公开(公告)号：US5169829A

公开(公告)日：1992-12-08

申请号：US873351

申请日：1992-04-21

申请人： Nobuhiko Fujita ,  Hideo Itozaki ,  Saburo Tanaka ,  Naoji Fujimori ,  Takahiro Imai ,  Keizo Harada ,  Shuji Yazu ,  Tetsuji Jodai ,  Noriyuki Yoshida ,  Satoshi Takano ,  Kenji Miyazaki ,  Noriki Hayashi

发明人： Nobuhiko Fujita ,  Hideo Itozaki ,  Saburo Tanaka ,  Naoji Fujimori ,  Takahiro Imai ,  Keizo Harada ,  Shuji Yazu ,  Tetsuji Jodai ,  Noriyuki Yoshida ,  Satoshi Takano ,  Kenji Miyazaki ,  Noriki Hayashi

IPC分类号： H01L39/24

CPC分类号： H01L39/249 ,  H01L39/2435 ,  H01L39/2464 ,  Y10S505/73 ,  Y10S505/742

摘要： An improvement in a process for manufacturing a superconductor, characterized by irradiating a material composed of compound oxide by one of ion beams selected from oxygen ion beam, inert gas ion beams and an ion beam consisting of a mixture of oxygen gas and inert gas to convert said material into a superconductor. When a focused ion beam is directed onto desired areas on said film layer, the areas irradiated by the ion beam are converted to a superconductor in a form of a superconducting circuit.

摘要翻译： 一种制造超导体的方法的改进，其特征在于，通过从氧离子束，惰性气体离子束和由氧气和惰性气体的混合物组成的离子束中的一种离子束照射由复合氧化物组成的材料，以转换 将材料称为超导体。 当聚焦离子束被引导到所述膜层上的所需区域上时，由离子束照射的区域被转换为超导电路形式的超导体。

公开(公告)号：US5334252A

公开(公告)日：1994-08-02

申请号：US952928

申请日：1992-09-25

申请人： Noriyuki Yoshida ,  Satoshi Takano ,  Shigeru Okuda ,  Noriki Hayashi ,  Tsukushi Hara ,  Kiyoshi Okaniwa ,  Takahiko Yamamoto

发明人： Noriyuki Yoshida ,  Satoshi Takano ,  Shigeru Okuda ,  Noriki Hayashi ,  Tsukushi Hara ,  Kiyoshi Okaniwa ,  Takahiko Yamamoto

IPC分类号： C01B13/14 ,  C01G1/00 ,  C01G3/00 ,  C23C14/00 ,  C23C14/08 ,  C23C14/28 ,  C23C14/34 ,  C30B23/08 ,  C30B29/22 ,  H01B12/06 ,  H01B13/00 ,  H01L39/24

CPC分类号： C23C14/087 ,  C23C14/0021 ,  C23C14/28 ,  H01L39/2448 ,  Y10S505/73 ,  Y10S505/732 ,  Y10S505/786

摘要： In order to enable formation of a smooth and dense oxide superconducting film with no clear appearance of grain boundaries in a fine structure even at a high film forming rate, a laser ablation method is employed to apply a laser beam 2 to a target 1 containing components of an oxide superconductive material and deposit particles, which are thus scattered from the target 1, on a substrate 3, while gaseous oxygen is supplied from a gaseous oxygen inlet 7 toward laser plasma 6, which is generated by the application of the laser beam 2.

摘要翻译： 为了即使在成膜速度高的情况下，也能够在精细结构中形成平滑且致密的氧化物超导膜，而且在精细结构中不会形成明显的晶界，因此采用激光烧蚀方法将激光束2施加于含有成分 的氧化物超导材料和从靶1散射的沉积颗粒在基板3上，同时从气态氧气入口7向激光等离子体6供应气态氧，激光等离子体6是通过施加激光束2 。

公开(公告)号：US5330966A

公开(公告)日：1994-07-19

申请号：US905994

申请日：1992-06-26

申请人： Noriki Hayashi ,  Satoshi Takano

发明人： Noriki Hayashi ,  Satoshi Takano

IPC分类号： H01L39/24 ,  B05D5/12 ,  C23C16/00

CPC分类号： H01L39/2451 ,  H01L39/2464 ,  Y10S505/704 ,  Y10S505/73 ,  Y10S505/731 ,  Y10S505/732 ,  Y10S505/734 ,  Y10S505/742

