公开(公告)号：US09543567B2

公开(公告)日：2017-01-10

申请号：US13613889

申请日：2012-09-13

申请人： Naoto Ohira ,  Ryuta Sugiura ,  Shohei Yokoyama ,  Miho Endo ,  Koji Kimura ,  Tsutomu Nanataki

发明人： Naoto Ohira ,  Ryuta Sugiura ,  Shohei Yokoyama ,  Miho Endo ,  Koji Kimura ,  Tsutomu Nanataki

IPC分类号： B05D5/12 ,  H01M4/04 ,  H01M4/1391 ,  H01M10/052

CPC分类号： H01M4/0471 ,  H01M4/1391 ,  H01M10/052 ,  Y02E60/122 ,  Y02P70/54

摘要： The present invention relates to a method for manufacturing cathode active material for a lithium secondary battery. The manufacturing method according to the present invention is characterized by including: (1) an intermediate generation process, wherein an intermediate which is powder or a shaped object containing the first material compound which is a compound of the transition metal other than lithium, which constitutes said lithium composite oxide, is generated, (2) a lithium source compound addition process, wherein the second material compound which is a lithium compound is added so that the second material compound in the shape of film may adhere to the surface of said intermediate, and (3) a sintering process, wherein lithium composite oxide is generated by sintering said intermediate in the state where said second material compound has adhered to its surface.

摘要翻译： 本发明涉及锂二次电池用正极活性物质的制造方法。 根据本发明的制造方法的特征在于包括：（1）中间生成工序，其中，作为粉末或成形体的中间体，其含有除锂以外的过渡金属的化合物的第一原料化合物，其构成 所述锂复合氧化物，（2）锂源化合物添加工序，其中添加作为锂化合物的第二材料化合物，使得膜形状的第二材料化合物可能粘附到所述中间体的表面， 和（3）烧结工艺，其中通过在所述第二材料化合物粘附到其表面的状态下烧结所述中间体而产生锂复合氧化物。

公开(公告)号：US08597567B2

公开(公告)日：2013-12-03

申请号：US12612034

申请日：2009-11-04

申请人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

发明人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

IPC分类号： C01D15/02 ,  C01G33/00

CPC分类号： C04B35/475 ,  C04B35/495 ,  C04B35/62218 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3255 ,  C04B2235/3291 ,  C04B2235/3298 ,  C04B2235/5445 ,  C04B2235/6025 ,  C04B2235/6562 ,  C04B2235/6587 ,  C04B2235/77 ,  C04B2235/787 ,  C04B2235/79 ,  C04B2235/9623 ,  H01L41/1873 ,  H01L41/43

摘要： A ceramic sheet is produced by a method in which inorganic particles including, as a main component, an oxide represented by general formula ABO3 and containing a volatile component are mixed such that the A/B ratio is 1.05 or more, the inorganic particles are formed into a self-supported planar shaped body with a thickness of 30 μm or less, and the shaped body is fired, without an inactive layer or with an inactive layer which does not substantially react with the shaped body and is disposed adjacent to the shaped body, at a temperature-rising rate of 30° C./min or more in a temperature range which is equal to or higher than a temperature at which the volatile component is volatilized.

摘要翻译： 通过将以通式ABO3表示的含有挥发性成分的氧化物作为主要成分的无机粒子混合，使A / B比为1.05以上的方法制造陶瓷片，形成无机粒子 成为具有30μm以下的自支撑平面状体，成形体被烧成而不具有非活性层或不与成形体基本上反应的非活性层，并与成形体相邻配置 在等于或高于挥发性成分挥发的温度的温度范围内以30℃/分钟以上的升温速度进行。

