Process for preparing precomposites based on nanotubes, particularly carbon nanotubes
    11.
    发明授权
    Process for preparing precomposites based on nanotubes, particularly carbon nanotubes 有权
    用于制备基于纳米管,特别是碳纳米管的预复合物的方法

    公开(公告)号:US09006327B2

    公开(公告)日:2015-04-14

    申请号:US12124403

    申请日:2008-05-21

    摘要: The subject of the present invention is a process for preparing a precomposite based on nanotubes, comprising bringing said nanotubes into contact with at least one given plasticizing agent.It also relates to a precomposite thus obtained, and to its use for conferring at least one electrical, mechanical and/or thermal property on a polymer material.It also relates to the use of a given plasticizer for improving the dispersion and/or mechanical properties and/or electrical conductivity and/or thermal conductivity of nanotubes in a polymer matrix.

    摘要翻译: 本发明的主题是一种制备基于纳米管的预复合物的方法,包括使所述纳米管与至少一种给定的增塑剂接触。 它还涉及由此获得的预复合物,以及其用于赋予聚合物材料上的至少一种电,机械和/或热性能的用途。 它还涉及使用给定的增塑剂来改善聚合物基质中纳米管的分散和/或机械性能和/或导电性和/或热导率。

    Process to make a conductive composition of a fluorinated polymer which contains polyaniline
    15.
    发明授权
    Process to make a conductive composition of a fluorinated polymer which contains polyaniline 失效
    制备含有聚苯胺的氟化聚合物的导电组合物的方法

    公开(公告)号:US07211202B2

    公开(公告)日:2007-05-01

    申请号:US10734596

    申请日:2003-12-15

    IPC分类号: H01B1/12

    摘要: The process of the present invention is a process to make a conductive fluorinated polymer composition (also called composite) wherein: a) an aqueous solution of an anilinium salt is mixed with an aqueous dispersion of a fluorinated polymer, b) then an oxidant is added to the mixture of step a) to make a blend of said fluorinated polymer and doped polyaniline (PANI), c) by-products and unreacted aniline are removed by washing with water or an alcohol to get a blend of purified fluorinated polymer and doped PANI, d) eventually the purified fluorinated polymer and doped PANI of step c) can be mixed with an acid, e) water is removed from the purified fluorinated polymer and doped PANI of step c) or d) if any and the remaining powder is melted and shaped in films, pellets or any object.

    摘要翻译: 本发明的方法是制备导电氟化聚合物组合物(也称为复合物)的方法,其中:a)将苯胺盐的水溶液与含氟聚合物的水分散体混合,b)然后加入氧化剂 与步骤a)的混合物制备所述氟化聚合物和掺杂的聚苯胺(PANI)的共混物,c)通过用水或醇洗涤除去副产物和未反应的苯胺,得到纯化的氟化聚合物和掺杂的PANI的混合物 d)最终纯化的氟化聚合物和步骤c)的掺杂PANI可以与酸混合,e)从纯化的氟化聚合物和步骤c)或d)的掺杂PANI中除去水,如果有的话,剩余的粉末熔化 并以薄膜,颗粒或任何物体成型。

    Conductive polymeric composite material with a resistance which is self-regulated by the temperature
    16.
    发明授权
    Conductive polymeric composite material with a resistance which is self-regulated by the temperature 失效
    导电聚合物复合材料,具有由温度自我调节的电阻

    公开(公告)号:US06790530B2

    公开(公告)日:2004-09-14

    申请号:US10608149

    申请日:2003-06-30

    IPC分类号: B32B1800

    摘要: The present invention relates to a composite material comprising, by weight, the total being 100% : A) 40 to 90% of PVDF homopolymer or copolymer crystallized essentially in the &bgr; form, B) 10 to 60% of a conductive filler, C) 0 to 40% of a crystalline or semi-crystalline polymer, D) 0 to 40% of a filler other than C, such that the crystals in the &bgr; form are nucleated on the surface of the particles of the conductive filler. This material is conductive with a resistance which is self-regulated by the temperature. It shows an increase in the resistance as a function of the temperature (PTC or “Positive Temperature Coefficient” effect), so that the intensity stabilizes at an equilibrium temperature.