摘要： An oxide superconducting layer is formed on a base material of silver, whose single side is coated with MgO, or single-crystalline MgO for depositing a Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 phase in a crystallographically oriented state by sputtering, CVD or laser ablation. Metal lead or lead oxide is then laid thereon by sputtering to obtain a two-layer structure, and the two-layer structure is heat treated in the atmospheric air. Thus, a bismuth oxide superconducting film, which is excellent in crystal orientation as well as denseness and thereby having high critical current density, is formed on the base material.

摘要翻译： 在银的基体材料上形成氧化物超导层，其单面涂覆有MgO，或者通过溅射，CVD或激光烧蚀在晶体取向状态下沉积Bi2Sr2Ca2Cu3相的单晶MgO。 然后通过溅射将金属铅或氧化铅放置在其上以获得双层结构，并且在大气中对该二层结构进行热处理。 因此，在基材上形成结晶取向性和密度优异，从而具有高临界电流密度的氧化铋超导膜。

公开(公告)号：US5312802A

公开(公告)日：1994-05-17

申请号：US613868

申请日：1990-11-29

申请人： Noriki Hayashi ,  Satoshi Takano ,  Shigeru Okuda ,  Hajime Hitotsuyanagi

发明人： Noriki Hayashi ,  Satoshi Takano ,  Shigeru Okuda ,  Hajime Hitotsuyanagi

IPC分类号： H01B12/06 ,  H01B13/00 ,  H01F6/06 ,  H01L39/24 ,  H01F7/22 ,  H01B12/02

CPC分类号： H01F6/06 ,  H01B12/06 ,  H01L39/248 ,  Y02E40/642 ,  Y10S505/70 ,  Y10S505/704 ,  Y10S505/705

摘要： An oxide superconductive wire is provided by, for example, forming an oxide superconductive layer on a tape-type flexible base. A preliminary compressive strain is applied to the oxide superconductive layer in the longitudinal direction. The remaining strain can be provided by using a base having thermal expansion coefficient larger than that of the oxide superconductive layer and by cooling the same after heat treatment, due to contraction of the base. Since the preliminary compressive strain is applied to the oxide superconductive layer, degradation of superconductivity of the oxide superconductive layer can be suppressed even if the oxide superconductive wire is bent in any direction, compared with the wire without such strain. Therefore, the oxide superconductive wire can be coiled, for example, without much degrading the superconductivity.

摘要翻译： PCT No.PCT / JP90 / 00422 Sec。 371日期1990年11月29日第 102（e）1990年11月29日PCT PCT 1990年3月29日PCT公布。 WO90 / 12408 PCT出版物 日期1990年10月18日。氧化物超导线例如通过在带状柔性基底上形成氧化物超导层而提供。 在纵向上对氧化物超导层施加预压缩应变。 可以通过使用具有大于氧化物超导层的热膨胀系数的碱的基底，并且由于基底的收缩而在热处理后对其进行冷却来提供剩余的应变。 由于将预压缩应变施加到氧化物超导层上，与没有这种应变的线相比，即使氧化物超导线在任何方向上弯曲，也可以抑制氧化物超导层的超导性的劣化。 因此，氧化物超导线例如可以卷绕，而不会使超导性降低。

公开(公告)号：US5187148A

公开(公告)日：1993-02-16

申请号：US662874

申请日：1991-03-01

申请人： Noriyuki Yoshida ,  Satoshi Takano ,  Shigeru Okuda ,  Noriki Hayashi ,  Tsukushi Hara ,  Kiyoshi Okaniwa ,  Takahiko Yamamoto

发明人： Noriyuki Yoshida ,  Satoshi Takano ,  Shigeru Okuda ,  Noriki Hayashi ,  Tsukushi Hara ,  Kiyoshi Okaniwa ,  Takahiko Yamamoto

IPC分类号： C01B13/14 ,  C01G1/00 ,  C01G3/00 ,  C23C14/00 ,  C23C14/08 ,  C23C14/28 ,  C23C14/34 ,  C30B23/08 ,  C30B29/22 ,  H01B12/06 ,  H01B13/00 ,  H01L39/24