公开(公告)号：US08212455B2

公开(公告)日：2012-07-03

申请号：US12358559

申请日：2009-01-23

申请人： Yukinobu Yura ,  Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

发明人： Yukinobu Yura ,  Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

IPC分类号： H01L41/08

CPC分类号： H01L41/0973 ,  C01G23/003 ,  C01G25/00 ,  C01G25/006 ,  C01G33/006 ,  C01G35/006 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/62 ,  C01P2004/80 ,  C01P2006/40 ,  C04B35/462 ,  C04B35/475 ,  C04B35/493 ,  C04B35/495 ,  C04B35/6262 ,  C04B35/62685 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3251 ,  C04B2235/3255 ,  C04B2235/3279 ,  C04B2235/3298 ,  C04B2235/365 ,  C04B2235/5292 ,  C04B2235/5445 ,  C04B2235/6025 ,  C04B2235/768 ,  C04B2235/787 ,  H01L41/083 ,  H01L41/1873 ,  H01L41/1876 ,  H01L41/1878 ,  H01L41/43 ,  Y10T29/42

摘要： An actuator includes a fired ceramic substrate having a space opened downward, a first electrode formed on the upper surface of the fired ceramic substrate above the space, a piezoelectric/electrostrictive body formed on the first electrode so that the volume changes with input and output of electric power, and a second electrode formed on the piezoelectric/electrostrictive body. The piezoelectric/electrostrictive body is composed of Pb(Zr1-xTix)O3 or (Li, Na, K) (Nb, Ta)O3 as a main component and contains crystals oriented along the direction of an electric field. In the actuator, the degree of orientation of the piezoelectric/electrostrictive body can be increased regardless of the orientation of the substrate on which the piezoelectric/electrostrictive body is formed.

摘要翻译： 致动器包括具有向下开口的烧制陶瓷基板，形成在空间上方的烧结陶瓷基板的上表面上的第一电极，形成在第一电极上的压电/电致伸缩体，使得体积随着输入和输出而变化 电力和形成在压电/电致伸缩体上的第二电极。 压电/电致伸缩体由Pb（Zr1-xTix）O3或（Li，Na，K）（Nb，Ta）O3作为主要成分构成，并含有沿电场方向取向的晶体。 在致动器中，可以增加压电/电致伸缩体的取向度，而不管其上形成有压电/电致伸缩体的基板的取向如何。

公开(公告)号：US20050269929A1

公开(公告)日：2005-12-08

申请号：US11145004

申请日：2005-06-02

申请人： Iwao Ohwada ,  Kei Sato ,  Nobuyuki Kobayashi ,  Shohei Yokoyama

发明人： Iwao Ohwada ,  Kei Sato ,  Nobuyuki Kobayashi ,  Shohei Yokoyama

IPC分类号： H01J1/00 ,  H01J1/02 ,  H01J1/14 ,  H01J1/312 ,  H01J1/32 ,  H01J9/02

CPC分类号： H01J1/32 ,  B82Y10/00 ,  H01J1/312 ,  H01J9/022

摘要： An electron emitter includes an emitter layer formed of a dielectric material, an upper electrode, and a lower electrode. A drive voltage is applied between the upper electrode and the lower electrode, for emitting electrons. The upper electrode is formed of scale-like conductive particles on the upper surface of the emitter layer and has a plurality of opening portions. The surfaces of overhanging portions of the opening portions that face the emitter layer are apart from the emitter layer. The overhanging portions each have such a cross-sectional shape as to be acutely pointed toward the inner edge of the opening portion, or the tip end of the overhanging portion, so that lines of electric force concentrate at the inner edge.

摘要翻译： 电子发射器包括由电介质材料，上电极和下电极形成的发射极层。 在上电极和下电极之间施加驱动电压以发射电子。 上电极由发射极层的上表面上的鳞状导电粒子形成，具有多个开口部。 面向发射极层的开口部分的突出部分的表面与发射极层分开。 突出部分各自具有尖锐地指向开口部分的内边缘或突出部分的尖端的横截面形状，使得电力线集中在内边缘处。

