公开(公告)号：US20120231287A1

公开(公告)日：2012-09-13

申请号：US13424755

申请日：2012-03-20

Applicant: Rajen M. Patel ,  David W. Fuchs ,  Pradeep Jain ,  Seema Karande ,  Mehmet Demirors ,  Mark Grant Spencer ,  Kim L. Walton ,  Angela N. Taha ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Anthony J. Castelluccio

Inventor： Rajen M. Patel ,  David W. Fuchs ,  Pradeep Jain ,  Seema Karande ,  Mehmet Demirors ,  Mark Grant Spencer ,  Kim L. Walton ,  Angela N. Taha ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Anthony J. Castelluccio

IPC: B32B27/32 ,  C08F210/02

CPC classification number: C08F210/16 ,  B32B27/08 ,  B32B27/10 ,  B32B27/18 ,  B32B27/32 ,  B32B2250/24 ,  B32B2307/31 ,  B32B2439/70 ,  Y10T428/269 ,  Y10T428/31938 ,  C08F2/00 ,  C08F2/38 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/04

Abstract: The present invention relates to compositions and processes of making and using interpolymers having a controlled molecular weight distribution. Multilayer films and film layers derived from novel ethylene/α-olefin interpolymers are also disclosed.

Abstract translation: 本发明涉及制备和使用具有受控分子量分布的互聚物的组合物和方法。 还公开了衍生自新乙烯/α-烯烃互聚物的多层膜和膜层。

公开(公告)号：US08153243B2

公开(公告)日：2012-04-10

申请号：US11762643

申请日：2007-06-13

Applicant: Rajen M. Patel ,  David W. Fuchs ,  Pradeep Jain ,  Seema Karande ,  Mehmet Demirors ,  Mark Grant Spencer ,  Kim L. Walton ,  Angela N. Taha ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Anthony J. Castelluccio

Inventor： Rajen M. Patel ,  David W. Fuchs ,  Pradeep Jain ,  Seema Karande ,  Mehmet Demirors ,  Mark Grant Spencer ,  Kim L. Walton ,  Angela N. Taha ,  Phillip D. Hustad ,  Roger L. Kuhlman ,  Anthony J. Castelluccio

IPC: B32B7/00 ,  C08F10/02

CPC classification number: C08F210/16 ,  B32B27/08 ,  B32B27/10 ,  B32B27/18 ,  B32B27/32 ,  B32B2250/24 ,  B32B2307/31 ,  B32B2439/70 ,  Y10T428/269 ,  Y10T428/31938 ,  C08F2/00 ,  C08F2/38 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/04

Abstract: The present invention relates to compositions and processes of making and using interpolymers having a controlled molecular weight distribution. Multilayer films and film layers derived from novel ethylene/α-olefin interpolymers are also disclosed.

Abstract translation: 本发明涉及制备和使用具有受控分子量分布的互聚物的组合物和方法。 还公开了衍生自新乙烯/α-烯烃互聚物的多层膜和膜层。

公开(公告)号：US20050187352A1

公开(公告)日：2005-08-25

申请号：US11113748

申请日：2005-04-25

Applicant: Pak-Wing Chum ,  Kurt Swogger ,  Thomas Oswald ,  Pradeep Jain

Inventor： Pak-Wing Chum ,  Kurt Swogger ,  Thomas Oswald ,  Pradeep Jain

IPC: C08F210/16 ,  C08J5/18 ,  C08L23/04 ,  C08L23/08 ,  C08L23/00

CPC classification number: C08L23/0815 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/04 ,  C08L2205/02 ,  C08L2314/06 ,  Y10T428/1334 ,  Y10T428/1345 ,  Y10T428/2913 ,  Y10T428/2929 ,  Y10T428/31913 ,  C08L2666/04 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/09 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: Polymer blends are disclosed that include from about 5 percent (by weight of the total composition) to about 95 percent (by weight of the total composition) of at least one first ethylene interpolymer having at least one first comonomer, and from about 95 percent (by weight of the total composition) to about 5 percent (by weight of the total composition) of at least one second ethylene interpolymer having at least one second comonomer. In the disclosed blends, the first comonomer is different from the second comonomer and the melt index (I2) of the first ethylene interpolymer is less than or equal to the melt index (I2) of the second ethylene interpolymer. The blend are also characterized as having a density of greater than or equal to 0.90 g/cc. Articles made from such blends are also disclosed.

