公开(公告)号：US6103660A

公开(公告)日：2000-08-15

申请号：US55908

申请日：1998-04-07

Applicant: Renee Van Yperen ,  Dieter Lindner ,  Lothar Mussmann ,  Egbert Lox ,  Thomas Kreuzer

Inventor： Renee Van Yperen ,  Dieter Lindner ,  Lothar Mussmann ,  Egbert Lox ,  Thomas Kreuzer

IPC: B01J21/16 ,  B01J23/58 ,  B01J23/63 ,  B01J37/02 ,  B01J37/03 ,  B01J23/40

CPC classification number: B01J37/035 ,  B01J23/63 ,  B01J37/0234 ,  B01J37/031

Abstract: A method of depositing catalytically active components on high-surface carrier materials is disclosed by dispersing the carrier materials in water and mixing this dispersion with an aqueous solution of soluble precursors of the catalytically active components. The pH of the dispersion is adjusted to a value between 6 and 8 before the aqueous solution of the precursors is supplied by capillary injection under constant agitation of the dispersion and thereafter, if necessary, the precursors of the catalytically active components are precipitated on the carrier material by capillary injection of a dilute base.

Abstract translation: 通过将载体材料分散在水中并将该分散体与催化活性组分的可溶性前体的水溶液混合来公开在高表面载体材料上沉积催化活性组分的方法。 在不断搅拌分散体之前，通过毛细管注入前体的水溶液，然后如果需要，催化活性组分的前体在载体上沉淀，将分散体的pH调节至6至8之间的值 材料通过毛细管注入稀碱。

公开(公告)号：US5852130A

公开(公告)日：1998-12-22

申请号：US664539

申请日：1996-06-17

Applicant: Lothar Mussmann ,  Yves Chauvin ,  Helene Olivier

Inventor： Lothar Mussmann ,  Yves Chauvin ,  Helene Olivier

IPC: B01J31/22 ,  B01J23/46 ,  B01J31/02 ,  B01J31/16 ,  B01J31/24 ,  C07B61/00 ,  C07C5/03 ,  C07C5/11 ,  C07C9/00 ,  C07C13/20 ,  C07C13/58 ,  C08F8/04

CPC classification number: B01J31/16 ,  B01J31/0278 ,  B01J31/0284 ,  B01J31/0288 ,  B01J31/20 ,  B01J31/2291 ,  B01J31/2404 ,  B01J31/2409 ,  B01J2231/645 ,  B01J23/462 ,  B01J23/464 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/828 ,  B01J2531/845

Abstract: A novel catalytic composition comprises at least one quaternary ammonium and/or phosphonium salt in which the anion is selected from the group formed by tetrafluoroborate, tetrachloroborate, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, trifluorosulphonate, fluorosulphonate, tetrachloroaluminate, dichlorocuprate, and trichlorozincate, and at least one complex of a transition metal from groups 8, 9 and 10, i.e., iron, ruthenium, cobalt, rhodium iridium, nickel, palladium and platinum. Application to total or selective hydrogenation of unsaturated compounds such as monoolefins, diolefins, acetylenic compounds, aromatic compounds, polynuclear aromatic compounds. Hydrogenation may be accompanied by isomerisation.

Abstract translation: 一种新型催化剂组合物包含至少一种季铵盐和/或鏻盐，其中阴离子选自四氟硼酸盐，四氯硼酸盐，六氟磷酸盐，六氟锑酸盐，六氟砷酸盐，三氟磺酸盐，氟磺酸盐，四氯铝酸盐，二氯磷酸盐和三氯酸锌形成的基团， 来自组8,9和10的过渡金属的一个复合物，即铁，钌，钴，铑铱，镍，钯和铂。 适用于单烯烃，二烯烃，炔属化合物，芳香族化合物，多核芳香族化合物等不饱和化合物的全部或选择性氢化。 氢化可伴随异构化。

公开(公告)号：US08569199B2

公开(公告)日：2013-10-29

申请号：US12444312

申请日：2007-09-17

Applicant: Katja Adelmann ,  Nicola Soeger ,  Lothar Mussmann ,  Marcus Pfeifer ,  Gerald Jeske

Inventor： Katja Adelmann ,  Nicola Soeger ,  Lothar Mussmann ,  Marcus Pfeifer ,  Gerald Jeske

