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    Selective hydrogenation catalyst and processes therefor and therewith
    11.
    发明授权
    Selective hydrogenation catalyst and processes therefor and therewith 有权
    选择性氢化催化剂及其工艺

    公开(公告)号：US06465391B1

    公开(公告)日：2002-10-15

    申请号：US09643266

    申请日：2000-08-22

    Applicant: Tin-Tack Peter Cheung ,  Marvin M. Johnson

    Inventor： Tin-Tack Peter Cheung ,  Marvin M. Johnson

    IPC: B01J2358

    CPC classification number: B01J27/12 ,  B01J23/50 ,  B01J23/66 ,  C07C7/167 ,  C07C2527/12 ,  Y02P20/52 ,  C07C11/04

    Abstract: A catalyst composition comprising an inorganic support material, a palladium component, a silver component, and a promoter component having the formula XYFn, wherein X is an alkaline metal, Y is an element selected from the group consisting of antimony, phosphorus, boron, aluminum, gallium, indium, thallium, and arsenic, and n is an integer which makes YFn a monovalent anion. The catalyst is employed in the selective hydrogenation of acetylene. The catalyst is made by incorporating a palladium component, a silver component, and a promoter component into an inorganic support material.

    Abstract translation: 一种催化剂组合物，其包含无机载体材料，钯组分，银组分和具有式XYFn的助催化剂组分，其中X是碱金属，Y是选自锑，磷，硼，铝的元素 ，镓，铟，铊和砷，n为使YFn为一价阴离子的整数。 催化剂用于乙炔的选择性氢化。 催化剂通过将钯组分，银组分和促进剂组分并入无机载体材料中而制成。

    Extending the life of an aromatization catalyst
    14.
    发明授权
    Extending the life of an aromatization catalyst 有权
    延长芳构化催化剂的使用寿命

    公开(公告)号：US07868217B2

    公开(公告)日：2011-01-11

    申请号：US11940115

    申请日：2007-11-14

    Applicant: Scott H. Brown ,  Tin-Tack Peter Cheung ,  Daniel P. Hagewiesche ,  Baiyi Zhao

    Inventor： Scott H. Brown ,  Tin-Tack Peter Cheung ,  Daniel P. Hagewiesche ,  Baiyi Zhao

    IPC: C07C2/52

    CPC classification number: B01J29/90 ,  B01J27/13 ,  B01J27/32 ,  B01J29/62 ,  B01J38/14 ,  C07C2/76 ,  C07C5/31 ,  C10G35/085 ,  C10G45/70 ,  C10G2300/1044 ,  C10G2400/30 ,  Y02P20/584 ,  Y10S585/904 ,  Y10S585/906 ,  C07C15/02

    Abstract: A method of extending the life of an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst, and oxidizing the catalyst prior to reaching the RDT. A method of aromatizing a hydrocarbon comprising identifying a rapid deactivation threshold (RDT) for an aromatization catalyst, and operating an aromatization reactor comprising the catalyst to extend the Time on Stream of the reactor prior to reaching the RDT. A method of characterizing an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst. A method of extending the life of an aromatization catalyst comprising predicting a rapid deactivation threshold (RDT) for an aromatization reactor by employing the catalyst in a reactor system under an accelerated fouling condition to identify a test rapid deactivation threshold (t-RDT), predicting the RDT for the aromatization reactor based upon the t-RDT, and oxidizing the catalyst prior to the predicted RDT to extend the Time on Stream of the aromatization catalyst.

    Abstract translation: 延长芳构化催化剂寿命的方法，包括鉴定催化剂的快速失活阈值（RDT），并在达到RDT之前氧化催化剂。 一种芳构化烃的方法，包括鉴定用于芳族化催化剂的快速失活阈值（RDT），以及操作包含催化剂的芳构化反应器以在达到RDT之前延长反应器上的时间。 表征芳构化催化剂的方法包括鉴定催化剂的快速失活阈值（RDT）。 一种延长芳构化催化剂的寿命的方法，包括通过在加速结垢条件下在反应器系统中使用催化剂来预测芳构化反应器的快速失活阈值（RDT），以鉴定测试快速失活阈值（t-RDT），预测 基于t-RDT的芳构化反应器的RDT，以及在预测的RDT之前氧化催化剂以延长芳构化催化剂的时间。