Abstract translation: 公开了包含约5％（总组合物重量）至约95％（按总组合物的重量计）的至少一种具有至少一种第一共聚单体的至少一种第一乙烯互聚物和约95％（ 的总组合物的重量）至约5％（总组合物的重量）至少一种具有至少一种第二共聚单体的第二乙烯互聚物。 在所公开的共混物中，第一共聚单体不同于第二共聚单体，并且第一乙烯互聚物的熔体指数（I 2/2）小于或等于熔融指数（I 2 / SUB>）。 共混物的特征还在于具有大于或等于0.90g / cc的密度。 还公开了由这种共混物制成的制品。

公开(公告)号：US06451916B1

公开(公告)日：2002-09-17

申请号：US09943853

申请日：2001-08-31

Applicant: Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

Inventor： Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

IPC: C08F800

CPC classification number: B01J8/0015 ,  B01J19/2435 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/04 ,  C08L2205/02 ,  Y10T428/31909 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08F2/001 ,  C08L2666/04 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F210/14

Abstract: The present invention pertains to a continuous process and polymerization system characterized by separate injection of catalyst and make-up feed, an ethylene interpolymer composition characterized as having broad molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a composition and a fabricated article made from such composition. The novel composition is characterized as having a melt flow ratio, I10/I2, from 8 to 30, a Mw/Mn of greater than 4 as determined by gel permeation chromatography, a melt index, I2, from 0.01 to 1000 grams/10 minutes, preferably greater that 0.1 to 10 grams/10 minutes, and a density less than 0.945 g/cm3. The novel composition exhibits good processibility and improved toughness properties, especially excellent film tear and impact resistance, and is particularly well-suited for use in applications such as high performance trash can liners and heavy duty shipping bags.

Abstract translation: 本发明涉及连续工艺和聚合体系，其特征在于分别注入催化剂和补充进料，特征在于具有宽分子量分布（MWD）和优化的组成均匀性的乙烯互聚物组合物，制备这种组合物的方法和 由这种组合物制成的制成品。 该新型组合物的特征在于具有通过凝胶渗透色谱法测定的熔体流动比I10 / I2，8至30，Mw / Mn大于4，熔体指数I 2为0.01至1000克/ 10分钟 ，优选为0.1〜10克/ 10分钟，密度小于0.945g / cm 3。 该新型组合物显示出良好的加工性和改进的韧性，特别优异的膜撕裂和抗冲击性，并且特别适合用于高性能垃圾桶衬里和重型运输袋等应用中。

公开(公告)号：US06319989B1

公开(公告)日：2001-11-20

申请号：US09463207

申请日：2000-01-20

Applicant: Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

Inventor： Kenneth W. Anderson ,  Pak-Wing S. Chum ,  David A. Eversdyk ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Kalyan Sehanobish ,  Li-Min Tau

IPC: C08F800

CPC classification number: C08J5/18 ,  B01J8/0015 ,  B01J19/2435 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08J2323/08 ,  C08L23/04 ,  C08L2205/02 ,  C08F2/001 ,  C08L2666/04 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F210/14

Abstract: The present invention pertains to a continuous process and polymerization system characterized by separate injection of catalyst and make-up feed, an ethylene interpolymer composition characterized as having broad molecular weight distribution (MWD) and optimized compositional uniformity, a process for making such a compostion and a fabricated article made from such composition. The novel composition is characterized as having a melt flow ratio, I10/I2, from 8 to 30, a Mw/Mn of greater than 4 as determined by gel permeation chromatography, a melt index, I2, from 0.01 to 1000 grams/10 minutes, preferably greater that 0.1 to 10 grams/10 minutes, and a density less than 0.945 g/cm3. The novel composition exhibits good processibility and improved toughness properties, especially excellent film tear and impact resistance, and is particularly well-suited for use in applications such as high performance trash can liners and heavy duty shipping bags.

Abstract translation: 本发明涉及连续工艺和聚合体系，其特征在于分别注入催化剂和补充进料，特征在于具有宽分子量分布（MWD）和优化的组成均匀性的乙烯互聚物组合物，制备这种组合物的方法和 由这种组合物制成的制成品。 该新型组合物的特征在于具有通过凝胶渗透色谱法测定的熔体流动比I10 / I2，8至30，Mw / Mn大于4，熔体指数I 2为0.01至1000克/ 10分钟 ，优选为0.1〜10克/ 10分钟，密度小于0.945g / cm 3。 该新型组合物显示出良好的加工性和改进的韧性，特别优异的膜撕裂和抗冲击性，并且特别适合用于高性能垃圾桶衬里和重型运输袋等应用中。