公开(公告)号：US08158255B2

公开(公告)日：2012-04-17

申请号：US12017567

申请日：2008-01-22

申请人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

发明人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

IPC分类号： B32B5/66

CPC分类号： C04B35/495 ,  C01G29/006 ,  C01G33/006 ,  C01G35/006 ,  C01P2002/34 ,  C01P2002/72 ,  C01P2004/03 ,  C04B35/475 ,  C04B35/493 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3251 ,  C04B2235/3279 ,  C04B2235/3284 ,  C04B2235/3291 ,  C04B2235/3298 ,  C04B2235/365 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/6025 ,  C04B2235/762 ,  C04B2235/786 ,  C04B2235/79 ,  Y10T428/2982 ,  Y10T428/2991

摘要： A plate-like polycrystalline particle is produced by forming inorganic particles into a self-supported, sheet-like shaped body with a predetermined thickness, firing the shaped body, and crushing and classifying the fired shaped body by passing through a mesh having openings with a predetermined size. The inorganic particles are composed of an oxide having a perovskite structure and grow into crystal grains with an isotropic and polyhedral shape. Since grain growth in the thickness direction is limited and grain growth in the surface direction of the sheet is promoted, it is possible to obtain crystal grains having a high aspect ratio and a high degree of orientation. Therefore, in the plate-like polycrystalline particle, in most parts, the number of crystal grains present in the thickness direction of the particle at any one point is one, and a high aspect ratio and a high degree of orientation are achieved.

摘要翻译： 通过将无机粒子形成为具有预定厚度的自支撑的片状体，制成板状多晶粒子，烧成成形体，通过具有开口的网状物进行粉碎分级， 预定尺寸。 无机颗粒由具有钙钛矿结构的氧化物组成并且生长成具有各向同性和多面体形状的晶粒。 由于厚度方向的晶粒生长受到限制，并且促进了片材的表面方向的晶粒生长，因此可以获得具有高纵横比和高取向度的晶粒。 因此，在板状多晶粒子中，在大多数部分中，任何一点存在于粒子的厚度方向上的晶粒的数量为一个，并且实现高纵横比和高取向度。

公开(公告)号：US20090185971A1

公开(公告)日：2009-07-23

申请号：US12035491

申请日：2008-02-22

申请人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

发明人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

IPC分类号： C01G21/02 ,  C01G33/00 ,  C01G53/04 ,  C01G23/04

CPC分类号： C01G23/003 ,  C01G25/00 ,  C01G33/006 ,  C01G35/006 ,  C01P2002/34 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2006/40 ,  C04B35/493 ,  C04B35/495 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3249 ,  C04B2235/3251 ,  C04B2235/3255 ,  C04B2235/3279 ,  C04B2235/36 ,  C04B2235/6025 ,  C04B2235/787 ,  C04B2235/80 ,  H01L41/1873 ,  H01L41/1876 ,  H01L41/43

摘要： A crystallographically-oriented ceramic including first regions, in which crystal nuclei remain and which contain a specific element in a predetermined concentration range and extend at least partially in a layered shape along a crystal plane, and second regions, which contain the specific element in a different concentration range from the first regions and extend at least partially in a layered shape along the crystal plane. The regions are alternately repeated, and a compositional distribution exists in a direction orthogonal to the crystal plane. In the first region, the concentration of Na is higher, the concentration of K is lower, the concentration of Nb is lower, and the concentration of Ta is higher than the second region, and in the second region, the concentration of Na is lower, the concentration of K is higher, the concentration of Nb is higher, and the concentration of Ta is lower than the first region.