CPC分类号： C23C14/087 ,  C23C14/0021 ,  C23C14/28 ,  H01L39/2448 ,  Y10S505/73 ,  Y10S505/732 ,  Y10S505/786

摘要： In order to enable formation of a smooth and dense oxide superconducting film with no clear appearance of grain boundaries in a fine structure even at a high film forming rate, a laser ablation method is employed to apply a laser beam 2 to a target 1 containing components of an oxide superconductive material and deposit particles, which are thus scattered from the target 1, on a substrate 3, while gaseous oxygen is supplied from a gaseous oxygen inlet 7 toward laser plasma 6, which is generated by the application of the laser beam 2.

公开(公告)号：US5017550A

公开(公告)日：1991-05-21

申请号：US175214

申请日：1988-03-30

申请人： Jun Shioya ,  Yoichi Yamaguchi ,  Akira Mizoguchi ,  Noriyuki Yoshida ,  Kenichi Takahashi ,  Kenji Miyazaki ,  Satoshi Takano ,  Noriki Hayashi

发明人： Jun Shioya ,  Yoichi Yamaguchi ,  Akira Mizoguchi ,  Noriyuki Yoshida ,  Kenichi Takahashi ,  Kenji Miyazaki ,  Satoshi Takano ,  Noriki Hayashi

IPC分类号： B32B18/00 ,  C04B35/45 ,  C04B41/50 ,  C04B41/52 ,  C04B41/85 ,  C04B41/89 ,  H01L39/24

CPC分类号： C04B41/009 ,  C04B35/45 ,  C04B35/4504 ,  C04B41/5074 ,  C04B41/52 ,  C04B41/85 ,  C04B41/89 ,  H01L39/2425 ,  H01L39/2432 ,  H01L39/2451 ,  H01L39/248 ,  Y10S505/704 ,  Y10S505/732

摘要： A thin film of an oxide superconductor having a homogeneous composition and less oxygen defects is produced by independently vaporizing onto a substrate at least one material selected from the group consisting of the elements of Ia, IIa and IIIa groups of the periodic table and their compounds and one material selected from the group consisting of Cu and its compounds and irradiating the substrate with oxygen ions and depositing the vaporized materials together with oxygen on the substrate to form the thin film of the oxide superconductor.

公开(公告)号：US4891355A

公开(公告)日：1990-01-02

申请号：US234976

申请日：1988-08-22

申请人： Noriki Hayashi ,  Satoshi Takano ,  Kenji Miyazaki ,  Noriyuki Yoshida

发明人： Noriki Hayashi ,  Satoshi Takano ,  Kenji Miyazaki ,  Noriyuki Yoshida

IPC分类号： C04B41/80 ,  C01G1/00 ,  H01B12/06 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/2464 ,  Y10S430/146 ,  Y10S505/731 ,  Y10S505/732 ,  Y10S505/739 ,  Y10S505/815 ,  Y10S505/816 ,  Y10S505/817 ,  Y10S505/818 ,  Y10S505/819 ,  Y10S505/82 ,  Y10S505/822 ,  Y10T29/49014

摘要： A method of producing a superconducting circuit by forming a film having a superconducting phase on a substrate and applying a laser beam to a part of the superconducting phase to cause transition of the part of the superconducting phase into a non-superconducting phase.

公开(公告)号：US5232909A

公开(公告)日：1993-08-03

申请号：US862103

申请日：1992-05-08

申请人： Satoshi Takano ,  Kenichi Takahashi ,  Kenji Miyazaki ,  Noriyuki Yoshida ,  Shinji Inazawa ,  Noriki Hayashi

发明人： Satoshi Takano ,  Kenichi Takahashi ,  Kenji Miyazaki ,  Noriyuki Yoshida ,  Shinji Inazawa ,  Noriki Hayashi

IPC分类号： B32B18/00 ,  C01G3/00 ,  C04B35/45 ,  C04B41/50 ,  C04B41/52 ,  C04B41/85 ,  C04B41/89 ,  H01L23/532 ,  H01L39/24