公开(公告)号：US6005053A

公开(公告)日：1999-12-21

申请号：US784681

申请日：1997-01-22

Applicant: Deepak R. Parikh ,  Pak-Wing S. Chum ,  Rajen M. Patel ,  Klye G. Kummer ,  Pradeep Jain ,  Thomas J. McKeand, Jr. ,  Ronald P. Markovich ,  Timothy E. Clayfield ,  Wasif Ahmed Khan

Inventor： Deepak R. Parikh ,  Pak-Wing S. Chum ,  Rajen M. Patel ,  Klye G. Kummer ,  Pradeep Jain ,  Thomas J. McKeand, Jr. ,  Ronald P. Markovich ,  Timothy E. Clayfield ,  Wasif Ahmed Khan

IPC: C08L23/04 ,  C08L23/08 ,  C08L91/00 ,  C08L33/02

CPC classification number: C08L23/0815 ,  C08L2205/02 ,  C08L91/00

Abstract: Polymer mixtures are disclosed which comprise at least one homogeneously branched ethylene polymer (A) and at least one ethylene polymer (B) having a crystallinity which is at least 7% greater than the crystallinity of polymer (A) with certain provisos. A process for making a molded article using the disclosed polymer mixtures is disclosed as well as films, film layers, coatings and molded articles formed from those mixtures. These mixtures have several advantages over polymer compositions of the prior art, including improved properties at elevated temperatures such as improved softening point under load, improved hardness, improved toughness, improved 100% modulus of elasticity, improved compression set, improved ability to prevent oil bleed out at lower temperatures when the mixture contains oil and reduced injection molding cycle time. The mixtures retain their performance advantages even when substantial amounts of additives such as oil and filler are incorporated into the mixture. The mixtures may also be crosslinked after they are formed into the shape of an article to form vulcanized elastomeric products. The polymer mixtures have utility in a variety of applications.

Abstract translation: 公开了包含至少一种均匀支化的乙烯聚合物（A）和至少一种乙烯聚合物（B）的聚合物混合物，其结晶度比聚合物（A）的结晶度大至少7％，具有某些条件。 公开了使用所公开的聚合物混合物制备模塑制品的方法以及由这些混合物形成的薄膜，薄膜层，涂层和模塑制品。 这些混合物具有优于现有技术的聚合物组合物的几个优点，包括在升高的温度下改进的性能，例如负载下改进的软化点，改进的硬度，改进的韧性，改进的100％弹性模量，改进的压缩永久变形，改进的防止油渗出的能力 当混合物含有油和降低注塑周期时，在较低的温度下出来。 即使将大量的添加剂如油和填料加入到混合物中，混合物也保持其性能优势。 在混合物形成制品的形状以形成硫化的弹性体产品之后，它们也可以交联。 聚合物混合物可用于各种应用。

公开(公告)号：US5977251A

公开(公告)日：1999-11-02

申请号：US831172

申请日：1997-04-01

Applicant: Che I. Kao ,  R. Bruce Combs ,  Gary A. Camp ,  David A. Eversdyk ,  Pradeep Jain ,  Greg A. Winter ,  Jeff H. Stultz

Inventor： Che I. Kao ,  R. Bruce Combs ,  Gary A. Camp ,  David A. Eversdyk ,  Pradeep Jain ,  Greg A. Winter ,  Jeff H. Stultz

IPC: B01J19/24 ,  C08F2/06 ,  C08F10/00 ,  C08F210/16

CPC classification number: C08F10/00 ,  B01J19/2435 ,  B01J19/245 ,  B01J19/2465 ,  B01J2219/00085 ,  B01J2219/00103 ,  B01J2219/00159 ,  B01J2219/00162 ,  B01J2219/00168 ,  B01J2219/00765 ,  C08F210/16 ,  Y02P20/584 ,  Y10S526/905

Abstract: A solution polymerization system for polymerizing a olefin monomer by reacting the monomer with catalyst and solvent has been invented. The system in one aspect including a flow loop with a product polymer outlet, the flow loop forming a recycling reactor, a catalyst inlet on the flow loop through which catalyst and solvent flow into the flow loop, a monomer inlet on the flow loop through which monomer and solvent flow into the flow loop and, with the catalyst, form a reactant materials stream, a first heat exchanger on the flow loop for receiving the reactant materials stream and any formed polymer and for removing heat of reaction or polymerization from the flow loop, and pump apparatus for pumping the reactant materials stream and formed polymer in the flow loop and from the first heat exchanger to the product polymer outlet. In one aspect, the system includes at least one additional heat exchanger on the flow loop for receiving the reactant materials stream and formed polymer and for removing heat of reaction or polymerization from the flow loop, the pump apparatus pumping formed polymer and remaining reactant materials to the product polymer outlet, and a portion of the formed polymer and remaining reactant materials flowing out from the product polymer outlet and the remainder recycling through the flow loop. In one aspect systems and methods according to the present invention are used to make polyethylene.

