公开(公告)号：US20080154064A1

公开(公告)日：2008-06-26

申请号：US12068500

申请日：2008-02-07

申请人： Shoji Hara ,  Tsuyoshi Fukuhara

发明人： Shoji Hara ,  Tsuyoshi Fukuhara

IPC分类号： C07C211/01 ,  C07C17/07

CPC分类号： C07D239/30 ,  C07B39/00 ,  C07B2200/09 ,  C07C17/093 ,  C07C17/16 ,  C07C17/18 ,  C07C29/64 ,  C07C51/60 ,  C07C67/307 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2601/18 ,  C07C2601/20 ,  C07C2603/74 ,  C07H1/00 ,  C07H9/04 ,  C07H13/04 ,  C07H13/08 ,  C07H19/06 ,  C07C22/08 ,  C07C21/18 ,  C07C19/08 ,  C07C23/38 ,  C07C23/02 ,  C07C23/10 ,  C07C63/10 ,  C07C69/63 ,  C07C35/52 ,  C07C35/48

摘要： A method of fluorination comprising reacting monosaccharides, oligosaccharides, polysaccharides, composite saccharides formed by bonding of these saccharides with proteins and lipids and saccharides having polyalcohols, aldehydes, ketones and acids of the polyalcohols, and derivatives and condensates of these compounds with a fluorinating agent represented by general formula (I) thermally or under irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region. In accordance with the method, the fluorination at a selected position can be conducted safely at a temperature in the range of 150 to 200° C. where the reaction is difficult in accordance with conventional methods. The above method comprising the irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region can be applied to substrates other than saccharides. When a complex compound comprising HF and a base is reacted under irradiation with microwave, fluorination at a specific position which is difficult in accordance with conventional methods proceeds highly selectively, efficiently in a short time and safely.

公开(公告)号：US07351863B2

公开(公告)日：2008-04-01

申请号：US10537437

申请日：2003-12-01

申请人： Shoji Hara ,  Tsuyoshi Fukuhara

发明人： Shoji Hara ,  Tsuyoshi Fukuhara

IPC分类号： C07C211/27 ,  C07H5/02 ,  C07H1/00

CPC分类号： C07D239/30 ,  C07B39/00 ,  C07B2200/09 ,  C07C17/093 ,  C07C17/16 ,  C07C17/18 ,  C07C29/64 ,  C07C51/60 ,  C07C67/307 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2601/18 ,  C07C2601/20 ,  C07C2603/74 ,  C07H1/00 ,  C07H9/04 ,  C07H13/04 ,  C07H13/08 ,  C07H19/06 ,  C07C22/08 ,  C07C21/18 ,  C07C19/08 ,  C07C23/38 ,  C07C23/02 ,  C07C23/10 ,  C07C63/10 ,  C07C69/63 ,  C07C35/52 ,  C07C35/48

摘要： A method of fluorination comprising reacting monosaccharides, oligosaccharides, polysaccharides, composite saccharides formed by bonding of these saccharides with proteins and lipids and saccharides having polyalcohols, aldehydes, ketones and acids of the polyalcohols, and derivatives and condensates of these compounds with a fluorinating agent represented by general formula (I) thermally or under irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region. In accordance with the method, the fluorination at a selected position can be conducted safely at a temperature in the range of 150 to 200° C. where the reaction is difficult in accordance with conventional methods. The above method comprising the irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region can be applied to substrates other than saccharides

摘要翻译： 一种氟化方法，包括使单糖，寡糖，多糖，这些糖与蛋白质和脂质结合形成的复合糖和多元醇的多元醇，醛，酮和酸的糖，以及这些化合物的衍生物和缩合物与氟化剂的代表性反应 通过通式（I）热或照射微波或具有波长在微波区域周围的波长的电磁波。 根据该方法，可以根据常规方法在150〜200℃的范围内的温度下安全地进行选择位置的氟化。 包含微波照射或微波周围波长的电磁波的上述方法可以应用于除糖以外的基材

公开(公告)号：US07307185B2

公开(公告)日：2007-12-11

申请号：US10591698

申请日：2005-03-02

申请人： Shoji Hara ,  Tsuyoshi Fukuhara

发明人： Shoji Hara ,  Tsuyoshi Fukuhara

IPC分类号： C07C69/63 ,  C07C31/34

CPC分类号： C07C29/124 ,  C07B39/00 ,  C07B53/00 ,  C07B2200/07 ,  C07C67/18 ,  C07D317/22 ,  C07D317/24 ,  C07C69/92 ,  C07C69/76 ,  C07C31/38