CPC分类号： C04B41/52 ,  C01G3/006 ,  C04B35/45 ,  C04B35/4504 ,  C04B35/4508 ,  C04B41/5074 ,  C04B41/85 ,  C04B41/89 ,  H01L23/53285 ,  H01L39/2425 ,  H01L39/2432 ,  H01L39/2451 ,  H01L39/2461 ,  H01L39/248 ,  C01P2002/34 ,  H01L2924/0002 ,  Y10S505/704 ,  Y10S505/733 ,  Y10S505/734 ,  Y10S505/735 ,  Y10S505/737 ,  Y10S505/742

摘要： A superconducting ceramics elongated body comprising a flexible ceramics elongated substrate and an oxide ceramics superconducting layer formed at least on a part of the surface of the ceramics elongated substrate to longitudinally extend along the ceramics elongated substrate. The superconducting ceramics elongated body further comprises a protective layer of ceramics containing a nitride, which is provided to at least cover the surface of the superconducting layer exposed on the ceramics elongated substrate. A method of manufacturing a superconducting ceramics elongated body by forming a longitudinally continuous superconducting layer on at least a part of the surface of a flexible ceramics elongated substrate. The superconducting layer is formed on the elongated substrate by a sol-gel method, a coating/sintering method, evaporation under oxygen ions, deposition from a fluoride solution or oxidation after application of corresponding fluorides.

摘要翻译： 一种超导陶瓷细长体，其包括柔性陶瓷细长衬底和至少形成在所述陶瓷细长衬底的表面的一部分上的氧化物陶瓷超导层，以沿着所述陶瓷细长衬底纵向延伸。 超导陶瓷细长体还包括含有氮化物的陶瓷保护层，其被设置成至少覆盖暴露在陶瓷细长衬底上的超导层的表面。 一种通过在柔性陶瓷细长基板的表面的至少一部分上形成纵向连续的超导层来制造超导陶瓷细长体的方法。 通过溶胶 - 凝胶法，涂覆/烧结法​​，在氧离子下蒸发，在氟化物溶液中沉积或在施加相应的氟化物后进行氧化，在细长衬底上形成超导层。

公开(公告)号：US5143898A

公开(公告)日：1992-09-01

申请号：US475048

申请日：1990-02-05

申请人： Satoshi Takano ,  Noriki Hayashi

发明人： Satoshi Takano ,  Noriki Hayashi

IPC分类号： B32B18/00 ,  C04B35/45 ,  C04B35/486 ,  H01L39/14

CPC分类号： C04B35/486 ,  C04B35/45 ,  H01L39/143 ,  Y10S428/93 ,  Y10S505/701 ,  Y10S505/702 ,  Y10S505/703 ,  Y10S505/704 ,  Y10T428/31

摘要： A superconducting wire comprises a flexible base material having average surface roughness of not more than 0.05 .mu.m and an oxide superconducting layer formed on the base material.A superconducting wire comprises a flexible base material of yttria stabilized zirconia containing less than 0.1 percent by weight of an Al impurity and an oxide superconducting layer formed on the base material.

公开(公告)号：US5130296A

公开(公告)日：1992-07-14

申请号：US677700

申请日：1991-03-29

申请人： Satoshi Takano ,  Shigeru Okuda ,  Noriyuki Yoshida ,  Noriki Hayashi ,  Kenichi Sato

发明人： Satoshi Takano ,  Shigeru Okuda ,  Noriyuki Yoshida ,  Noriki Hayashi ,  Kenichi Sato

IPC分类号： C01B13/14 ,  C01G1/00 ,  C01G3/00 ,  H01B12/00 ,  H01B12/06 ,  H01B13/00 ,  H01L39/24

CPC分类号： H01L39/2454 ,  Y10S505/732

摘要： When an oxide superconducting thin film is formed on a substrate by a vapor phase method such as laser ablation, for example, a plurality of grooves are formed on the substrate by photolithography or beam application in the same direction with an average groove-to-groove pitch of not more than 10 .mu.m, so that the oxide superconducting thin film is formed on a surface provided with such a plurality of grooves. Thus promoted is growth of crystals of the oxide superconducting thin film in parallel with the grooves, whereby respective directions of a-axes and c-axes are regulated to some extent. This improves critical current density of the oxide superconducting thin film.