公开(公告)号：US09970101B2

公开(公告)日：2018-05-15

申请号：US15332562

申请日：2016-10-24

Applicant: Corning Incorporated

Inventor： Xinyuan Liu ,  Robert George Manley ,  Robert Michael Morena ,  Zhen Song

IPC: H01L29/16 ,  C01B31/04 ,  C23C16/26 ,  C03C17/22 ,  C04B41/85 ,  C23C16/02 ,  C23C16/44 ,  C01B32/182 ,  C01B32/186

CPC classification number: C23C16/26 ,  C01B32/182 ,  C01B32/186 ,  C03C17/22 ,  C03C2217/28 ,  C03C2218/152 ,  C04B41/85 ,  C23C16/0227 ,  C23C16/44 ,  Y10T428/24975 ,  Y10T428/25 ,  Y10T428/265 ,  Y10T428/30

Abstract: A catalyst-free CVD method for forming graphene. The method involves placing a substrate within a reaction chamber, heating the substrate to a temperature between 600° C. and 1100° C., and introducing a carbon precursor into the chamber to form a graphene layer on a surface of the substrate. The method does not use plasma or a metal catalyst to form the graphene.

公开(公告)号：US20160149260A1

公开(公告)日：2016-05-26

申请号：US14934297

申请日：2015-11-06

Applicant: Corning Incorporated

Inventor： Michael Edward Badding ,  Xinyuan Liu ,  Yanxia Ann Lu

IPC: H01M10/0562 ,  H01M4/90 ,  H01M10/0525 ,  H01M4/40 ,  H01M12/08 ,  H01M8/08

CPC classification number: H01M10/0562 ,  C04B35/486 ,  C04B2235/3203 ,  C04B2235/3227 ,  C04B2235/3251 ,  C04B2235/3286 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/5472 ,  C04B2235/5481 ,  C04B2235/764 ,  H01M4/382 ,  H01M4/405 ,  H01M4/525 ,  H01M4/9016 ,  H01M8/08 ,  H01M10/0525 ,  H01M10/0585 ,  H01M12/08 ,  H01M2300/0002 ,  H01M2300/0071

Abstract: An air stable solid garnet composition, comprising:a bulk composition and a surface protonated composition on at least a portion of the bulk composition as defined herein, and the protonated surface composition is present on at least a portion of the exterior surface of the bulk composition at a thickness of from 0.1 to 10,000 nm. Also disclosed is a composite electrolyte structure, and methods of making and using the composition and the composite electrolyte structure.

Abstract translation: 一种空气稳定的固体石榴石组合物，其包含：本体组合物和本文定义的本体组合物的至少一部分上的表面质子化组合物，并且质子化表面组合物存在于本体组合物的外表面的至少一部分上 厚度为0.1〜10,000nm。 还公开了复合电解质结构，以及制造和使用该组合物和复合电解质结构的方法。

公开(公告)号：US20150110998A1

公开(公告)日：2015-04-23

申请号：US14061342

申请日：2013-10-23

Applicant: Corning Incorporated

Inventor： Nicholas Francis Borrelli ,  Curtis Robert Fekety ,  Xinyuan Liu ,  Zhen Song

IPC: C23C16/02 ,  C23C16/26

CPC classification number: C23C16/0218 ,  C01B32/186 ,  C03C3/085 ,  C03C10/0027 ,  C03C17/22 ,  C03C2217/28 ,  C03C2218/345 ,  C04B41/009 ,  C04B41/52 ,  C23C16/26 ,  C30B25/18 ,  C30B29/02 ,  Y10T428/24149 ,  Y10T428/24851 ,  Y10T428/24917 ,  C04B41/5001 ,  C04B41/4531 ,  C04B41/51 ,  C04B41/0072 ,  C04B41/0009 ,  C04B35/19

Abstract: An insulating glass-ceramic substrate for synthesizing graphene includes discrete, crystalline, nanophase metallic regions capable of catalyzing graphene growth. The nanophase regions may be formed by thermal treatment of a glass-ceramic substrate containing the corresponding metal oxide. Single layer and double layer graphene are prepared on the modified glass-ceramic substrate in a vacuum chemical vapor deposition (CVD) process from hydrocarbon precursors. The graphene-coated glass-ceramic substrate is electrically conductive.