    摘要翻译: 本发明涉及一种复合材料,其重量百分比为100%:A)40-90%的PVDF均聚物或基本上以β形式结晶的共聚物,B)10-60%的导电填料,C) 0至40%的结晶或半结晶聚合物,D)0至40%的C以外的填料,使得β型晶体在导电填料的颗粒表面成核。 该材料具有由温度自我调节的电阻导电。 它表现出作为温度(PTC或“正温度系数”效应)的函数的电阻的增加,使得强度在平衡温度下稳定。

    PROCESS FOR PRODUCING FIBROUS MATERIAL PRE-IMPREGNATED WITH THERMOSETTING POLYMER
    18.
    发明申请
    PROCESS FOR PRODUCING FIBROUS MATERIAL PRE-IMPREGNATED WITH THERMOSETTING POLYMER 审中-公开
    用热成型聚合物预先制备纤维材料的方法

    公开(公告)号:US20130248087A1

    公开(公告)日:2013-09-26

    申请号:US13885700

    申请日:2011-11-17

    IPC分类号: B32B37/02

    摘要: A method for producing a fibrous material including carbon fibres or glass fibres or plant fibres or polymer-based fibres, that are used alone or in a mixture, and are impregnated by a thermohardenable polymer using a mixture containing a hardener and carbon nanofillers, such as carbon nanotubes (CNT). A mixture containing said nanofillers, such as CNTs, and the hardener is used to introduce said nanofillers into the fibrous material. A continuous production line (L) for producing the material in the form of at least one calibrated and homogeneous strip (20) of reinforcing fibres impregnated with a thermohardenable polymer, includes the device (100) for arranging two series of fibres (1, 2) used to form a strip in such a way as to arrange the two series of fibres such that they are brought into contact with each other by means of two calendering devices.

    摘要翻译: 一种用于生产包含碳纤维或玻璃纤维或植物纤维或聚合物基纤维的纤维材料的方法,其单独使用或混合使用,并且使用含有硬化剂和碳纳米填料的混合物,由可热硬化的聚合物浸渍,例如 碳纳米管(CNT)。 使用含有所述纳米填料(例如CNT)和硬化剂的混合物将所述纳米填料引入纤维材料中。 用于生产以至少一种经过可热固化的聚合物浸渍的增强纤维的校准的均质带(20)形式的材料的连续生产线(L)包括用于布置两系列纤维(1,2)的装置(100) )用于形成条带,以便布置两束光纤,使得它们通过两个压延装置相互接触。

    METHOD FOR MANUFACTURING A POLYESTER COMPOSITION HAVING IMPROVED IMPACT PROPERTIES
    19.
    发明申请
    METHOD FOR MANUFACTURING A POLYESTER COMPOSITION HAVING IMPROVED IMPACT PROPERTIES 失效
    制备具有改进的冲击性能的聚酯组合物的方法

    公开(公告)号:US20120271004A1

    公开(公告)日:2012-10-25

    申请号:US13383533

    申请日:2010-07-13

    摘要: The invention relates to a method for manufacturing a thermoplastic composition including: a polyester resin (c); a mixture including a copolymer (a) of an α-olefin and of a monomer having an ethylenic unsaturation and an epoxy function, as well as a core-shell compound (b); characterized in that said method includes a first step of manufacture the mixture of (a) and (b) by extrusion at a temperature at which the copolymer (a) is in the molten state and at a maximum temperature of 60 to 180° C.; a second step of manufacturing the thermoplastic composition by extrusion or by mixing the polyester resin (c) with the mixture of (a) and (b) produced in the first step.

    摘要翻译: 本发明涉及一种热塑性组合物的制造方法,包括:聚酯树脂(c); 包含α-烯烃的共聚物(a)和具有烯属不饱和键和环氧官能团的单体以及核 - 壳化合物(b)的混合物; 其特征在于所述方法包括通过在共聚物(a)处于熔融状态和最高温度为60至180℃的温度下挤出制备(a)和(b)的混合物的第一步骤。 ; 通过挤出或通过将聚酯树脂(c)与在第一步骤中制备的(a)和(b)的混合物混合来制造热塑性组合物的第二步骤。