摘要:
The present invention is directed to a composition made by reacting A) an aldehyde of 1 to 12 carbon atoms or a reactive equivalent thereof; and B) at least one etheramine represented by the formula R.sup.2 �O(CH.sub.2 CH(R)O).sub.n --R.sup.1 --NH.sub.2 !.sub.y(I) wherein each n is a number from 0 to about 50; each R is selected from the group consisting of hydrogen, hydrocarbyl groups of 1 to about 16 carbon atoms, and mixtures thereof; each R.sup.1 is selected from the group consisting of a hydrocarbylene group containing 2 to about 18 carbon atoms and a group represented by the formula ##STR1## wherein both R.sup.6 and R.sup.7 are hydrocarbylene groups of about 3 to about 10 carbon atoms and p is a number from 1 to 4; y is 1, 2, or 3; and each R.sup.2 is a hydrocarbyl group having a valence of y and containing 1 to about 50 carbon atoms when y is 1 and 1 to about 18 carbon atoms when y is 2 or 3; y is 1, 2, or 3; provided that when n is zero, y is 1. The reaction product can include a N-substituted perhydro-s-triazine represented by the formula ##STR2## Fuel additives containing these compositions are useful in reducing intake valve deposit and do not contribute to the increase in combustion chamber deposit in port fuel injected engines.
摘要:
A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently selected from members of the group consisting of: groups of the formula wherein R3 is H or hydrocarbyl, R4 is a divalent hydrocarbylene group, n=0 or 1, and each of R9 and R10 is independently H, alkoxyhydrocarbyl, hydroxyhydrocarbyl, hydrocarbyl, aminohydrocarbyl, N-alkoxyalkyl- or hydroxyalkyl-substituted aminohydrocarbyl, or a group of the formula &Parenopenst;Y&Parenclosest;cR11—M, wherein each Y is independently a group of the formula each R11 is a divalent hydrocarbyl group, R12 is as defined above for R9 and R10, and M is H, hydrocarbyl, amino, an amide group, an amide-containing group, an acylamino group, an imide group, or an imide-containing group, and c is 0 or a number ranging from 1 to about 100, or one of R9 and R10 taken together with the adjacent N constitute a N—N group; and each B is independently selected from members of the group of formula: wherein each X is independently O, S, or NRb, each Rb is independently H, NH2, hydrocarbyl, hydroxy-hydrocarbyl or aminohydrocarbyl, and each Z is independently a group of the formula wherein each of R3, R4, and n is as defined hereinabove; Ra is an ethylene group, a propylene group, which groups optionally have hydrocarbyl or hydroxyhydrocarbyl substituents, or wherein J is H, SH, NH2, or OH, and tautomers thereof; a is 0 or a number ranging from 1 to about 50, and b is a number ranging from 1 to about 30.
摘要:
This invention relates to a composition, comprising: (A) a compound represented by the formula RO(C4H8O)nCH2CH2CH2NH2 (I) wherein in formula (I), R is an aliphatic hydrocarbyl group of about 8 to about 30 carbon atoms, an n is a number in the range of about 12 to about 30; and (B) a compound selected from the group consisting of: a fatty acid; a fatty acid amide; a fatty acid ester; an amide, imide or ester derived from a hydrocarbyl substituted succinic acid or anhydride wherein the hydrocarbyl substituent has about 8 to about 30 carbon atoms; an alkoxylated amine, and mixtures of two or more thereof. The invention also relates to concentrates and fuels containing the foregoing composition.
摘要:
Various heterocyclic compounds have been discovered that impart improved fuel economy and friction modification to lubricant and fuel compositions. These hetrocyclic compounds of the invention preferably contain nitrogen and may be further reacted with hydrocarbyl carboxylic acid acylating reactants or hydrocarbyl phenolic reactants to give higher molecular materials. These higher molecular weight materials have higher oil-solubility and impart dispersancy properties to lubricant and fuel compositions.
摘要:
An internal combustion engine with a catalyst-containing exhaust-gas aftertreatment device is lubricated with a composition of a base oil; and a zinc salt of a mixture of phosphorus-containing compounds having hydrocarbyl groups R1 and R2 where the average total number of carbon atoms in R1 plus R2 for the mixture of phosphorus-containing compounds is at least 9.5, where 4 to 30 weight percent of such groups contain 2 to 4 carbon atoms and where in less than 8 mole percent of the phosphorus-containing molecules in the mixture of phosphorus-containing compounds each of R1 and R2 contain 2 to 4 carbon atoms.
摘要:
A fluid composition of (a) a friction modifier derived from the reaction of a carboxylic acid or a reactive equivalent thereof with an aminoalcohol, the friction modifier containing at least two hydrocarbyl groups; and (b) a dispersant other than a species of (a), provides good friction properties to an automatic transmission.
摘要:
This invention relates to low-sulfur diesel fuels which are useful with diesel engines equipped with exhaust system particulate traps. These fuels contain an effective mount of an organometallic complex to lower the ignition temperature of exhaust particles collected in the trap. The sulfur content of these diesel fuels is no more than about 0.1% by weight, preferably no more than about 0.05% by weight. The organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include .dbd.X, --XR, --NR.sub.2, --NO.sub.2, .dbd.NR, .dbd.NXR, .dbd.N--R*--XR, ##STR1## --CN, --N.dbd.NR and --N.dbd.CR.sub.2 ; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Fe, Co, Cu, Zn, B, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to methods of operating a diesel engine equipped with an exhaust system particulate trap using the foregoing low-sulfur diesel fuels.
摘要:
This invention relates to low-sulfur diesel fuels which are useful with diesel engines equipped with exhaust system particulate traps. These fuels contain an effective amount of an organometallic complex to lower the ignition temperature of exhaust particles collected in the trap. The sulfur content of these diesel fuels is no more than about 0.1% by weight, preferably no more than about 0.05% by weight. The organometallic complex is soluble or stably dispersible in the diesel fuel and is derived from (i) an organic compound containing at least two functional groups attached to a hydrocarbon linkage, and (ii) a metal reactant capable of forming a complex with the organic compound (i), the metal being any metal capable of reducing the ignition temperature of the exhaust particles. The functional groups include .dbd.X, --XR, --NR.sub.2, --NO.sub.2, .dbd.NR, .dbd.NXR, .dbd.N--R*--XR, ##STR1## --CN, --N.dbd.NR and --N.dbd.CR.sub.2 ; wherein X is O or S, R is H or hydrocarbyl, R* is hydrocarbylene or hydrocarbylidene, and a is a number (e.g., zero to about 10). Useful metals include Na, K, Mg, Ca, Sr, Ba, Ti, Zr, V, Cr, Mo, Mn, Fe, Co, Cu, Zn, B, Pb, Sb, and mixtures of two or more thereof. This invention is also directed to methods of operating a diesel engine equipped with an exhaust system particulate trap using the foregoing low-sulfur diesel fuels.
摘要:
This invention relates to metal salts of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each antion containing group is a group of the formula ##STR1## wherein each group in (II) is as described in the specification. These salts find utility in lubricants and fuels other than 2-cycle engine lubricants and fuels.
摘要:
This invention relates to lubricants for two-cycle engines comprising a major amount of at least one oil of lubricating viscosity and a minor amount of at least one compound of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each anion containing group is a group of the formula ##STR1## wherein T is selected from the group consisting of ##STR2## Additive concentrates and lubricant-fuel mixtures for two cycle engines are also disclosed as well as methods for operating two-cycle engines.