摘要翻译： 一种晶体取向陶瓷，其包括第一区域，其中晶核保留并且包含预定浓度范围的特定元素并且沿着晶面至少部分地以层状形式延伸，并且在第一区域中含有特定元素的第二区域 与第一区域不同的浓度范围，并且至少部分地沿着晶面延伸成层叠形状。 这些区域交替重复，并且在与晶面正交的方向上存在组成分布。 在第一区域，Na的浓度较高，K浓度较低，Nb浓度较低，Ta浓度高于第二区域，第二区域的Na浓度较低 ，K浓度较高，Nb浓度较高，Ta浓度低于第一区域。

公开(公告)号：US07528539B2

公开(公告)日：2009-05-05

申请号：US11145004

申请日：2005-06-02

申请人： Iwao Ohwada ,  Kei Sato ,  Nobuyuki Kobayashi ,  Shohei Yokoyama

发明人： Iwao Ohwada ,  Kei Sato ,  Nobuyuki Kobayashi ,  Shohei Yokoyama

IPC分类号： H01J1/46

CPC分类号： H01J1/32 ,  B82Y10/00 ,  H01J1/312 ,  H01J9/022

摘要： An electron emitter includes an emitter layer formed of a dielectric material, an upper electrode, and a lower electrode. A drive voltage is applied between the upper electrode and the lower electrode, for emitting electrons. The upper electrode is formed of scale-like conductive particles on the upper surface of the emitter layer and has a plurality of opening portions. The surfaces of overhanging portions of the opening portions that face the emitter layer are apart from the emitter layer. The overhanging portions each have such a cross-sectional shape as to be acutely pointed toward the inner edge of the opening portion, or the tip end of the overhanging portion, so that lines of electric force concentrate at the inner edge.

摘要翻译： 电子发射器包括由电介质材料，上电极和下电极形成的发射极层。 在上电极和下电极之间施加驱动电压以发射电子。 上电极由发射极层的上表面上的鳞状导电粒子形成，具有多个开口部。 面向发射极层的开口部分的突出部分的表面与发射极层分开。 突出部分各自具有尖锐地指向开口部分的内边缘或突出部分的尖端的横截面形状，使得电力线集中在内边缘处。

公开(公告)号：US20100119800A1

公开(公告)日：2010-05-13

申请号：US12612034

申请日：2009-11-04

申请人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

发明人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

IPC分类号： B32B5/00 ,  C04B35/64

CPC分类号： C04B35/475 ,  C04B35/495 ,  C04B35/62218 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3255 ,  C04B2235/3291 ,  C04B2235/3298 ,  C04B2235/5445 ,  C04B2235/6025 ,  C04B2235/6562 ,  C04B2235/6587 ,  C04B2235/77 ,  C04B2235/787 ,  C04B2235/79 ,  C04B2235/9623 ,  H01L41/1873 ,  H01L41/43

摘要： A ceramic sheet 20 is produced by a method in which inorganic particles including, as a main component, an oxide represented by general formula ABO3 and containing a volatile component are mixed such that the A/B ratio is 1.05 or more, the inorganic particles are formed into a self-supported planar shaped body with a thickness of 30 μm or less, and the shaped body is fired, without an inactive layer or with an inactive layer which does not substantially react with the shaped body and is disposed adjacent to the shaped body, at a temperature-rising rate of 30° C./min or more in a temperature range which is equal to or higher than a temperature at which the volatile component is volatilized.

摘要翻译： 通过以下方法制造陶瓷片20：将无机粒子作为主要成分，由通式ABO3表示的含有挥发性成分的氧化物混合，使得A / B比为1.05以上，无机粒子为 形成厚度为30μm以下的自支撑平面状体，并且成形体被烧制而没有无活性层或不与成形体基本上反应的不活泼层，并且与成形体 在等于或高于挥发性组分挥发的温度的温度范围内以30℃/分钟以上的升温速度进行。

公开(公告)号：US20090189489A1

公开(公告)日：2009-07-30

申请号：US12358559

申请日：2009-01-23

申请人： Yukinobu YURA ,  Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

发明人： Yukinobu YURA ,  Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

IPC分类号： H01L41/04 ,  H01L41/24

CPC分类号： H01L41/0973 ,  C01G23/003 ,  C01G25/00 ,  C01G25/006 ,  C01G33/006 ,  C01G35/006 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/62 ,  C01P2004/80 ,  C01P2006/40 ,  C04B35/462 ,  C04B35/475 ,  C04B35/493 ,  C04B35/495 ,  C04B35/6262 ,  C04B35/62685 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3251 ,  C04B2235/3255 ,  C04B2235/3279 ,  C04B2235/3298 ,  C04B2235/365 ,  C04B2235/5292 ,  C04B2235/5445 ,  C04B2235/6025 ,  C04B2235/768 ,  C04B2235/787 ,  H01L41/083 ,  H01L41/1873 ,  H01L41/1876 ,  H01L41/1878 ,  H01L41/43 ,  Y10T29/42