    Systems of producing monoolefins by the extraction-hydrogenation of highly unsaturated hydrocarbons
    15.
    发明授权
    Systems of producing monoolefins by the extraction-hydrogenation of highly unsaturated hydrocarbons 失效
    通过高度不饱和烃的提取氢化生产单烯烃的体系

    公开(公告)号：US07674438B2

    公开(公告)日：2010-03-09

    申请号：US11534241

    申请日：2006-09-22

    Applicant: Tin-Tack Peter Cheung ,  Marvin M. Johnson

    Inventor： Tin-Tack Peter Cheung ,  Marvin M. Johnson

    IPC: B01J8/04

    CPC classification number: C07C5/09 ,  C07C5/05 ,  C07C7/10

    Abstract: In some embodiments, a monoolefin production system comprising an extraction-hydrogenation zone for extracting a highly unsaturated hydrocarbon from an olefin stream into a polar solvent and, in situ, hydrogenating the highly unsaturated hydrocarbon to a monoolefin. In other embodiments, monoolefin production systems include an extraction-hydrogenation zone for performing the extraction and hydrogenating steps in situ. In alternative embodiments, the hydrogenation zone is disposed downstream from the extraction zone.

    Abstract translation: 在一些实施方案中，单烯烃生产系统包括用于从烯烃流中提取高度不饱和烃到极性溶剂中的提取氢化区，并且原位将高度不饱和烃氢化成单烯烃。 在其它实施方案中，单烯烃生产系统包括用于原位进行萃取和氢化步骤的萃取氢化区。 在替代实施方案中，氢化区位于提取区的下游。

    Method of treating a catalytic reactor system prior to reactor servicing
    16.
    发明授权
    Method of treating a catalytic reactor system prior to reactor servicing 有权
    在反应器维修之前处理催化反应器系统的方法

    公开(公告)号：US07582272B2

    公开(公告)日：2009-09-01

    申请号：US10799987

    申请日：2004-03-12

    Applicant: David J. Glova ,  Tin-Tack Peter Cheung ,  Dan B. Knorr

    Inventor： David J. Glova ,  Tin-Tack Peter Cheung ,  Dan B. Knorr

    IPC: B01D53/72

    CPC classification number: C10G35/04 ,  B01J29/90 ,  B01J38/12 ,  B01J38/14 ,  B01J2208/02

    Abstract: A method of servicing a catalytic reactor system, comprising an abatement of at least one hazardous substance from the catalytic reactor system while preserving activity of a catalyst contained therein. A method of servicing a catalytic reactor system, comprising oxidizing the catalytic reactor system at a temperature of from about 350° F. to about 500° F. to abate at least one hazardous substance from the catalytic reactor system and reducing servicing time by about 50% of a time required for complete regenerative oxidation of the catalytic reactor system. A method of servicing a catalytic reactor system, comprising abating at least one hazardous substance from the catalytic reactor system such that a fouling rate of a catalyst contained therein is substantially the same before and after the servicing.

    Abstract translation: 一种维修催化反应器系统的方法，包括从催化反应器系统中减少至少一种有害物质，同时保持其中所含催化剂的活性。 一种维修催化反应器系统的方法，包括在约350°F至约500°F的温度下氧化催化反应器系统以从催化反应器系统中减少至少一种有害物质，并将维修时间减少约50 催化反应器系统的完全再生氧化所需的时间的百分比。 一种维修催化反应器系统的方法，包括从催化反应器系统中减少至少一种有害物质，使得其中所含催化剂的结垢率在维修前后基本相同。

    Selective hydrogenation catalyst and methods of making and using same
    17.
    发明授权
    Selective hydrogenation catalyst and methods of making and using same 有权
    选择性氢化催化剂及其制备和使用方法

    公开(公告)号：US07417007B2

    公开(公告)日：2008-08-26

    申请号：US11458937

    申请日：2006-07-20

    Applicant: Tin-Tack Peter Cheung ,  Joseph Bergmeister, III ,  Zongxuan Hong

    Inventor： Tin-Tack Peter Cheung ,  Joseph Bergmeister, III ,  Zongxuan Hong

    IPC: B01J27/02 ,  B01J27/045 ,  B01J27/10

    CPC classification number: B01J27/13 ,  B01J21/04 ,  B01J23/44 ,  B01J23/50 ,  B01J27/125 ,  B01J35/1009 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/24 ,  C10G45/40 ,  C10G2300/70

