Sensor for determining the carbon monoxide concentration of a gas mixture
    12.
    发明申请
    Sensor for determining the carbon monoxide concentration of a gas mixture 审中-公开
    用于确定气体混合物的一氧化碳浓度的传感器

    公开(公告)号:US20050029102A1

    公开(公告)日:2005-02-10

    申请号:US10491255

    申请日:2002-10-02

    摘要: A sensor (1) for ascertaining a carbon monoxide concentration of a gas mixture (2), having a proton-conducting electrolyte (4) disposed between at least two electrochemically active electrodes (5, 6), in particular catalytically active electrodes (5, 6), of which at least one electrode is CO-sensitive, and in which a measurement unit (8) for measuring at least a first, electrical operating parameter of the sensor (1) at at least one electrode (5, 6) of the sensor (1) is provided, is proposed, with which calibration intervals are markedly lengthened and cross-sensitivities are minimized. This is attained according to the invention in that an evaluation unit (8) is provided for evaluating a change over time in the first, electrical operating parameter of the sensor (1) as a function of a known change over time of at least one second operating parameter.

    摘要翻译: 一种用于确定气体混合物(2)的一氧化碳浓度的传感器(1),其具有设置在至少两个电化学活性电极(5,6)之间的质子传导电解质(4),特别是催化活性电极(5, 6),其中至少一个电极是CO敏感的,其中用于在至少一个电极(5,6)处测量传感器(1)的至少第一电操作参数的测量单元(8) 提供了传感器(1),其中校准间隔被显着延长并且交叉敏感度被最小化。 这是根据本发明获得的,因为提供了评估单元(8),用于根据已知的至少一秒的时间变化的函数来评估传感器(1)的第一电操作参数中随时间的变化 操作参数。

    Chemical microreactors and method for producing same
    13.
    发明授权
    Chemical microreactors and method for producing same 有权
    化学微反应器及其制造方法

    公开(公告)号:US06409072B1

    公开(公告)日:2002-06-25

    申请号:US09380055

    申请日:1999-10-25

    IPC分类号: C03F120

    摘要: Chemical microreactors for chemical systhesis and their methods of manufacture are known, but have disadvantages such as extremely high manufacturing costs or poor flexibility for adaptation to various cases of application. These disadvantages are avoided by means of the microreactors and manufacturing methods according to the invention. The microreactors are characterized in that the reactors contain fluid ducts in at least one plane as well as feed and return lines for fluids, wherein the fluid ducts are defined by side walls of metal opposing each other and further side walls of metal or plastic extending between said side walls, and in which the planes are connected together and/or with a closure segment closing open fluid ducts by means of appropriate solder or adhesive layers. The manufacturing method is characterized by process sequences in which the individual reactor planes produced by means of electrolytic methods, are connected together by soldering or gluing.

    摘要翻译: 用于化学合成的化学微反应器及其制造方法是已知的,但是具有诸如制造成本极高的柔性以及适用于各种应用的难度的缺点。 这些缺点通过根据本发明的微反应器和制造方法来避免。 微反应器的特征在于,反应器在至少一个平面中包含流体管道以及用于流体的进料和返回管线,其中流体管道由相对的金属侧壁和金属或塑料的另一侧壁 所述侧壁,其中所述平面连接在一起,和/或通过适当的焊料或粘合剂层封闭开放的流体管道的闭合段。 制造方法的特征在于通过电解方法制造的各个反应堆平面通过焊接或胶合连接在一起的工艺顺序。

    Procedure for controlling the reducing agent in an exhaust gas post-processing system
    15.
    发明授权
    Procedure for controlling the reducing agent in an exhaust gas post-processing system 失效
    在排气后处理系统中控制还原剂的方法

    公开(公告)号:US07614220B2

    公开(公告)日:2009-11-10

    申请号:US11599898

    申请日:2006-11-14

    IPC分类号: F01N3/00

    摘要: The invention relates to a procedure for controlling the reducing agent in an exhaust gas post-processing system of a combustion machine with an exhaust gas duct, in which an SCR catalytic converter is provided in the direction of flow of the exhaust, wherein a reducing agent generation system has an NOx and CO/H2 generation unit,, an oxidation catalytic converter and a combined NOx storage / ammonia generation unit in the standard gas route of the reducing agent generation system, and, in order to reduce nitrogen oxide, ammonia is added as a reducing agent in front of the SCR catalytic converter by the reducing agent generation system, wherein source materials for the generation of ammonia are at least intermittently added to the NOx and CO/H2 generation unit via a fuel supply line and via an air supply line, wherein during the fat phase the air/fuel composition is changed in front of the oxidation catalytic converter in the form of a lambda modulation for a lambda value. It can thus be achieved that, in pulse mode, a high H2/CO yield can be achieved with a simultaneously low HC slip and the higher HC penetrations associated with the natural aging of the catalytic converter and the decreasing H2/CO yields are compensated. Influences resulting from the reactor geometry of the oxidation catalytic converter can be influences or compensated with the procedure in terms of its drive-away characteristic.