Abstract translation: 已经发明了通过使单体与催化剂和溶剂反应来使烯烃单体聚合的溶液聚合体系。 该系统在一个方面包括具有产物聚合物出口的流动回路，形成循环反应器的流动回路，流动回路上的催化剂入口，催化剂和溶剂通过该回路进入流动回路，流动回路上的单体入口， 单体和溶剂流入流动回路，并且与催化剂形成反应物料流，流动回路上用于接收反应物料流和任何形成的聚合物的第一热交换器，以及用于从流动回路除去反应或聚合的热量 以及泵装置，用于将反应物料流和形成的聚合物泵送在流动回路中并从第一热交换器泵送到产物聚合物出口。 在一个方面，该系统在流动回路上包括至少一个额外的热交换器，用于接收反应物料流和形成的聚合物，并用于从流动回路除去反应或聚合的热量，泵设备将形成的聚合物和剩余的反应物材料泵送到 产物聚合物出口，以及形成的聚合物的一部分和剩余的反应物料从产物聚合物出口流出，其余反应物质通过流动回路循环。 一方面，根据本发明的系统和方法用于制备聚乙烯。

公开(公告)号：US5792534A

公开(公告)日：1998-08-11

申请号：US475953

申请日：1995-06-07

Applicant: Jacquelyn A. deGroot ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Seema V. Karande ,  Laura K. Mergenhagen ,  Dan G. Moldovan ,  Kenneth B. Stewart ,  Nicole F. Whiteman

Inventor： Jacquelyn A. deGroot ,  Lonnie G. Hazlitt ,  Pradeep Jain ,  Seema V. Karande ,  Laura K. Mergenhagen ,  Dan G. Moldovan ,  Kenneth B. Stewart ,  Nicole F. Whiteman

IPC: B65D81/34 ,  B29C47/00 ,  B29K23/00 ,  B29L9/00 ,  B32B27/32 ,  B65D1/00 ,  B65D65/40 ,  C08F110/02 ,  C08F210/08 ,  C08F210/16 ,  C08J5/18 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/16 ,  C09J123/08

CPC classification number: C08L23/06 ,  B29C47/0004 ,  B29C47/0021 ,  B29C47/0026 ,  B32B27/32 ,  B32B27/322 ,  C08J5/18 ,  C08L23/0815 ,  C09J123/0815 ,  C08F110/02 ,  C08F210/16 ,  C08J2323/04 ,  C08J2323/08 ,  C08L2205/02 ,  C08L2314/06 ,  Y10T428/1334 ,  Y10T428/1352 ,  Y10T428/1393 ,  Y10T428/1397 ,  Y10T428/24992 ,  Y10T428/2826 ,  Y10T428/31913

Abstract: The subject invention provides a polymer mixture having high heat resistivity, low hexane extractive and controllably lower or higher modulus. The mixture is comprised of at least one first substantially linear ethylene polymer, Component (A), and at least one second ethylene polymer which is a homogeneously branched polymer, heterogeneously branched linear polymer or a non-short chain branched linear polymer. When fabricated into film, the mixture is characterized by a heat seal initiation temperature which is substantially lower than its Vicat softening point as well as a high ultimate hot tack strength. When fabricated as a molded article, the mixture is characterized by high microwave warp distortion while maintaining a lower modulus. The polymer mixture is particularly well-suited for use in multilayer film structures as a sealant layer for such applications as cook-in packages, hot-fill packages, and barrier shrink films. In molding applications, the mixture is well-suited as freezer-to-microwave food storage containers and lids which maintain good flexibility at low temperature to allow easy openability of such containers.