IPC: B01J23/10 ,  B01J23/00 ,  B01D53/46

CPC classification number: B01J23/002 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2255/2063 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/20784 ,  B01D2255/407 ,  B01D2255/9155 ,  B01J23/10 ,  B01J23/24 ,  B01J23/30 ,  B01J23/888 ,  B01J27/04 ,  B01J37/0201 ,  B01J37/0248 ,  B01J2523/00 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/48 ,  Y02A50/2325 ,  Y02T10/24 ,  B01J2523/69 ,  B01J2523/842

Abstract: Selective catalytic reduction with ammonia or a compound that decomposes to ammonia is a known method for the removal of nitrogen oxides from the exhaust gas of primarily lean-burn internal combustion engines. The vanadium-containing SCR catalysts that have long been generally used for this are characterized by a good conversion profile. However, the volatility of vanadium oxide can, at higher exhaust gas temperatures, lead to the emission of toxic vanadium compounds. Zeolite-based SCR catalysts, which are used in particular in discontinuous SCR systems, constitute a very cost-intensive solution for the problem.A method is proposed by which a homogeneous cerium-zirconium mixed oxide is activated for the SCR reaction in a defined manner by the introduction of sulphur and/or transition metal. Using this method, a highly active, ageing-resistant SCR catalyst is provided, which represents a vanadium-free, cost-effective and high-performance alternative to the existing SCR catalysts and is suitable in particular for use in motor vehicles.

Abstract translation: 用氨或分解成氨的化合物进行选择性催化还原是从主要贫燃内燃机的废气中除去氮氧化物的已知方法。 长期以来一般使用的含钒SCR催化剂的特征在于良好的转化率。 然而，在更高的废气温度下，氧化钒的挥发性会导致有毒的钒化合物的排放。 特别是在不连续SCR系统中使用的基于沸石的SCR催化剂构成了该问题的非常成本高的解决方案。 提出了一种通过引入硫和/或过渡金属以规定的方式使均相铈锆混合氧化物活化用于SCR反应的方法。 使用这种方法，提供了高活性，耐老化的SCR催化剂，其代表了现有SCR催化剂的无钒，成本效益和高性能替代物，并且特别适用于机动车辆。

公开(公告)号：US08568678B2

公开(公告)日：2013-10-29

申请号：US12307696

申请日：2007-06-06

Applicant: Nicola Soeger ,  Lothar Mussmann ,  Ralf Sesselmann ,  Katja Adelmann ,  Wolfgang Schneider

Inventor： Nicola Soeger ,  Lothar Mussmann ,  Ralf Sesselmann ,  Katja Adelmann ,  Wolfgang Schneider

IPC: B01D53/56 ,  C01B33/36 ,  B01D47/00 ,  B01J8/02 ,  B01J29/04 ,  B01J21/00 ,  B01J21/18

CPC classification number: F01N3/2066 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2255/102 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2255/50 ,  B01D2255/911 ,  B01D2255/9202 ,  B01J29/072 ,  B01J35/0006 ,  B01J37/0246 ,  F01N2370/04 ,  F01N2610/02 ,  Y02A50/2325 ,  Y02T10/24

Abstract: The reductive removal of nitrogen oxides from the exhaust gas from internal combustion engines operated predominantly under lean conditionstakes place in a selective catalytic reduction (SCR) of the nitrogen oxides by means of ammonia or a compound which can be decomposed into ammonia as reducing agent. Conventional SCR catalysts typically have a relatively narrow working temperature window, usually 350° C. to 520° C., in which good nitrogen oxide conversions can be achieved with sufficient selectivity. SCR catalyst formulations whose working window is in the temperature range from 150° C. to 350° C. generally not be used at higher temperatures since they oxidize the ammonia required as reducing 18 agent to nitrogen oxides at above 350° C. To cover the entire exhaust gas temperature range typical of vehicles having been operating internal combustion enginesextending from 200° C. to 600° C., it has therefore mostly been necessary to use complicated exhaust gas systemscontaining a plurality of catalysts having different working temperature ranges. Disclosed is a structured SCR catalyst whose working range extends over a significantly broader temperature window and by means of which complicated exhaust gas units can be considerably simplified, with a saving of components.