Abstract translation: 用于合成石墨烯的绝缘玻璃陶瓷基片包括能够催化石墨烯生长的离散的，结晶的纳米相金属区域。 可以通过热处理含有相应的金属氧化物的玻璃陶瓷基板来形成纳米相区域。 在来自碳氢化合物前体的真空化学气相沉积（CVD）方法中，在改性玻璃陶瓷基板上制备单层和双层石墨烯。 石墨烯涂覆的玻璃陶瓷基板是导电的。

公开(公告)号：US12037248B2

公开(公告)日：2024-07-16

申请号：US18211682

申请日：2023-06-20

Applicant: CORNING INCORPORATED ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Hui Bi ,  Fuqiang Huang ,  Xinyuan Liu ,  Zhen Song ,  Yufeng Tang ,  Tongping Xiu

IPC: B32B9/00 ,  C01B32/182 ,  C01B32/186 ,  C01B32/198 ,  C03C17/22 ,  C23C16/26 ,  B82Y30/00 ,  C23C16/50

CPC classification number: C01B32/198 ,  C01B32/182 ,  C01B32/186 ,  C03C17/22 ,  C23C16/26 ,  B82Y30/00 ,  C03C2217/28 ,  C03C2217/40 ,  C03C2217/70 ,  C03C2218/111 ,  C03C2218/153 ,  C23C16/50 ,  Y10T428/30

Abstract: Disclosed herein are methods for forming a graphene film on a substrate, the methods comprising depositing graphene on a surface of the substrate by a first vapor deposition step to form a discontinuous graphene crystal layer; depositing a graphene oxide layer on the discontinuous graphene crystal layer to form a composite layer; and depositing graphene on the composite layer by a second vapor deposition step, wherein the graphene oxide layer is substantially reduced to a graphene layer during the second vapor deposition step. Transparent coated substrates comprising such graphene films are also disclosed herein, wherein the graphene films have a resistance of less than about 10 KΩ/sq.

公开(公告)号：US20230369641A1

公开(公告)日：2023-11-16

申请号：US18225927

申请日：2023-07-25

Applicant: CORNING INCORPORATED ,  SHANGHAI INSTITUTE OF CERAMICS, CHINESE ACADEMY OF SCIENCES

Inventor： Michael Edward Badding ,  Yinghong Chen ,  Xiao Huang ,  Cai Liu ,  Xinyuan Liu ,  Yanxia Ann Lu ,  Zhen Song ,  Zhaoyin Wen ,  Tongping Xiu ,  Nathan Michael Zink

IPC: H01M10/0562 ,  C04B35/488 ,  C04B35/626 ,  C04B35/01 ,  C04B35/495 ,  C04B35/64 ,  C04B35/486 ,  H01M10/052 ,  C04B35/48

CPC classification number: H01M10/0562 ,  C04B35/488 ,  C04B35/6261 ,  C04B35/01 ,  C04B35/6262 ,  C04B35/495 ,  C04B35/64 ,  C04B35/486 ,  H01M10/052 ,  C04B35/62605 ,  C04B35/481 ,  C04B2235/602 ,  C04B2235/3208 ,  C04B2235/3244 ,  C04B2235/3227 ,  C04B2235/3203 ,  C04B2235/79 ,  C04B2235/5436 ,  C04B2235/786 ,  C04B2235/77 ,  C04B2235/3225 ,  C04B2235/3217 ,  C04B2235/6025 ,  C04B2235/96 ,  C04B2235/764 ,  C04B2235/3206 ,  C04B2235/85

Abstract: A composite ceramic including: a lithium garnet major phase; and a grain growth inhibitor minor phase, as defined herein. Also disclosed is a method of making composite ceramic, pellets and tapes thereof, a solid electrolyte, and an electrochemical device including the solid electrolyte, as defined herein.

公开(公告)号：US20230348275A1

公开(公告)日：2023-11-02

申请号：US18211682

申请日：2023-06-20

Applicant: CORNING INCORPORATED ,  Shanghai Institute of Ceramics, Chinese Academy of Sciences

Inventor： Hui Bi ,  Fuqiang Huang ,  Xinyuan Liu ,  Zhen Song ,  Yufeng Tang ,  Tongping Xiu

IPC: C01B32/198 ,  C01B32/182 ,  C01B32/186 ,  C03C17/22 ,  C23C16/26

CPC classification number: C01B32/198 ,  C01B32/182 ,  C01B32/186 ,  C03C17/22 ,  C23C16/26 ,  C23C16/50

Abstract: Disclosed herein are methods for forming a graphene film on a substrate, the methods comprising depositing graphene on a surface of the substrate by a first vapor deposition step to form a discontinuous graphene crystal layer; depositing a graphene oxide layer on the discontinuous graphene crystal layer to form a composite layer; and depositing graphene on the composite layer by a second vapor deposition step, wherein the graphene oxide layer is substantially reduced to a graphene layer during the second vapor deposition step. Transparent coated substrates comprising such graphene films are also disclosed herein, wherein the graphene films have a resistance of less than about 10 KΩ/sq.