Abstract translation: 本发明提供了具有高耐热性，低己烷萃取和可控地更低或更高模量的聚合物混合物。 该混合物由至少一种第一基本上线性的乙烯聚合物，组分（A）和至少一种第二乙烯聚合物组成，其是均匀支化的聚合物，非均匀支化的线性聚合物或非短链支化的线型聚合物。 当制成膜时，混合物的特征在于热封起始温度明显低于其维卡软化点以及高极限热粘性强度。 当制造成模制品时，混合物的特征在于高的微波翘曲变形，同时保持较低的模量。 聚合物混合物特别适合用于多层膜结构，作为诸如煮熟包装，热填充包装和阻挡收缩膜之类的应用的密封剂层。 在成型应用中，该混合物非常适合作为冷冻至微波食品储存容器和盖子，其在低温下保持良好的柔韧性，以允许这种容器容易打开。

公开(公告)号：US5582923A

公开(公告)日：1996-12-10

申请号：US344262

申请日：1994-11-23

Applicant: Lawrence T. Kale ,  Pradeep Jain ,  David C. Kelley ,  Deepak R. Parikh ,  Sharon L. Baker ,  Osborne K. McKinney

Inventor： Lawrence T. Kale ,  Pradeep Jain ,  David C. Kelley ,  Deepak R. Parikh ,  Sharon L. Baker ,  Osborne K. McKinney

IPC: B29C47/00 ,  B29C47/02 ,  B32B27/08 ,  B32B27/32 ,  B32B37/15 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F110/00 ,  C08F110/02 ,  C08F210/16 ,  C08G83/00 ,  C08J5/18 ,  C08L23/02 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08 ,  C08L23/16 ,  C08J5/00

CPC classification number: C08J5/18 ,  B29C47/0004 ,  B29C47/02 ,  B32B27/08 ,  B32B27/32 ,  B32B27/322 ,  B32B37/153 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  C08G83/003 ,  C08L23/04 ,  C08L23/0815 ,  C08L23/16 ,  B29C47/00 ,  B29C47/0016 ,  B29K2023/06 ,  B29K2023/0641 ,  B29K2023/083 ,  B29K2995/0022 ,  C08F110/00 ,  C08F110/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08J2303/08 ,  C08J2323/04 ,  C08J2323/08 ,  C08L2205/02 ,  C08L23/02 ,  C08L23/06 ,  C08L2314/06 ,  Y10T428/31913 ,  Y10T428/31935 ,  Y10T428/31938

Abstract: An ethylene polymer extrusion composition having high draw down and substantially reduced neck-in, a process for making such a composition and a process of using such a composition to prepare extrusion coatings, extrusion profiles and extrusion cast films are disclosed. The ethylene polymer extrusion composition is made of 75-95 weight percent of at least one ethylene .alpha.-olefin interpolymer and 5-25 weight percent of at least one high pressure ethylene polymer characterized as having high melt strength and a broad, bimodal molecular weight distribution. In profiles, coatings or films, the composition can be used as sealant, adhesive or abuse resistance layers.

公开(公告)号：US09388254B2

公开(公告)日：2016-07-12

申请号：US13991836

申请日：2011-12-21

Applicant: Kishori Deshpande ,  Ravindra S. Dixit ,  Pradeep Jain

Inventor： Kishori Deshpande ,  Ravindra S. Dixit ,  Pradeep Jain

IPC: C08F210/16 ,  C08F2/14 ,  C08L23/08 ,  C08F4/76 ,  C08F10/02

CPC classification number: C08F4/76 ,  C08F4/659 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/16 ,  C08F2/14 ,  C08F210/14 ,  C08F2500/01 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/02 ,  C08F2500/12 ,  C08F4/64193

Abstract: The invention provides a polymerization process comprising polymerizing a reaction mixture comprising one or more monomer types, at least one catalyst, and at least one solvent, to form a polymer dispersion, and wherein the at least one catalyst is soluble in the at least one solvent, and wherein the polymer forms a dispersed phase in the solvent, and wherein the at least one solvent is a hydrocarbon. The invention provides a composition comprising an ethylene-based polymer comprising at least the following properties: a) a weight average molecular weight (Mw(abs)) greater than, or equal to, 60,000 g/mole; and b) a molecular weight distribution (Mw(abs)/Mn(abs)) greater than, or equal to, 2.3.

Abstract translation: 本发明提供聚合方法，其包括使包含一种或多种单体类型，至少一种催化剂和至少一种溶剂的反应混合物聚合以形成聚合物分散体，并且其中所述至少一种催化剂可溶于所述至少一种溶剂 ，并且其中所述聚合物在溶剂中形成分散相，并且其中所述至少一种溶剂是烃。 本发明提供一种包含乙烯基聚合物的组合物，其至少包括以下性质：a）大于或等于60,000g / mol的重均分子量（Mw（abs））; 和b）大于或等于2.3的分子量分布（Mw（abs）/ Mn（abs））。