公开(公告)号：US4175114A

公开(公告)日：1979-11-20

申请号：US841622

申请日：1977-10-13

申请人： Charles J. Plank ,  Edward J. Rosinski ,  Mae K. Rubin

发明人： Charles J. Plank ,  Edward J. Rosinski ,  Mae K. Rubin

IPC分类号： B01J29/40 ,  C01B39/36 ,  C01B39/38 ,  C01B33/28

CPC分类号： C01B39/38 ,  B01J29/40 ,  C01B39/365 ,  Y10S423/21 ,  Y10S423/29

摘要： As synthesized by previous methods, ZSM-5 or ZSM-11 zeolites are crystallized in the presence of substantial amounts of a nitrogen-containing compound. When synthesized in this way, they contain an organic ammonium cation as well as a metal cation such as sodium. To obtain a more active form, the sodium ion must be exchanged out. Such exchange, especially with ZSM-5 and ZSM-11, is difficult unless there is calcination of the zeolite to remove the obstructing organo compounds. By making these zeolites in the presence of (1) seeds of the desired zeolite, (2) mixtures of them with ammonium hydroxide and/or alcohol, (3) the alcohol per se or (4) mixtures of the alcohol with ammonium hydroxide, a product substantially deficient in organic ammonium cation is obtained. These products can be exchanged directly without any calcination.

公开(公告)号：US4157293A

公开(公告)日：1979-06-05

申请号：US934234

申请日：1978-08-16

申请人： Charles J. Plank ,  Edward J. Rosinski ,  Edwin N. Givens

发明人： Charles J. Plank ,  Edward J. Rosinski ,  Edwin N. Givens

IPC分类号： B01J29/40 ,  B01J29/44 ,  B01J29/46 ,  C07C2/00 ,  B01J29/28 ,  C07C15/02

CPC分类号： B01J29/46 ,  B01J29/40 ,  B01J29/405 ,  B01J29/44 ,  C07C2/00 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/40

摘要： A process for converting hydrocarbons with stabilized crystalline aluminosilicate catalysts. The catalysts contain zinc, and are stabilized by adding thereto another metal of Group IB or Group VIII (e.g. copper or nickel). Germanium, rhenium and the rare earth metals may also be added.

摘要翻译： 用稳定的结晶硅铝酸盐催化剂转化烃的方法。 催化剂含有锌，并通过加入另一种IB或VIII族金属（如铜或镍）来稳定。 还可以加入锗，铼和稀土金属。

公开(公告)号：US4116813A

公开(公告)日：1978-09-26

申请号：US852167

申请日：1977-11-16

申请人： Mae K. Rubin ,  Edward J. Rosinski ,  Charles J. Plank

发明人： Mae K. Rubin ,  Edward J. Rosinski ,  Charles J. Plank

IPC分类号： C07C43/04 ,  B01J29/00 ,  B01J29/50 ,  B01J29/70 ,  C01B39/30 ,  C07B61/00 ,  C07C1/00 ,  C07C1/20 ,  C07C2/12 ,  C07C4/06 ,  C07C5/27 ,  C07C6/12 ,  C07C9/00 ,  C07C11/02 ,  C07C15/02 ,  C07C41/00 ,  C07C67/00 ,  C10G11/05 ,  C10G11/04 ,  B01J8/24

CPC分类号： C10G11/05 ,  B01J29/50 ,  B01J29/70 ,  B01J29/7049 ,  C01B39/305 ,  C07C1/20 ,  C07C2/12 ,  C07C4/06 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  C07C2529/06

摘要： A crystalline zeolite, designated ZSM-34, having the composition as synthesized and in anhydrous form, expressed as mole ratios of oxides as follows:(0.5-1.3)R.sub.2 O : (0-0.15)Na.sub.2 0 : (0.10-0.50)K.sub.2 O : Al.sub.2 O.sub.3 : XSiO.sub.2where R is the organic nitrogen-containing cation, [(CH.sub.3).sub.3 NCH.sub.2 CH.sub.2 OH], derived from choline, and X is 8 to 50, said zeolite having an X-ray diffraction pattern, identifying it as a member of the offretite-erionite family and the ability, after calcination at 1000.degree. F for at least a period of time to remove the organic cation, to sorb at least 9.5 weight percent of n-hexane at ambient temperature and a n-hexane pressure of 20 mm. Organic compound conversion is carried out in the presence of a catalytically-active form of said zeolite.