    摘要翻译: 本发明涉及一种用于控制具有废气管道的燃烧机的废气后处理系统中的还原剂的方法,其中SCR催化转化器沿排气方向设置,其中还原剂 发电系统在还原剂生成系统的标准气体路径中具有NOx和CO / H2生成单元,氧化催化转化器和组合的NOx储存/氨生成单元,为了还原氮氧化物,添加氨 作为通过还原剂生成系统在SCR催化转化器前面的还原剂,其中用于产生氨的源材料经由燃料供给管线至少间歇地添加到NOx和CO / H2生成单元,并且经由空气供给 线,其中在脂肪相期间,空气/燃料组合物以λ值的λ调制形式在氧化催化转化器之前改变。 因此,可以实现在脉冲模式中,可以同时具有低HC滑移并且与催化转化器的自然老化相关联的较高的HC渗透和降低的H 2 / CO收率来实现高的H 2 / CO收率。 由氧化催化转化器的反应器几何结构产生的影响可以根据其驱走特性的程序来影响或补偿。

    Method for metering ammonia into the exhaust-gas region of an internal combustion engine and device for implementing the method
    16.
    发明授权
    Method for metering ammonia into the exhaust-gas region of an internal combustion engine and device for implementing the method 有权
    用于将氨计量到内燃机的排气区域中的方法和用于实施该方法的装置

    公开(公告)号:US07373775B2

    公开(公告)日:2008-05-20

    申请号:US11023210

    申请日:2004-12-21

    IPC分类号: F01N3/00 F01N3/10

    摘要: A method for metering ammonia into the exhaust-gas region of an internal combustion engine and a device for implementing the method. The ammonia storage capacity of an SCR catalytic converter situated in the exhaust-gas region of the internal combustion engine is utilized. After the internal combustion engine has been switched off, ammonia is introduced into the exhaust-gas region in front of the SCR catalytic converter. Thus, following a renewed start-up of the internal combustion engine, the ammonia required in the SCR catalytic converter for reducing the nitrogen oxides contained in the exhaust gas of the internal combustion engine are already available before an ammonia source is ready for operation. The procedure eliminates the need for a pressure storage of ammonia in the switched-off state of the internal combustion engine.

    摘要翻译: 用于将氨计量到内燃机的排气区域中的方法和用于实施该方法的装置。 使用位于内燃机的排气区域中的SCR催化转化器的氨储存容量。 在关闭内燃机之后,将氨引入SCR催化转化器前面的废气区域。 因此,在内燃机的更新启动之后,在氨源准备运行之前,SCR催化转化器中所需的用于还原内燃机废气中的氮氧化物所需的氨已经可用。 该过程消除了在内燃机的关闭状态下对氨的压力存储的需要。

    Device and procedure for the production of ammonia

    公开(公告)号:US20070202031A1

    公开(公告)日:2007-08-30

    申请号:US11602898

    申请日:2006-11-20

    IPC分类号: B01D53/34 F01N3/10

    摘要: The invention concerns a device to produce ammonia as a reducing agent for the selective catalytic reduction (SCR) of nitrogen oxides in the exhaust gas of a combustion source, especially of an internal combustion engine, whereby the ammonia is admixed with the exhaust gas in the direction of flow in front of a SCR-catalytic converter. In so doing, provision is made for a nitrogen oxide production unit separated from the combustion source and its exhaust gas duct and a hydrogen production unit separated from the combustion source and its exhaust gas duct; and nitrogen oxide of the nitrogen oxide production unit and the hydrogen of the hydrogen production unit are delivered at least to a storage catalytic converter or a nitrogen oxide storage and a subsequently connected catalytic converter for the storage of the nitrogen oxide and for the formation of ammonia. The invention concerns additionally a procedure for the production of ammonia as a reducing agent for the selective catalytic reduction (SCR) of nitrogen oxides in the exhaust gas of a combustion source, especially of an internal combustion engine, whereby the ammonia is admixed with the exhaust gas in the direction of flow in front of a SCR-catalytic converter. In so doing, nitrogen oxide is produced in a nitrogen oxide production unit separate from the combustion source an its exhaust gas duct and is stored in at least one storage catalytic converter or a nitrogen oxide storage and a subsequently connected catalytic converter. Furthermore, hydrogen and/or a hydrogen-carbon monoxide-mixture is produced in a hydrogen production unit separated from the combustion source and its exhaust gas duct and delivered to a storage catalytic converter. Hydrogen and the stored nitrogen oxide are converted catalytically to ammonia in the storage catalytic converter or in the catalytic converter. Device and procedure allow for a self-sufficient production of ammonia outside of the exhaust gas tract of the combustion source and without an intervention into the operating parameters of the combustion source, whereby operating resources normally transported exclusively in a motor vehicle are used.

    Control of air flow for apparatus to produce reduction agents
    18.
    发明申请
    Control of air flow for apparatus to produce reduction agents 审中-公开
    控制装置生产还原剂的气流

    公开(公告)号:US20070108039A1

    公开(公告)日:2007-05-17

    申请号:US11599887

    申请日:2006-11-14

    IPC分类号: H05F3/00 B01J19/08

    摘要: The invention concerns a device for the production of ammonia for the selective catalytic reduction of nitrogen oxides in the exhaust of an internal combustion engine with an air supply. If the air supply includes a power supply, which is independent of the power of the internal combustion engine, and which powers a compression stage for air supply, the result would be an efficient production of reduction agents even under varying operating conditions of the internal combustion engine and the addition of the reduction agent in proper amounts to the exhaust to be cleaned.

    摘要翻译: 本发明涉及用于生产氨的装置,用于选择性地催化还原具有空气供应的内燃机排气中的氮氧化物。 如果空气源包括独立于内燃机的功率的电源,并且为供气供应的压缩级供电,则结果将是即使在内燃的变化的操作条件下还原剂的有效生产 发动机和将还原剂以适当的量添加到待清洁的废气中。