摘要： An actuator includes a fired ceramic substrate having a space opened downward, a first electrode formed on the upper surface of the fired ceramic substrate above the space, a piezoelectric/electrostrictive body formed on the first electrode so that the volume changes with input and output of electric power, and a second electrode formed on the piezoelectric/electrostrictive body. The piezoelectric/electrostrictive body is composed of Pb(Zr1-xTix)O3 or (Li, Na, K) (Nb, Ta)O3 as a main component and contains crystals oriented along the direction of an electric field. In the actuator, the degree of orientation of the piezoelectric/electrostrictive body can be increased regardless of the orientation of the substrate on which the piezoelectric/electrostrictive body is formed.

摘要翻译： 致动器包括具有向下开口的烧制陶瓷基板，形成在空间上方的烧结陶瓷基板的上表面上的第一电极，形成在第一电极上的压电/电致伸缩体，使得体积随着输入和输出而变化 电力和形成在压电/电致伸缩体上的第二电极。 压电/电致伸缩体由Pb（Zr1-xTix）O3或（Li，Na，K）（Nb，Ta）O3作为主要成分构成，并含有沿电场方向取向的晶体。 在致动器中，可以增加压电/电致伸缩体的取向度，而不管其上形成有压电/电致伸缩体的基板的取向如何。

公开(公告)号：US20080295948A1

公开(公告)日：2008-12-04

申请号：US12013602

申请日：2008-01-14

申请人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

发明人： Shohei Yokoyama ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki

IPC分类号： C03B29/00

CPC分类号： B32B18/00 ,  C04B35/493 ,  C04B35/495 ,  C04B35/64 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3206 ,  C04B2235/3251 ,  C04B2235/3279 ,  C04B2235/3284 ,  C04B2235/365 ,  C04B2235/5445 ,  C04B2235/6025 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/661 ,  C04B2235/768 ,  C04B2235/787 ,  C04B2235/79 ,  C04B2235/9623 ,  C04B2237/345 ,  C04B2237/346 ,  C04B2237/582 ,  C04B2237/62 ,  C04B2237/68 ,  C04B2237/704 ,  H01L41/1873 ,  H01L41/43 ,  Y10S117/902

摘要： A method for producing a crystallographically-oriented ceramic includes the steps of forming a first sheet with a thickness of 10 μm or less containing a first inorganic material in which grain growth occurs at a first temperature or higher and a second sheet containing a second inorganic material in which grain growth occurs at a second temperature higher than the first temperature, laminating one or more each of the first and second sheets to form a laminated body, firing the laminated body at a temperature equal to or higher than the first temperature and lower than the second temperature to cause grain growth in the first inorganic material, and then firing the laminated body at a temperature equal to or higher than the second temperature to cause grain growth in the second inorganic material in the direction of a crystal plane of the first inorganic material.

摘要翻译： 制造结晶取向陶瓷的方法包括以下步骤：形成厚度为10μm以下的第一片材​​，其含有在第一温度以上发生晶粒生长的第一无机材料和含有第二无机材料的第二片材 其中在比第一温度高的第二温度下发生晶粒生长，层压第一和第二片中的一个或多个以形成层压体，在等于或高于第一温度并低于 所述第二温度在所述第一无机材料中引起晶粒生长，然后在等于或高于所述第二温度的温度下焙烧所述层压体，以使所述第二无机材料在所述第一无机材料的晶面方向上晶粒生长 材料。