摘要翻译： 称为ZSM-34的结晶沸石，具有合成和无水形式的组成，表示为氧化物的摩尔比如下：

公开(公告)号：US4105541A

公开(公告)日：1978-08-08

申请号：US850876

申请日：1977-11-14

申请人： Charles J. Plank ,  Mae K. Rubin ,  Edward J. Rosinski

发明人： Charles J. Plank ,  Mae K. Rubin ,  Edward J. Rosinski

IPC分类号： B01J29/65 ,  B01J29/68 ,  B01J8/24 ,  C07C15/02

CPC分类号： B01J29/655 ,  B01J29/65 ,  B01J29/68

摘要： Catalytic conversion of hydrocarbon compounds in the presence of crystalline zeolite ZSM-38, or a thermal decomposition product thereof, is provided. Zeolite ZSM-38 has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(0.3-2.5)R.sub.2 O:(0-0.8)M.sub.2 O:Al.sub.2 O.sub.3 :(x)SiO.sub.2wherein R is an organic cation, especially an organic nitrogen-containing cation, M is an alkali metal cation and x is greater than 8, and is characterized by a specified X-ray powder diffraction pattern.

公开(公告)号：US4082695A

公开(公告)日：1978-04-04

申请号：US707790

申请日：1976-07-22

申请人： Edward J. Rosinski ,  Thomas R. Stein ,  Ronald H. Fischer

发明人： Edward J. Rosinski ,  Thomas R. Stein ,  Ronald H. Fischer

IPC分类号： B01J23/85 ,  B01J35/10 ,  C10G45/08 ,  B01J21/04 ,  B01J23/84 ,  B01J23/88

CPC分类号： C10G45/08 ,  B01J23/85 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1085

摘要： The disclosure concerns the demetalation and desulfurization of metal and sulfur containing petroleum oils, preferably those containing residua hydrocarbon components, through the use of a catalyst comprising a hydrogenating component composited on a refractory base, preferably an alumina, whose pores are substantially distributed over a narrow 100A to 200A diameter range, but also having at least about 5% of its pores of a diameter greater than 500A.

公开(公告)号：US4066531A

公开(公告)日：1978-01-03

申请号：US616964

申请日：1975-09-26

申请人： Hartley Owen ,  Paul B. Venuto ,  Edward J. Rosinski

发明人： Hartley Owen ,  Paul B. Venuto ,  Edward J. Rosinski

IPC分类号： C10G11/18 ,  C10G11/02

CPC分类号： C10G11/18 ,  C10G2400/20 ,  C10G2400/30

摘要： Liquid product rich in benzene, toluene and xylene and having a substantially lower mid-boiling point than heavy reformate feedstock or similar feedstock, such as, for example, from pyrolysis gasoline, of a class having an initial boiling point between about 230.degree. F and about 250.degree. F and an end point between about 350.degree. F and about 430.degree. F, and gaseous product rich in light olefins and isoparaffins which is good alkylation plant feed are produced by contacting said heavy reformate feedstock or said similar feedstock with a porous acid-active zeolite catalyst having a fluid activity index of at least about 18 in a fluidized catalyst system absent added hydrogen at a temperature of from about 800.degree. F to about 1200.degree. F, a catalyst/oil (i.e. heavy reformate or similar feedstock) weight ratio of from about 0.5 to about 40 and a catalyst residence time of from about 0.1 second to about 20 seconds.

公开(公告)号：US3974062A

公开(公告)日：1976-08-10

申请号：US515757

申请日：1974-10-17

申请人： Hartley Owen ,  Edward J. Rosinski ,  Paul B. Venuto

发明人： Hartley Owen ,  Edward J. Rosinski ,  Paul B. Venuto

IPC分类号： B01J8/24 ,  C10G11/18 ,  C10G11/02

CPC分类号： C10G11/18 ,  B01J8/24

摘要： A refinery process is described for converting desalted full range crude oils and syncrudes derived from coal, shale and tar sands. The process involves mixing and reacting the full range heavy oil feed with a low molecular weight carbon-hydrogen fragment contributor such as methanol or C.sub.2 -C.sub.5 olefins in the presence of a fluid zeolite cracking catalyst comprising mordenite.

