摘要:
The present invention relates to a process and a device for manufacturing synthesis gas. The reactor according to the invention comprises within a single housing: A non catalytic combustion chamber (1) comprising at least one device (2) for injecting a fuel and at least one device (3) for injecting an oxidizer so as to achieve a partial combustion in said chamber, and at least one catalytic bed (4) which the gases coming from combustion chamber (1) run into, and also comprising at least one device (6) for injecting an additional oxidizer. The reactor and the process according to the invention may be applied to any chemical manufacturing utilizing synthesis gas, such as the manufacturing of ammonia, urea, methanol, higher hydrocarbons, etc.
摘要:
A process for sweetening a petroleum cut containing mercaptans, wherein said petroleum cut is subjected to oxidation conditions by its being passed in the presence of air in contact with a porous catalyst said process being characterized in that said catalyst comprises 10 to 98% by weight of at least one mineral solid phase constituted of analkaline aluminosilicate with a Si/Al atomic ratio less than or equal to 5, 1 to 60% by weight of active carbon, 0.02 to 2% by weight of at least one metal chelate and 0 to 20% by weight of at least one organic or mineral binding agent, has a basicity determined according to the 2896 ASTM standard with 20 milli-equivalents of potash per gram and a total BET surface area of 10 m.sup.2 g.sup.-1, and contains inside its pore structure a permanent aqueous phase representing 0.1 to 40% by weight of dry catalyst.
摘要:
A reactor for manufacturing synthesis gas as a single housing, equipped with a non-catalytic combustion chamber having at least one device for injecting a fuel and at least one device for injecting an oxidizer so as to achieve partial combustion in said chamber, and at least one catalytic bed from which the gases coming from the combustion chamber discharge into, said catalytic bed being equipped with at least one device for injecting an additional oxidizer. A process for operating the reactor may be applied to any chemical manufacturing utilizing synthesis gas, such as the manufacturing of ammonia, urea, methanol, higher hydrocarbons, etc.
摘要:
The invention concerns an isomerization catalyst comprising 4 to 15% of at least one halogen and at least one metal from group VIII deposited on a support composed of a mixture of specific proportions of eta alumina and gamma alumina. The invention also concerns a process for reducing the benzene content of gasoline fractions and isomerizing paraffins in the presence of this catalyst, in which isomerization is carried out on a mixture of a) a feed with the following composition by weight: 40% to 80% of paraffins, 0.5% to 7% of cyclic hydrocarbons and 6% to 45% of aromatics, and with a maximum distillation temperature of between 70.degree. C. and 90.degree. C., and b) a C.sub.5 -C.sub.6 cut which is generally a straight run cut.
摘要:
The invention concerns a process for the elimination of mercury from hydrocarbons by passage of the feedstock with hydrogen over a catalyst then bringing the product obtained into contact with a mercury retention bed, the catalyst comprising at least one element selected from the group constituted by iron, nickel, cobalt, molybdenum, tungsten, palladium, wherein at least 5% is in the sulphide state. Any arsenic present in the feedstock is also eliminated.In accordance with the invention, the catalyst is simultaneously presulphurated and reduced.The invention results in a considerable reduction in operation period and high retention efficiency at temperatures between 120.degree. C. and 250.degree. C. and in the presence of 0-1000 mg of sulphur/kg of feed.
摘要:
For removing mercury and any arsenic in hydrocarbon charges containing mercury and sulfur, the charge is contacted with an arsenic collecting material having catalytic properties ("catalyst") in hydrogen, the material containing at least one metal selected from the group consisting of nickel, cobalt, iron, palladium, and platinum; at least one metal selected from the group consisting of chromium, molybdenum, tungsten, and uranium; and an active phase carrier. Downstream of the catalyst or mixed therewith is a mercury collecting material containing a sulfide of at least one metal selected from the group consisting of copper, iron, and silver or sulfur, and an active phase carrier.
摘要:
The invention concerns a multifunctional catalyst containing cerium, uranium and at least one metal, for converting pollutants emitted by internal combustion engines, and their preparation.A catalyst comprises a porous layer containingfrom about 20% to about 99% of at least one refractory oxidefrom about 0.8% to about 70% of at least one cerium oxidefrom about 0.1% to about 50% of at least one uranium oxidefrom about 0.1% to about 20% of a metal selected from the group made up of Pt, Rh, Pd, Ru, Ir and Au, and mixtures thereof.Applications are in the catalytic converter industry.
摘要:
Manufacture of catalysts containing at least three essential metals consisting of copper, zinc and aluminum.The process for manufacturing the catalyst comprises the formation of homogeneous amorphous precipitate of the above-mentioned metals, followed with a washing in two steps, first with water, then with an acid solution.These catalysts are used in balanced reactions involving alcohols and synthesis gas, particularly in methanol synthesis.
摘要:
A gas containing carbon oxysulfide or carbon disulfide is passed in admixture with oxygen through a catalyst formed of a carrier, vanadium oxide and silver, the proportion of iron oxide, if any, being lower than 1% by weight. The amount of vanadium oxide may be 0.5 to 10% by weight and that of silver 0.05 to 4% by weight.
摘要:
Catalyst for the decomposition of nitrogen oxides, particularly for use in catalytic exhaust boxes in view of decomposing the nitrogen oxides contained in the exhaust gases from internal combustion engines, comprising, deposited on a carrier, from 3 to 20% of an active phase of the formula Ni.sub.x (Fe.sub.y Cr.sub.z)O.sub.t, in which x has a value from 0.5 to 1.5, y + z a value from 1.5 to 3, the ratio ##EQU1## A VALUE FROM 0.01 TO 0.9 AND T A VALUE LOWER THAN 10.