    Abstract: A method for producing a selective hydrogenation catalyst for hydrogenating a highly unsaturated hydrocarbon to an unsaturated hydrocarbon comprising contacting an inorganic catalyst support with a chlorine-containing compound to form a chlorided catalyst support and adding palladium to the chlorided catalyst support to form a supported-palladium composition. A selective hydrogenation catalyst for hydrogenating a highly unsaturated hydrocarbon to an unsaturated hydrocarbon formed by the method comprising contacting an inorganic catalyst support with a chlorine-containing compound to form a chlorided catalyst support and adding palladium to the chlorided catalyst support to form a supported-palladium composition. A method of selectively hydrogenating a highly unsaturated hydrocarbon to an unsaturated hydrocarbon comprising contacting the highly unsaturated hydrocarbon with a selective hydrogenation catalyst composition produced by contacting an inorganic catalyst support with a chlorine-containing compound to form a chlorided catalyst support and adding palladium to the chlorided catalyst support to form a supported-palladium composition.

    Abstract translation: 一种制备用于将高度不饱和烃氢化成不饱和烃的选择性氢化催化剂的方法，包括使无机催化剂载体与含氯化合物接触以形成氯化催化剂载体并向氯化催化剂载体中加入钯以形成负载钯 组成。 一种用于将高度不饱和烃氢化成不饱和烃的选择性氢化催化剂，该方法包括使无机催化剂载体与含氯化合物接触以形成氯化催化剂载体，并向氯化催化剂载体中加入钯以形成负载钯 组成。 包括将高度不饱和烃选择性氢化为不饱和烃的方法，包括使高度不饱和烃与选择性氢化催化剂组合物接触，所述选择性氢化催化剂组合物通过使无机催化剂载体与含氯化合物接触而形成氯化催化剂载体并向氯化物中加入钯 催化剂载体以形成负载型钯组合物。

    Hydrocarbon hydrogenation catalyst and process
    18.
    发明授权
    Hydrocarbon hydrogenation catalyst and process 失效
    烃氢化催化剂和工艺

    公开(公告)号：US06794552B2

    公开(公告)日：2004-09-21

    申请号：US10036930

    申请日：2001-12-21

    Applicant: Tin-Tack Peter Cheung ,  Darin B. Tiedtke ,  Marvin M. Johnson ,  Gary A. Delzer

    Inventor： Tin-Tack Peter Cheung ,  Darin B. Tiedtke ,  Marvin M. Johnson ,  Gary A. Delzer

    IPC: C07C505

    CPC classification number: B01J23/66 ,  B01J23/002 ,  B01J23/005 ,  B01J23/50 ,  B01J23/58 ,  B01J37/0081 ,  B01J2523/00 ,  C07C5/03 ,  C07C5/08 ,  C07C2521/04 ,  B01J2523/18 ,  B01J2523/27 ,  B01J2523/31 ,  B01J2523/824 ,  B01J2523/13 ,  B01J2523/22 ,  B01J2523/23

    Abstract: A catalyst composition is provided which can be used for hydrogenating a highly unsaturated hydrocarbon such as an alkyne or a diolefin. The catalyst composition contains palladium, a catalyst component of either silver or an alkali metal compound, or both silver and an alkali metal compound, and a metal aluminate catalyst support. Such metal aluminate catalyst support is prepared by a process of incorporating alumina with a metal component, preferably impregnating alumina with a melted metal component, to thereby provide a metal-incorporated alumina followed by drying and high temperature calcining to thereby provide a metal aluminate catalyst support. The catalyst composition disclosed can be used for hydrogenating a highly unsaturated hydrocarbon to a less unsaturated hydrocarbon. The process involves contacting a highly unsaturated hydrocarbon with a catalyst composition in the presence of hydrogen under a hydrogenation condition sufficient to effect a hydrogenation of the highly unsaturated hydrocarbon.