公开(公告)号：US20230219840A1

公开(公告)日：2023-07-13

申请号：US18081790

申请日：2022-12-15

Applicant: CORNING INCORPORATED ,  ICFO- The Institute of Photonic Science ,  Institucio Catalana de Recerca i Estudis Avancats ( ICREA)

Inventor： Connie Li ,  Xinyuan Liu ,  Miriam Marchena Martín-Francés ,  Valerio Pruneri ,  Wageesha Senaratne ,  Zhen Song ,  Kamal Kishore Soni

IPC: C03C17/22 ,  C01B32/186 ,  C01B32/182

CPC classification number: C03C17/22 ,  C01B32/186 ,  C01B32/182 ,  C01B2204/02 ,  C01P2004/34 ,  C01P2004/64 ,  C01P2004/03 ,  C01P2004/62 ,  C03C2217/28 ,  C01B2204/04 ,  C01P2002/82 ,  C01P2002/85 ,  C03C2217/425 ,  C03C2218/328 ,  C03C2218/152 ,  C01B2204/32 ,  C03C2218/33 ,  C01P2004/02

Abstract: Disclosed herein are graphene coatings characterized by a porous, three-dimensional, spherical structure having a hollow core, along with methods for forming such graphene coatings on glasses, glass-ceramics, ceramics, and crystalline materials. Such coatings can be further coated with organic or inorganic layers and are useful in chemical and electronic applications.

公开(公告)号：US11548811B2

公开(公告)日：2023-01-10

申请号：US17359739

申请日：2021-06-28

Applicant: CORNING INCORPORATED ,  ICFO—The Institute of Photonic Science ,  Institució Catalana de Recerca i Estudis Avançats (ICREA)

Inventor： Connie Li ,  Xinyuan Liu ,  Miriam Marchena Martín-Francés ,  Valerio Pruneri ,  Wageesha Senaratne ,  Zhen Song ,  Kamal Kishore Soni

IPC: C03C17/22 ,  C01B32/186 ,  C01B32/182

Abstract: Disclosed herein are graphene coatings characterized by a porous, three-dimensional, spherical structure having a hollow core, along with methods for forming such graphene coatings on glasses, glass-ceramics, ceramics, and crystalline materials. Such coatings can be further coated with organic or inorganic layers and are useful in chemical and electronic applications.

公开(公告)号：US10593998B2

公开(公告)日：2020-03-17

申请号：US14934315

申请日：2015-11-06

Applicant: Corning Incorporated

Inventor： Michael Edward Badding ,  Paul Oakley Johnson ,  Xinyuan Liu

IPC: H01M10/00 ,  H01M10/36 ,  H01M4/40 ,  H01M10/052 ,  H01M10/0585 ,  H01M10/056 ,  H01M4/38 ,  H01M4/02 ,  H01M4/505

Abstract: A composite electrolyte tri-layer structure, including a first layer having a first ceramic electrolyte, where the first electrolyte is stable against contact with lithium metal, a second layer having a second ceramic electrolyte, where the second electrolyte is stable against aqueous contact, and a third layer having a third non-aqueous electrolyte interposed between the first layer and second layer, wherein the first electrolyte, the second electrolyte, and the third electrolyte each have a different relative chemical stability. Also disclosed is a method of making and using the tri-layer structure, and an energy storage article or device incorporating at least one of the tri-layer structures.

公开(公告)号：US20160149267A1

公开(公告)日：2016-05-26

申请号：US14934315

申请日：2015-11-06

Applicant: Corning Incorporated

Inventor： Michael Edward Badding ,  Paul Oakley Johnson ,  Xinyuan Liu

IPC: H01M10/36 ,  H01M4/40

Abstract: A composite electrolyte tri-layer structure, including: a first layer comprising a first ceramic electrolyte, which first electrolyte is stable against contact with lithium metal; a second layer comprising a second ceramic electrolyte, which second electrolyte is stable against aqueous contact; and a third layer comprising a third non-aqueous electrolyte interposed between the first layer and second layer, wherein the first electrolyte, the second electrolyte, and the third electrolyte each have a different relative chemical stability. Also disclosed is a method of making and using the tri-layer structure, and an energy storage article or device incorporating at least one of the tri-layer structures.

Abstract translation: 一种复合电解质三层结构，包括：第一层，包含第一电解质，第一电解质与锂金属接触是稳定的; 第二层，包括第二陶瓷电解质，所述第二电解质对水接触是稳定的; 以及第三层，其包含介于所述第一层和第二层之间的第三非水电解质，其中所述第一电解质，所述第二电解质和所述第三电解质各自具有不同的相对化学稳定性。 还公开了制造和使用三层结构的方法，以及结合三层结构中的至少一种的储能物品或装置。