ,  C10G2300/1011 ,  Y02P30/20 ,  Y02W30/622 ,  Y02W30/625 ,  Y02W30/705

Abstract: A decomposition apparatus and a decomposition system for high-efficiency decomposition of waste plastic and organic matter, in particular medical waste formed of varieties of plastic, are provided by introduction of a catalyst circulating means using a rotary wheel and/or introduction of a mixing vessel.

Abstract translation: 通过使用旋转轮引入催化剂循环装置和/或引入混合容器来提供废塑料和有机物，特别是由各种塑料形成的医疗废物进行高效分解的分解装置和分解系统 。

公开(公告)号：US08226895B2

公开(公告)日：2012-07-24

申请号：US12289209

申请日：2008-10-22

Applicant: Chikara Inaba

Inventor： Chikara Inaba

IPC: B01J8/24 ,  B01J8/34 ,  B01J8/38 ,  C01B33/107

CPC classification number: C01B33/10736 ,  B01J8/1827 ,  B01J8/34 ,  B01J8/382 ,  B01J19/30 ,  B01J2208/00867 ,  B01J2219/30207 ,  B01J2219/30215 ,  B01J2219/30408 ,  B01J2219/312

Abstract: A reaction apparatus for producing trichlorosilane in which metal silicon powder M is reacted with hydrogen chloride gas, thus generating trichlorosilane, includes: an apparatus body into which the metal silicon powder is supplied; and an ejection port for ejecting the hydrogen chloride gas into the apparatus body from the bottom part of the apparatus body, wherein a plurality of holed pieces having a through hole penetrating in the thickness direction and a plurality of pellets interposed between these holed pieces are stacked in a mixed state on the upper side of the ejection port.

Abstract translation: 一种制造三氯硅烷的反应装置，其中金属硅粉末M与氯化氢气体反应，从而产生三氯硅烷，包括：提供金属硅粉末的装置体; 以及用于从装置主体的底部将氯化氢气体喷射到装置主体中的排出口，其中多个具有沿厚度方向贯穿的通孔的孔和多个在这些孔之间插入的颗粒被堆叠 在喷射口的上侧处于混合状态。

公开(公告)号：US08048192B2

公开(公告)日：2011-11-01

申请号：US11320707

申请日：2005-12-30

Applicant: Thomas Pompilio Diaz ,  Samson Hettiarachchi ,  Peter Louis Andresen ,  Young Jin Kim

Inventor： Thomas Pompilio Diaz ,  Samson Hettiarachchi ,  Peter Louis Andresen ,  Young Jin Kim

IPC: B22F1/00

CPC classification number: B01J23/42 ,  B01J8/20 ,  B01J8/382 ,  B01J8/388 ,  B01J19/0086 ,  B01J35/0013 ,  B01J37/0221 ,  B01J37/033 ,  B01J37/342 ,  B01J2208/00212 ,  B01J2208/003 ,  B22F1/0018 ,  B22F9/30 ,  B22F2998/00 ,  B82Y30/00 ,  Y10S977/773 ,  B22F1/0022 ,  B22F2203/11 ,  B22F2203/13 ,  B22F1/0014

Abstract: Provided are methods and systems for generating nanoparticles from an inorganic precursor compound using a hydrothermal process within at least one CSTR or PFR maintained at an elevated temperature and an elevated pressure and a treatment vessel in which this reaction solution can be applied to one or more catalyst substrates. In operation, the reaction solution may be maintained within the CSTR at a substantially constant concentration and within a reaction temperature range for a reaction period sufficient to obtain nanoparticles having a desired average particle size of, for example, less than 10 nm formation and/or deposition. Variations of the basic method and system can provide, for example, the generation of complex particle size distribution profiles, the selective deposition of a multi-modal particle size distribution on a single substrate.

Abstract translation: 提供了使用在保持在升高的温度和升高的压力下的至少一个CSTR或PFR中的水热法从无机前体化合物产生纳米颗粒的方法和系统，以及处理容器，其中该反应溶液可以应用于一种或多种催化剂 底物。 在操作中，反应溶液可以以基本上恒定的浓度保持在CSTR内并且在反应温度范围内，反应时间足以获得具有例如小于10nm形成的所需平均粒度的纳米颗粒和/或 沉积 基本方法和系统的变化可以提供例如复合粒度分布曲线的产生，在单个基底上选择性沉积多模态粒度分布。