Abstract translation: 来自主要在贫态条件下运行的内燃机废气中的氮氧化物的还原去除通过氨或可分解成氨作为还原剂的化合物置于氮氧化物的选择性催化还原（SCR）中。 常规SCR催化剂通常具有相对窄的工作温度窗口，通常为350℃至520℃，其中可以以足够的选择性实现良好的氮氧化物转化。 工作窗口在150°C至350°C温度范围内的SCR催化剂配方通常不会在较高温度下使用，因为它们会将需要的氨氧化为在高于350°C的氮氧化物所需的氨。 已经运行内燃机的车辆的典型的整个排气温度范围从200℃升高到600℃，因此大多需要使用包含具有不同工作温度范围的多个催化剂的复杂的废气系统。 公开了一种结构化SCR催化剂，其工作范围在明显更宽的温度窗口上延伸，并且借助于这些SCR催化剂可以显着简化复杂的废气单元，同时节省了部件。

公开(公告)号：US08057768B2

公开(公告)日：2011-11-15

申请号：US12226857

申请日：2008-10-23

Applicant: Wolfgang Schneider ,  Lothar Mussmann ,  Gerald Jeske ,  Michael Schiffer ,  Marcus Pfeifer

Inventor： Wolfgang Schneider ,  Lothar Mussmann ,  Gerald Jeske ,  Michael Schiffer ,  Marcus Pfeifer

IPC: B01D53/94 ,  F01N3/10

CPC classification number: F01N3/2066 ,  B01D53/9418 ,  B01D53/944 ,  B01D53/9477 ,  B01D2251/206 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2258/012 ,  B01J23/44 ,  F01N3/035 ,  F01N13/009 ,  F01N2570/14 ,  Y02T10/24

Abstract: The invention relates to a special device for the purification of diesel exhaust gases, which device comprises, in the flow direction of the exhaust gas, an oxidation catalyst, a diesel particle filter with catalytically active coating, and, downstream of a device for introducing a reducing agent from an external reducing agent source, an SCR catalyst. The oxidation catalyst and the catalytically active coating of the diesel particle filter contain palladium and platinum. The ratio of the noble metals platinum and palladium in the overall system and on the individual components, oxidation catalyst and catalytically coated diesel particle filter, are coordinated with one another in such a way as to obtain firstly an optimum NO/NO2 ratio in the exhaust gas upstream of the downstream SCR catalyst, and secondly optimum heating and HC conversion behaviour during an active particle filter regeneration.

Abstract translation: 本发明涉及一种用于净化柴油机废气的专用装置，该装置在排气的流动方向上包括氧化催化剂，具有催化活性涂层的柴油颗粒过滤器，以及用于引入 还原剂来自外部还原剂源，SCR催化剂。 柴油颗粒过滤器的氧化催化剂和催化活性涂层含有钯和铂。 整个系统中的贵金属铂和钯与单个组分，氧化催化剂和催化涂层柴油颗粒过滤器的比例彼此协调，以便首先获得排气中最佳的NO / NO 2比例 下游SCR催化剂上游的气体，其次是活性颗粒过滤器再生过程中的最佳加热和HC转化行为。

公开(公告)号：US07485599B2

公开(公告)日：2009-02-03

申请号：US11784622

申请日：2007-04-09

Applicant: Mamoun Muhammed ,  Othon Adamopoulos ,  Tassilo Bog ,  Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Matthias Feger ,  Egbert Lox ,  Thomas Kreuzer

Inventor： Mamoun Muhammed ,  Othon Adamopoulos ,  Tassilo Bog ,  Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Matthias Feger ,  Egbert Lox ,  Thomas Kreuzer

IPC: B01J23/02 ,  B01J23/10

CPC classification number: C01G25/00 ,  B01D53/945 ,  B01D2255/206 ,  B01D2255/908 ,  B01J23/002 ,  B01J23/10 ,  B01J37/03 ,  B01J2523/00 ,  B82Y30/00 ,  C01B13/0262 ,  C01B13/0281 ,  C01F17/0018 ,  C01F17/0043 ,  C01G25/006 ,  C01P2002/50 ,  C01P2002/60 ,  C01P2004/64 ,  C01P2006/12 ,  Y02T10/22 ,  B01J2523/23 ,  B01J2523/3712 ,  B01J2523/31 ,  B01J2523/48 ,  B01J2523/3706

Abstract: An oxygen storage material comprising cerium oxide and at least one second oxide of a metal M1 is disclosed as well as a process for manufacturing the material and the use of this material in an exhaust gas cleaning catalyst. In a preferred embodiment the oxygen storage material comprises particles from a Ce/M1 mixed oxide solid solution coated with an oxide of another metal M2. Metal M1 e.g. can be calcium or zirconium while metal M2 most preferably is aluminum.

