Fabrication of magnetic nanoparticles
    16.
    发明授权
    Fabrication of magnetic nanoparticles 有权
    磁性纳米粒子的制备

    公开(公告)号:US09504256B2

    公开(公告)日:2016-11-29

    申请号:US14489587

    申请日:2014-09-18

    CPC classification number: A01N59/16 A01N25/26 A01N43/90 A01N63/04

    Abstract: Methods for forming core-shell magnetic nanoparticles are provided. The method can include: forming an oxide shell around a metal oxide core to form a core-shell magnetic nanoparticle; attaching an anchoring agent to the magnetic nanoparticle; reacting a RAFT agent with the functional group of the anchoring agent such that the RAFT agent is bonded to the magnetic nanoparticle through the anchoring agent; and attaching a polymeric chain to the RAFT agent.

    Abstract translation: 提供了形成核 - 壳磁性纳米颗粒的方法。 该方法可以包括:在金属氧化物核周围形成氧化物壳以形成核 - 壳磁性纳米颗粒; 将锚固剂附着到磁性纳米颗粒上; 使RAFT试剂与锚定剂的官能团反应,使得RAFT试剂通过锚固剂与磁性纳米颗粒结合; 并将聚合物链连接到RAFT试剂上。

    Low odor chain transfer agents for controlled radical polymerization
    20.
    发明授权
    Low odor chain transfer agents for controlled radical polymerization 有权
    用于受控自由基聚合的低气味链转移剂

    公开(公告)号:US07332552B2

    公开(公告)日:2008-02-19

    申请号:US10583681

    申请日:2004-05-27

    CPC classification number: C07C327/36 C07C329/16 C07C333/24 C08F2/38

    Abstract: The present invention relates to low odor α-cyano-dithiocarboxylic ester compounds of formula I for use as chain transfer agents in free radical polymerizations, and polymerization processes employing them: wherein R1 is selected from alkyl, substituted alkyl, heteroaryl, substituted heteroaryl, alkylaryl, substituted alkylaryl, aryl, substituted aryl, alkoxy, aryloxy, thioalkyl, thioaryl, substituted thioalkyl, substituted thioaryl, secondary amino and tertiary amino; R2 is selected from alkyl, aryl, substituted aryl, heteroaryl, substituted heteroaryl, and COOR3; and R3 is alkyl.

    Abstract translation: 本发明涉及在自由基聚合中用作链转移剂的式I的低气味α-氰基 - 二硫代羧酸酯化合物和使用它们的聚合方法:其中R 1选自烷基,取代的 烷基,杂芳基,取代的杂芳基,烷基芳基,取代的烷基芳基,芳基,取代的芳基,烷氧基,芳氧基,硫代烷基,硫代芳基,取代的硫代烷基,取代的硫代芳基,仲氨基和叔氨基; R 2选自烷基,芳基,取代的芳基,杂芳基,取代的杂芳基和COOR 3; R 3是烷基。

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