摘要： The present invention provides a process for producing an optically active fluoro compound represented by formula (3) through reaction between a specific fluoroamine and an optically active diol; and a process for producing an optically active fluoroalcohol through hydrolysis of the optically active fluoro compound. According to the process of the present invention, such optically active fluoro compounds and optically active fluoroalcohols can be produced at high optical purity and high yield in a simple manner. Such optically active fluoroalcohols are a useful source for producing drugs, pesticides, and other functional chemicals

摘要翻译： 本发明提供一种通过特定的氟代胺和光学活性的二醇之间的反应制备由式（3）表示的光学活性的氟化合物的方法; 以及通过光学活性氟化合物的水解生产光学活性氟代醇的方法。 根据本发明的方法，可以简单的方式以高光学纯度和高产率制备这种光学活性氟化合物和光学活性氟代醇。 这种光学活性氟代醇是生产药物，杀虫剂和其它功能性化学物质的有用来源

公开(公告)号：US06773809B1

公开(公告)日：2004-08-10

申请号：US09707882

申请日：2000-11-08

申请人： Takashi Itoh ,  Shoji Hara ,  Hirosaku Nagano

发明人： Takashi Itoh ,  Shoji Hara ,  Hirosaku Nagano

IPC分类号： B32B712

CPC分类号： H05K3/4655 ,  B32B7/12 ,  C09J183/14 ,  H05K3/4652 ,  H05K2201/0162 ,  H05K2201/0358 ,  Y10T428/2852 ,  Y10T428/2878 ,  Y10T428/2883

摘要： There is provided a copper foil with an insulating adhesive which is excellent in that an insulating adhesive layer has low dieletric constant, low dieletric loss tangent and high adhering force at a normal temperature and a high temperature, and steps for manufacturing a multilayer printed circuit board can be shortened due to the presence of a copper foil on which a circuit can be formed by etching or the like. An insulating adhesive composition containing as an essential component an organic compound having at least two alkenyl groups having the reactivity with a SiH group in one molecule, and a silicon compound containing at least two SiH groups in one molecule and a copper foil are incorporated.

摘要翻译： 提供了一种具有绝缘粘合剂的铜箔，其绝缘粘合剂层具有低常压，高温下的低缺陷常数，低损耗切线和高粘附力，以及用于制造多层印刷电路板的步骤 可以由于存在可以通过蚀刻等形成电路的铜箔而被缩短。一种绝缘粘合剂组合物，其含有具有至少两个具有与SiH基反应性的烯基的有机化合物作为必要成分 一分子和一分子中含有至少两个SiH基团的硅化合物和铜箔。

公开(公告)号：US06605353B2

公开(公告)日：2003-08-12

申请号：US09749607

申请日：2000-12-28

申请人： Koji Okada ,  Hitoshi Nojiri ,  Shoji Hara

发明人： Koji Okada ,  Hitoshi Nojiri ,  Shoji Hara

IPC分类号： B32B2738

CPC分类号： H05K3/287 ,  C08G59/26 ,  C08G59/3245 ,  C08G73/1039 ,  C08G73/1046 ,  C08G73/1064 ,  C08G73/14 ,  C08G73/16 ,  C08L63/00 ,  C08L79/08 ,  G03F7/037 ,  G03F7/0387 ,  G03F7/0388 ,  Y10S428/901 ,  Y10T428/24917 ,  Y10T428/31511 ,  Y10T428/31529 ,  Y10T428/31681 ,  Y10T428/31721

摘要： An object of the present invention is to provide an epoxy modified polyimide, which is a resin capable of treating at a low processing temperature and having an excellent heat resistance; photosensitive composition; coverlay film, which is excellent in electrical insulation property, heat resistance for soldering, film-formability, flexibility, and chemical resistance; solder resist; and printed wiring board. The epoxy modified polyimide is obtained by synthesizing polyimide having a hydroxy group or carboxy group and subsequently reacting the polyimide with an epoxy compound. The photosensitive composition is obtained by adding a photoreaction initiator or the like to the epoxy modified polyimide. The coverlay film and the solder resist can be formed from the photosensitive composition. The printed wiring board is produced using the coverlay film and the solder resist.