摘要翻译： 描述了一种炼油方法，用于转化脱盐的全系原油和源自煤，页岩和焦油砂的合成油。 该方法包括在包含丝光沸石的流体沸石裂化催化剂存在下，使全范围重油进料与低分子量碳氢原子片段贡献者如甲醇或C 2 -C 5烯烃混合和反应。

公开(公告)号：US4521298A

公开(公告)日：1985-06-04

申请号：US331428

申请日：1981-12-16

申请人： Edward J. Rosinski ,  Albert B. Schwartz

发明人： Edward J. Rosinski ,  Albert B. Schwartz

IPC分类号： B01J29/08 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/80 ,  C10G11/04 ,  C10G11/05 ,  C10G11/02

CPC分类号： B01J29/80 ,  B01J29/40 ,  C10G11/04 ,  C10G11/05 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/084 ,  B01J29/65 ,  B01J29/70

摘要： A process for increasing gasoline octane number and/or total gasoline yield in catalytic cracking units by the addition of a very small amount of finely divided shape selective additive promoter, which additive promoter is not intimately combined with a substantial amount of another solid prior to contact with the cracking catalyst. The additive promoter is a zeolite characterized by a silica to alumina mole ratio greater than about 500 and a constraint index within the approximate range of 1 to 12.

摘要翻译： 通过加入非常少量的精细分散的形状选择性添加剂促进剂来提高催化裂化装置中汽油辛烷值和/或总汽油产率的方法，该添加剂促进剂在接触前不与大量其它固体紧密结合 与裂化催化剂。 添加剂促进剂是一种特征在于二氧化硅与氧化铝的摩尔比大于约500，约束指数在约1到12的范围内的沸石。

公开(公告)号：US4378308A

公开(公告)日：1983-03-29

申请号：US210492

申请日：1980-11-26

申请人： Philip J. Angevine ,  Edward J. Rosinski

发明人： Philip J. Angevine ,  Edward J. Rosinski

IPC分类号： B01J23/85 ,  B01J33/00 ,  B01J37/02 ,  C10G45/04 ,  B01J35/10

CPC分类号： B01J23/85 ,  B01J33/00 ,  B01J37/024 ,  C10G45/04 ,  B01J37/0215

摘要： Metal poisoning of hydrodesulfurization catalysts is reduced by coating the catalyst surface with a hydrated clay mineral, hydrated alumina, hydrated silica, or mixtures thereof. The catalyst and process in which it is used are particularly useful for the desulfurization of residual oils to produce low-sulfur, fuel oil products.

摘要翻译： 通过用水合粘土矿物，水合氧化铝，水合二氧化硅或其混合物涂覆催化剂表面，降低加氢脱硫催化剂的金属中毒。 其使用的催化剂和方法特别可用于残油的脱硫以产生低硫燃料油产品。

公开(公告)号：US4247416A

公开(公告)日：1981-01-27

申请号：US16248

申请日：1979-02-28

申请人： Harry G. Doherty ,  Charles J. Plank ,  Edward J. Rosinski

发明人： Harry G. Doherty ,  Charles J. Plank ,  Edward J. Rosinski

IPC分类号： B01J29/70 ,  B01J37/02 ,  C01B39/48 ,  C07C2/12 ,  C10G11/05 ,  C10G35/095 ,  C10G45/64 ,  C10G47/16 ,  C01B33/28 ,  B01J31/14

CPC分类号： B01J37/0209 ,  B01J29/70 ,  C01B39/48 ,  C07C2/12 ,  C10G11/05 ,  C10G35/095 ,  C10G45/64 ,  C10G47/16 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2529/70

摘要： A new crystalline zeolite, designated "ZSM-25", a method of making the zeolite and using the zeolite in catalytic conversion of hydrocarbons, is the subject of this application. The new zeolite has a composition in the anhydrous state expressed in terms of mole ratios of oxides as follows:(0.01-0.4)R.sub.2 O:(0.9.+-.0.2)M.sub.2 O:Al.sub.2 O.sub.3 : (6-10)SiO.sub.2wherein R is an organic nitrogen-containing cation such as tetraethylammonium ions and M is an alkali metal cation such as sodium and is characterized by a specified X-ray powder diffraction pattern.

摘要翻译： 本申请的主题是名为“ZSM-25”的新型结晶沸石，制备沸石和使用沸石催化转化烃的方法。 新型沸石具有以氧化物摩尔比表示的无水状态的组成如下：（0.01-0.4）R 2 O：（0.9 +/- 0.2）M 2 O：Al 2 O 3：（6-10）SiO 2其中R是有机 含氮阳离子如四乙基铵离子和M是碱金属阳离子如钠，其特征在于规定的X射线粉末衍射图。