    Abstract translation: 提供了可用于氢化高度不饱和烃如炔烃或二烯烃的催化剂组合物。 催化剂组合物包含钯，银或碱金属化合物的催化剂组分，或银和碱金属化合物两者以及金属铝酸盐催化剂载体。 这种金属铝酸盐催化剂载体是通过将氧化铝与金属组分掺入的方法制备的，优选用熔融的金属组分浸渍氧化铝，从而提供掺入金属的氧化铝，然后进行干燥和高温煅烧，从而提供金属铝酸盐催化剂载体 。 所公开的催化剂组合物可用于将高度不饱和烃氢化为较不饱和的烃。 该方法包括在氢气存在下使氢不饱和烃与催化剂组合物接触，氢化条件足以进行高度不饱和烃的氢化。

    Hydrocarbon upgrading process
    19.
    发明授权
    Hydrocarbon upgrading process 有权
    碳氢化合物升级过程

    公开(公告)号：US06258989B1

    公开(公告)日：2001-07-10

    申请号：US09410516

    申请日：1999-09-30

    Applicant: Steven A. Owen ,  Marvin M. Johnson ,  Tin-Tack Peter Cheung ,  Mark E. Lashier

    Inventor： Steven A. Owen ,  Marvin M. Johnson ,  Tin-Tack Peter Cheung ,  Mark E. Lashier

    IPC: C07C202

    CPC classification number: C10G69/00 ,  C07C2/02 ,  C07C2603/68 ,  C10G65/06 ,  C10G69/126 ,  C07C13/61

    Abstract: A hydrocarbon feedstock containing C5 olefins, C5 diolefins, CPD, DCPD, and aromatics is processed by the steps of heating a hydrocarbon feedstock containing CPD, DCPD, C5 diolefins, benzene, toluene, and xylene in a heating zone, to dimerize CPD to DCPD, thereby forming a first effluent; separating the first effluent into a C6+ stream and a C5 diolefin stream; separating the C6+ stream into a C6-C9 stream and a C10+ stream; separating the C10+ stream into a fuel oil stream and a DCPD stream; and hydrotreating the C6-C9 stream to thereby form a BTX stream. In an alternate embodiment, the hydrocarbon feedstock is processed by the steps of heating the hydrocarbon feedstock in a heating zone, to dimerize CPD to DCPD, thereby forming a first effluent; separating the first effluent into a C5-C9 stream and a C10+ stream; separating the C10+ stream into a fuel oil stream and a DCPD stream; contacting the C5-C9 stream with a selective hydrogenation catalyst, in a first reaction zone and in the presence of hydrogen, to hydrogenate at least a portion of the diolefins, alkynes, and styrene contained in the C5-C9 stream, thereby forming a second effluent; separating the second effluent into a C6-C9 stream and a C5 olefin stream; and contacting the C6-C9 stream with a hydrodesulfurization catalyst, in a second reaction zone and in the presence of hydrogen, to desulfurize at least a portion of the sulfur-containing compounds contained in the C6-C9 stream thereby forming a BTX stream.

    Abstract translation: 通过在加热区中加热含有CPD，DCPD，C5二烯烃，苯，甲苯和二甲苯的烃原料以将CPD二聚化为DCPD的步骤来处理含有C5烯烃，C5二烯烃，CPD，DCPD和芳族化合物的烃原料 ，从而形成第一流出物; 将第一流出物分离成C6 +流和C5二烯烃流; 将C6 +流分离成C6-C9流和C10 +流; 将C10 +流分离成燃料油流和DCPD流; 并加氢处理C6-C9流，从而形成BTX流。 在替代实施方案中，烃原料通过以下步骤加工：在加热区中加热烃原料，将CPD二聚到DCPD，由此形成第一流出物; 将第一流出物分离成C5-C9流和C10 +流; 将C10 +流分离成燃料油流和DCPD流; 在第一反应区和氢的存在下，将C5-C9流与选择性氢化催化剂接触，氢化C5-C9流中所含的二烯烃，炔烃和苯乙烯的至少一部分，从而形成第二 流出物 将第二流出物分离成C6-C9流和C5烯烃流; 并在第二反应区和氢气存在下使C6-C9流与加氢脱硫催化剂接触，以将C6-C9流中至少一部分含硫化合物脱硫，从而形成BTX流。

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