摘要翻译： 本发明的目的是提供一种环氧改性聚酰亚胺，其是能够在低加工温度下处理并具有优异耐热性的树脂; 感光组合物; 电绝缘性优异，焊接耐热性，成膜性，柔软性和耐化学性优异的覆盖膜; 阻焊剂; 和印刷线路板。 通过合成具有羟基或羧基的聚酰亚胺，随后使聚酰亚胺与环氧化合物反应，得到环氧改性聚酰亚胺。 通过将光反应引发剂等添加到环氧改性聚酰亚胺中来获得感光性组合物。 覆盖膜和阻焊剂可以由光敏组合物形成。 使用覆盖膜和阻焊剂制造印刷线路板。

公开(公告)号：US07968751B2

公开(公告)日：2011-06-28

申请号：US12068481

申请日：2008-02-07

申请人： Shoji Hara ,  Tsuyoshi Fukuhara

发明人： Shoji Hara ,  Tsuyoshi Fukuhara

IPC分类号： C07C211/03 ,  C07C211/08

CPC分类号： C07D239/30 ,  C07B39/00 ,  C07B2200/09 ,  C07C17/093 ,  C07C17/16 ,  C07C17/18 ,  C07C29/64 ,  C07C51/60 ,  C07C67/307 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2601/18 ,  C07C2601/20 ,  C07C2603/74 ,  C07H1/00 ,  C07H9/04 ,  C07H13/04 ,  C07H13/08 ,  C07H19/06 ,  C07C22/08 ,  C07C21/18 ,  C07C19/08 ,  C07C23/38 ,  C07C23/02 ,  C07C23/10 ,  C07C63/10 ,  C07C69/63 ,  C07C35/52 ,  C07C35/48

摘要： A method of fluorination comprising reacting monosaccharides, oligosaccharides, polysaccharides, composite saccharides formed by bonding of these saccharides with proteins and lipids and saccharides having polyalcohols, aldehydes, ketones and acids of the polyalcohols, and derivatives and condensates of these compounds with a fluorinating agent represented by general formula (I) thermally or under irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region. In accordance with the method, the fluorination at a selected position can be conducted safely at a temperature in the range of 150 to 200° C. where the reaction is difficult in accordance with conventional methods. The above method comprising the irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region can be applied to substrates other than saccharides. When a complex compound comprising HF and a base is reacted under irradiation with microwave, fluorination at a specific position which is difficult in accordance with conventional methods proceeds highly selectively, efficiently in a short time and safely.

公开(公告)号：US07889971B2

公开(公告)日：2011-02-15

申请号：US10121662

申请日：2002-04-15

申请人： Shoji Hara

发明人： Shoji Hara

IPC分类号： H04N5/77 ,  H04N5/84 ,  H04N5/89

CPC分类号： G06F17/3089 ,  G06F17/3028 ,  G06F2216/09

摘要： In the case where an image data set stored in a recording medium of an image server or the like is linked to a Web page, an error message is prevented from being shown even if the image data set is deleted. Confirmation means confirms a storage period for the image data set. If the storage period has expired, character image generation means generates a character image data set of the same format and having the same file name as the image data set. The character image represented by the character image data set indicates deletion of the image data set. Compression means compresses the image data set and the compressed image data set is stored in another recording medium. The image data set is then deleted. When an access to the image data set is attempted, the character image data set is referred to.

摘要翻译： 在存储在图像服务器等的记录介质中的图像数据集被链接到网页的情况下，即使图像数据集被删除，也防止显示错误消息。 确认意味着确认图像数据集的存储期。 如果存储期限已经过去，则字符图像生成装置生成与图像数据集相同的格式并具有相同文件名的字符图像数据集。 由字符图像数据组表示的字符图像表示图像数据集的删除。 压缩装置压缩图像数据集，压缩图像数据集存储在另一记录介质中。 然后删除图像数据集。 当尝试访问图像数据集时，参考字符图像数据集。

公开(公告)号：US20080319228A1

公开(公告)日：2008-12-25

申请号：US12068481

申请日：2008-02-07

申请人： Shoji Hara ,  Tsuyoshi Fukuhara

发明人： Shoji Hara ,  Tsuyoshi Fukuhara

IPC分类号： C07C211/15

CPC分类号： C07D239/30 ,  C07B39/00 ,  C07B2200/09 ,  C07C17/093 ,  C07C17/16 ,  C07C17/18 ,  C07C29/64 ,  C07C51/60 ,  C07C67/307 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2601/18 ,  C07C2601/20 ,  C07C2603/74 ,  C07H1/00 ,  C07H9/04 ,  C07H13/04 ,  C07H13/08 ,  C07H19/06 ,  C07C22/08 ,  C07C21/18 ,  C07C19/08 ,  C07C23/38 ,  C07C23/02 ,  C07C23/10 ,  C07C63/10 ,  C07C69/63 ,  C07C35/52 ,  C07C35/48

摘要： A method of fluorination comprising reacting monosaccharides, oligosaccharides, polysaccharides, composite saccharides formed by bonding of these saccharides with proteins and lipids and saccharides having polyalcohols, aldehydes, ketones and acids of the polyalcohols, and derivatives and condensates of these compounds with a fluorinating agent represented by general formula (I) thermally or under irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region. In accordance with the method, the fluorination at a selected position can be conducted safely at a temperature in the range of 150 to 200° C. where the reaction is difficult in accordance with conventional methods. The above method comprising the irradiation with microwave or an electromagnetic wave having a wavelength around the microwave region can be applied to substrates other than saccharides. When a complex compound comprising HF and a base is reacted under irradiation with microwave, fluorination at a specific position which is difficult in accordance with conventional methods proceeds highly selectively, efficiently in a short time and safely.

