Abstract:
An in-situ method for repairing a thermal barrier coating deposited on a component that has suffered localized spallation including depositing a ceramic paste on a surface area of the component exposed by the localized spallation, the ceramic paste including a ceramic material in a binder material, the ceramic material including solid zirconia particles, the binder material including a silicone compound. The method also including heating the binder material to yield a repair coating that covers the surface area of the component, the silicone compound promoting the bonding of the solid zirconia particles.
Abstract:
A masking material and a method for applying the masking material to preselected surfaces of a component to protect the surfaces to which the masking material is applied from exposure to a vapor phase of aluminum gas while a protective environmental coating is applied to other surfaces of the component. The component, such as found in the hot section of a gas turbine engine, typically has intricate internal passageways. A ceramic material is applied as a mask over preselected surfaces while leaving remaining surfaces of a component exposed. The component typically is a superalloy component, and the exposed surfaces are to be coated with an environmental protective coating. The surfaces are preselected on the basis of whether coating is desired on the surface. The ceramic material forms a continuous, crack-free mask on these preselected surfaces without obstructing the internal passageways. The ceramic material which forms a mask is stable at the elevated temperatures of environmental coating application. The ceramic mask material must be continuous and substantially crack-free to prevent the penetration of the aggressive gas phase of the environmental coating material onto the surface of the component where it would otherwise undesirably be deposited. The ceramic material does not react with either the surface of the superalloy component or the gaseous vapors of the coating composition. At the conclusion of the coating operation, the ceramic coating applied as a mask can be easily and completely removed from the surface of the substrate by simple mechanical means, which surface is free of any coating from the coating operation.
Abstract:
Disclosed herein is a multifunctional catalyst system comprising a substrate; and a catalyst pair disposed upon the substrate; wherein the catalyst pair comprises a first catalyst and a second catalyst; and wherein the first catalyst initiates or facilitates the reduction of carbon dioxide to carbon monoxide while the second catalyst initiates or facilitates the conversion of carbon monoxide to an organic compound. Disclosed herein is a method comprising reducing carbon dioxide to carbon monoxide in a first reaction catalyzed by a first catalyst; and reacting carbon monoxide with hydrogen in a second reaction catalyzed by second catalyst; wherein the first catalyst and the second catalyst are disposed upon a single substrate.
Abstract:
In some embodiments, the present invention is directed to methods of making structures with complex functional architectures, where such structures generally comprise at least two mesoporous regions comprising different chemical activity, and where such methods afford spatial control over the placement of such regions of differing chemical activity. In some embodiments, the present invention is also directed to the structures formed by such methods, where such structures are themselves novel.
Abstract:
Disclosed herein are a system and a method for the production of hydrogen. The system advantageously combines an independent high temperature heat source with a solid oxide electrolyzer cell and a heat exchanger. The heat exchanger is used to extract heat from the molecular components such as hydrogen derived from the electrolysis. A portion of the hydrogen generated in the solid oxide electrolyzer cell is recombined with steam and recycled to the solid oxide electrolyzer cell. The oxygen generated on the anode side is swept with compressed air and used to drive a gas turbine that is in operative communication with a generator. Electricity generated by the generator is used to drive the electrolysis in the solid oxide electrolyzer cell.
Abstract:
A porous structure and method of making the porous structure is disclosed. The porous structure includes a substrate comprising at least one pore having an internal surface. At least a first portion of the internal surface of the at least one pore has a first fluid contact angle and at least second portion of the internal surface of the at least one pore has a second fluid contact angle. The difference between the first fluid contact angle and the second fluid contact angle has an absolute value of at least about 5 degrees and the second fluid contact angle is greater than about 40 degrees.
Abstract:
A process capable of depositing a diffusion coating of uniform thickness on localized surface regions of a component. The process makes use of an adhesive mixture containing a binding agent that is consumed as part of the deposition process so as not to negatively affect the quality and uniformity of the resulting coating. The process entails mixing a particulate donor material containing a coating element, a dissolved activator, and a particulate filler to form an adhesive mixture having a formable, malleable consistency. The adhesive mixture is applied to a surface of the component, and the component is heated to a temperature sufficient to vaporize and react the activator with the coating element of the donor material, thereby forming a reactive vapor of the coating element. The reactive vapor reacts at the surface of the component to form a diffusion coating containing the coating element.
Abstract:
A beta-phase NiAl overlay coating containing a dispersion of ceramic particles and a process for depositing the overlay coating. If the coating is used to adhere a thermal barrier coating (TBC), the TBC exhibits improved spallation resistance as a result of the dispersion of ceramic particles having a dispersion-strengthening effect on the overlay coating. The overlay coating contains at least one reactive element and is deposited so that the some of the reactive element deposits as the ceramic particles dispersed in the overlay coating.
Abstract:
The present invention provides high-throughput systems and methods for the fabrication and evaluation of electrode and electrolyte materials for solid oxide fuel cells. The present invention includes systems and methods for synthesizing and optimizing the performance of electrodes and electrode-electrolyte combinations and utilizes small-scale techniques to perform such optimization based on chemical composition and variable processing. Advantageously, rapid device performance systems and methods coupled with structural and surface systems and methods allow for an increased discovery rate of new materials for solid oxide fuel cells.
Abstract:
A membrane structure is provided. The membrane structure includes a polymer layer having a plurality of pores; and a ceramic layer disposed on the polymer layer. The ceramic layer has a plurality of substantially unconnected pores. Each of the substantially unconnected pores is in fluid communication with at least one of the pores of the polymer layer. A method of manufacturing a membrane structure is provided. The method includes the steps of providing a polymer layer having a plurality of pores; and disposing a ceramic layer on the polymer layer. Disposing a ceramic layer includes depositing a metal layer on the polymer layer; and anodizing the metal layer to convert the metal layer into a porous layer. At least one of the depositing step and the anodizing step is performed as a continuous process. Alternatively, at least one of the depositing and the anodizing step is performed as a batch process.