Abstract translation: 公开了一种包含氧化铈和金属M1的至少一种第二氧化物的储氧材料，以及用于制造材料的方法和在废气清洁催化剂中使用该材料。 在优选的实施方案中，储氧材料包含涂覆有另一种金属M2的氧化物的Ce / M1混合氧化物固溶体的颗粒。 金属M1例如 可以是钙或锆，而金属M2最优选是铝。

公开(公告)号：US06655129B2

公开(公告)日：2003-12-02

申请号：US10056814

申请日：2002-01-24

Applicant: Dieter Lindner ,  Jorg-Michael Richter ,  Egbert Lox ,  Thomas Kreuzer ,  Martin Votsmeier ,  Lothar Mussmann

Inventor： Dieter Lindner ,  Jorg-Michael Richter ,  Egbert Lox ,  Thomas Kreuzer ,  Martin Votsmeier ,  Lothar Mussmann

IPC: F01N300

CPC classification number: F02D41/2458 ,  F02D41/0295 ,  F02D41/1408 ,  F02D41/1456 ,  F02D2041/1437 ,  F02D2200/0814 ,  Y02T10/22

Abstract: A process is provided for operating a three-way catalyst that contains an oxygen storage component, that has a minimum and a maximum filling degree for oxygen and that is located in the exhaust gas line of an internal combustion engine. The air/fuel mixture supplied to the engine is varied in such a way that the filling degree of the oxygen storage component in the catalyst is held within a set-point interval between the minimum and maximum filling degree. According to this process, in order to regulate the air/fuel mixture, migration of the filling degree out of the set-point interval is checked in a test phase in such a way that the filling degree is increased or lowered relative to the instantaneous value (initial value) by short-term enrichment or reduction in richness of the air/fuel mixture supplied to the engine by a certain amount and immediately returned to the initial value by a short-term opposing change in the air/fuel mixture (lean/rich pulse sequence or rich/lean pulse sequence). In the case of a breakthrough of lean or rich exhaust gas through the catalyst during the test phase, the air/fuel mixture is enriched or reduced in richness in order to correct the filling degree, wherein the amount by which the filling degree during the test phase is increased or decreased is such that no breakthrough of lean or rich exhaust gas takes place through the catalyst when the filling degree of the oxygen storage component is within the set-point interval.

公开(公告)号：US06475951B1

公开(公告)日：2002-11-05

申请号：US09513341

申请日：2000-02-25

Applicant: Rainer Domesle ,  Ulrich Göbel ,  Lothar Mussmann ,  Egbert Lox ,  Thomas Kreuzer

Inventor： Rainer Domesle ,  Ulrich Göbel ,  Lothar Mussmann ,  Egbert Lox ,  Thomas Kreuzer

IPC: B01J2300

CPC classification number: B01D53/945 ,  B01J23/002 ,  B01J23/58 ,  B01J23/63 ,  B01J37/0205 ,  B01J37/0248 ,  B01J2523/00 ,  Y02T10/22 ,  B01J2523/3712 ,  B01J2523/48

Abstract: A powdered catalyst material based on aluminum oxide, which contains at least one basic metal oxide and at least one noble metal from the platinum group of the Periodic Table of Elements in addition to aluminum oxide. The catalyst material is obtainable by loading a support material already stabilized by basic oxides by renewed impregnation with further basic oxides. After drying and calcining this post-impregnated material at temperatures below 800° C., the catalytically active noble metals are also incorporated into the support material by impregnation.

Abstract translation: 基于氧化铝的粉末状催化剂材料，其除了氧化铝之外还含有至少一种碱金属氧化物和至少一种来自元素周期表的铂族的贵金属。 催化剂材料可以通过用另外的碱性氧化物再次浸渍加载已经通过碱性氧化物稳定的载体材料而获得。 在低于800℃的温度下干燥和煅烧该浸渍后材料之后，催化活性的贵金属也通过浸渍掺入载体材料中。

公开(公告)号：US20100221161A1

公开(公告)日：2010-09-02

申请号：US12226857

申请日：2008-10-23

Applicant: Wolfgang Schneider ,  Lothar Mussmann ,  Gerald Jeske ,  Michael Schiffer ,  Marcus Pfeifer

Inventor： Wolfgang Schneider ,  Lothar Mussmann ,  Gerald Jeske ,  Michael Schiffer ,  Marcus Pfeifer