摘要翻译： 一种氟化方法，包括使单糖，寡糖，多糖，这些糖与蛋白质和脂质结合形成的复合糖和多元醇的多元醇，醛，酮和酸的糖，以及这些化合物的衍生物和缩合物与氟化剂的代表性反应 通过通式（I）热或照射微波或具有波长在微波区域周围的波长的电磁波。 根据该方法，可以根据常规方法在150〜200℃的范围内的温度下安全地进行选择位置的氟化。 包含微波照射或微波周围波长的电磁波的上述方法可以应用于除糖以外的基材。 当包含HF和碱的络合物在微波照射下反应时，根据常规方法困难的特定位置的氟化在高速选择性地进行，在短时间内和安全地进行。

公开(公告)号：US20070191631A1

公开(公告)日：2007-08-16

申请号：US10591698

申请日：2005-03-02

申请人： Shoji Hara ,  Tsuyoshi Fukuhara

发明人： Shoji Hara ,  Tsuyoshi Fukuhara

IPC分类号： C07C69/63

CPC分类号： C07C29/124 ,  C07B39/00 ,  C07B53/00 ,  C07B2200/07 ,  C07C67/18 ,  C07D317/22 ,  C07D317/24 ,  C07C69/92 ,  C07C69/76 ,  C07C31/38

摘要： The present invention provides a process for producing an optically active fluoro compound represented by formula (3) through reaction between a specific fluoroamine and an optically active diol; and a process for producing an optically active fluoroalcohol through hydrolysis of the optically active fluoro compound. According to the process of the present invention, such optically active fluoro compounds and optically active fluoroalcohols can be produced at high optical purity and high yield in a simple manner. Such optically active fluoroalcohols are a useful source for producing drugs, pesticides, and other functional chemicals.

摘要翻译： 本发明提供一种通过特定的氟代胺和光学活性的二醇之间的反应制备由式（3）表示的光学活性的氟化合物的方法; 以及通过光学活性氟化合物的水解生产光学活性氟代醇的方法。 根据本发明的方法，可以简单的方式以高光学纯度和高产率制备这种光学活性氟化合物和光学活性氟代醇。 这种光学活性氟代醇是生产药物，杀虫剂和其它功能性化学物质的有用来源。

公开(公告)号：US07252881B2

公开(公告)日：2007-08-07

申请号：US10257502

申请日：2001-04-12

申请人： Takashi Itoh ,  Shoji Hara ,  Hirosaku Nagano ,  Masaru Nishinaka

发明人： Takashi Itoh ,  Shoji Hara ,  Hirosaku Nagano ,  Masaru Nishinaka

IPC分类号： B32B15/08 ,  B32B27/28 ,  H05K1/03

CPC分类号： H05K3/4655 ,  B32B27/06 ,  H05K3/386 ,  H05K3/388 ,  H05K3/389 ,  H05K3/4652 ,  H05K2201/0129 ,  H05K2201/0154 ,  H05K2201/0195 ,  H05K2201/0209 ,  H05K2201/0239 ,  H05K2201/0358 ,  H05K2201/068 ,  H05K2203/121 ,  Y10T428/24917 ,  Y10T428/2804 ,  Y10T428/2848 ,  Y10T428/31681 ,  Y10T428/31692 ,  Y10T428/31721

摘要： A multilayer structure comprising a conductor layer, an adhesive layer, and a polymer film layer interposed between the conductor layer and the adhesive layer. The multilayer structure can be used to provide a multilayer wiring board having excellent electrical properties and an excellent balance of physical properties, high heat resistance, a narrow pitch wiring pattern, a small-diameter via, uniform insulating layer thickness, an appropriately low coefficient of linear expansion, and stable adhesiveness between a metal and the polymer film. The polymer film layer may contain at least one repeating unit represented by formula (1) in the molecule. The present invention also provides a multilayer wiring board obtained from the multilayer structure.

摘要翻译： 一种多层结构，包括导体层，粘合剂层和介于导体层和粘合剂层之间的聚合物膜层。 多层结构可以用于提供具有优异的电性能和良好的物理平衡性，高耐热性，窄间距布线图案，小直径孔，均匀绝缘层厚度，适当低的系数 线膨胀，金属与聚合物膜之间的粘合性稳定。 聚合物膜层可以在分子中含有至少一个由式（1）表示的重复单元。 本发明还提供从多层结构体获得的多层布线基板。