IPC: B01D53/94 ,  F01N3/035 ,  B01D50/00

CPC classification number: F01N3/2066 ,  B01D53/9418 ,  B01D53/944 ,  B01D53/9477 ,  B01D2251/206 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2258/012 ,  B01J23/44 ,  F01N3/035 ,  F01N13/009 ,  F01N2570/14 ,  Y02T10/24

Abstract: The invention relates to a special device for the purification of diesel exhaust gases, which device comprises, in the flow direction of the exhaust gas, an oxidation catalyst, a diesel particle filter with catalytically active coating, and, downstream of a device for introducing a reducing agent from an external reducing agent source, an SCR catalyst. The oxidation catalyst and the catalytically active coating of the diesel particle filter contain palladium and platinum. The ratio of the noble metals platinum and palladium in the overall system and on the individual components, oxidation catalyst and catalytically coated diesel particle filter, are coordinated with one another in such a way as to obtain firstly an optimum NO/NO2 ratio in the exhaust gas upstream of the downstream SCR catalyst, and secondly optimum heating and HC conversion behaviour during an active particle filter regeneration.

Abstract translation: 本发明涉及一种用于净化柴油机废气的专用装置，该装置在排气的流动方向上包括氧化催化剂，具有催化活性涂层的柴油颗粒过滤器，以及用于引入 还原剂来自外部还原剂源，SCR催化剂。 柴油颗粒过滤器的氧化催化剂和催化活性涂层含有钯和铂。 整个系统中的贵金属铂和钯与单个组分，氧化催化剂和催化涂层柴油颗粒过滤器的比例彼此协调，以便首先获得排气中最佳的NO / NO 2比例 下游SCR催化剂上游的气体，其次是活性颗粒过滤器再生过程中的最佳加热和HC转化行为。

公开(公告)号：US20100209327A1

公开(公告)日：2010-08-19

申请号：US12307696

申请日：2007-06-06

Applicant: Nicola Soeger ,  Lothar Mussmann ,  Ralf Sesselmann ,  Katja Adelmann ,  Wolfgang Schneider

Inventor： Nicola Soeger ,  Lothar Mussmann ,  Ralf Sesselmann ,  Katja Adelmann ,  Wolfgang Schneider

IPC: B01D53/56 ,  B01J29/072 ,  B01D53/94

CPC classification number: F01N3/2066 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2255/102 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2255/50 ,  B01D2255/911 ,  B01D2255/9202 ,  B01J29/072 ,  B01J35/0006 ,  B01J37/0246 ,  F01N2370/04 ,  F01N2610/02 ,  Y02A50/2325 ,  Y02T10/24

Abstract: The reductive removal of nitrogen oxides from the exhaust gas from internal combustion engines operated predominantly under lean conditions takes place in a selective catalytic reduction (SCR) of the nitrogen oxides by means of ammonia or a compound which can be decomposed into ammonia as reducing agent. Conventional SCR catalysts typically have a relatively narrow working temperature window, usually 350° C. to 520° C., in which good nitrogen oxide conversions can be achieved with sufficient selectivity. SCR catalyst formulations whose working window is in the temperature range from 150° C. to 350° C. generally not be used at higher temperatures since they oxidize the ammonia required as reducing 18 agent to nitrogen oxides at above 350° C. To cover the entire exhaust gas temperature range typical of vehicles having been operating internal combustion engines extending from 200° C. to 600° C., it has therefore mostly been necessary to use complicated exhaust gas systems containing a plurality of catalysts having different working temperature ranges. Disclosed is a structured SCR catalyst whose working range extends over a significantly broader temperature window and by means of which complicated exhaust gas units can be considerably simplified, with a saving of components.

Abstract translation: 来自主要在贫条件下运行的内燃机的废气中的氮氧化物的还原除去通过氨或可分解成氨作为还原剂的化合物在氮氧化物的选择性催化还原（SCR）中进行。 常规SCR催化剂通常具有相对窄的工作温度窗口，通常为350℃至520℃，其中可以以足够的选择性实现良好的氮氧化物转化。 工作窗口在150°C至350°C温度范围内的SCR催化剂配方通常不会在较高温度下使用，因为它们会将需要的氨氧化为在高于350°C的氮氧化物所需的氨。 已经运行内燃机的车辆的典型的整个排气温度范围从200℃延伸到600℃，因此大多需要使用包含具有不同工作温度范围的多个催化剂的复杂的废气系统。 公开了一种结构化SCR催化剂，其工作范围在明显更宽的温度窗口上延伸，并且借助于这些SCR催化剂可以显着简化复杂的废气单元，同时节省了部件。