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    METHOD FOR THE CONTINUOUS PRODUCTION OF BIODEGRADABLE POLYESTERS
    12.
    发明申请
    METHOD FOR THE CONTINUOUS PRODUCTION OF BIODEGRADABLE POLYESTERS 审中-公开
    连续生产可生物降解聚酯的方法

    公开(公告)号：US20140128514A1

    公开(公告)日：2014-05-08

    申请号：US14082271

    申请日：2013-11-18

    申请人： Uwe Witt ,  Motonori Yamamoto

    发明人： Uwe Witt ,  Motonori Yamamoto

    IPC分类号： C08G63/127

    CPC分类号： C08G63/181 ,  C08G18/4219 ,  C08G18/4241 ,  C08G18/73 ,  C08G63/127 ,  C08G63/16 ,  C08G63/20 ,  C08G63/60 ,  C08G63/78 ,  C08G2230/00

    摘要： A process for the continuous production of a biodegradable polyester, wherea mixture of aliphatic dihydroxy compounds, aliphatic and aromatic dicarboxylic acids or their liquid esters, and, optionally, further comonomers is mixed, without addition of a catalyst, to give a paste, and i) this mixture with at least a portion of the catalyst, is continuously esterified or, transesterified; ii) the transesterification or, esterification product obtained in i) is continuously precondensed with any remaining amount of catalyst to an intrinsic viscosity of from 20 to 70 cm3/g; iii) the product obtainable from ii) is continuously polycondensed to an intrinsic viscosity of from 60 to 170 cm3/g, and iv) the product obtainable from iii) is reacted continuously with a chain extender in a polyaddition reaction to an intrinsic viscosity of from 150 to 320 cm3/g. The invention further relates to biodegradable polyesters obtained_by this process.

    摘要翻译： 连续生产可生物降解的聚酯的方法，其中脂肪族二羟基化合物，脂族和芳族二羧酸或它们的液体酯的混合物，以及任选的其它共聚单体混合，不加入催化剂，得到糊状物，和 i）与至少一部分催化剂的该混合物连续酯化或酯交换; ii）在i）中获得的酯交换反应或酯化产物用任何剩余量的催化剂连续预缩合至特性粘度为20至70cm 3 / g; iii）从ii）获得的产品连续缩聚至特性粘度为60至170cm 3 / g，并且iv）将可从iii）获得的产品在加聚反应中与扩链剂连续反应至特性粘度为 150〜320cm3 / g。 本发明还涉及通过该方法获得的生物可降解聚酯。

    POLYESTER POLYOLS BASED ON TEREPHTHALIC ACID
    13.
    发明申请
    POLYESTER POLYOLS BASED ON TEREPHTHALIC ACID 审中-公开
    基于过敏酸的聚酯多元醇

    公开(公告)号：US20110201716A1

    公开(公告)日：2011-08-18

    申请号：US13124217

    申请日：2009-10-13

    申请人： Lionel Gehinger ,  Gunnar Kampf ,  Gerlinde Tischer

    发明人： Lionel Gehinger ,  Gunnar Kampf ,  Gerlinde Tischer

    IPC分类号： C08G18/34 ,  C07C69/76 ,  C08J9/06

    CPC分类号： C08G18/4219 ,  C08G18/4018 ,  C08G18/4288 ,  C08G63/127 ,  C08G63/48 ,  C08G2101/0025

    摘要： Polyester polyol comprising the esterification product of a) from 10 to 70 mol % of a dicarboxylic acid composition comprising a1) from 50 to 100 mol % of a material based on terephthalic acid, selected from among terephthalic acid, dimethyl terephthalate, polyalkylene terephthalate and mixtures thereof, a2) from 0 to 50 mol % of phthalic acid, phthalic anhydride or isophthalic acid, a3) from 0 to 50 mol % of one or more dicarboxylic acids, b) from 2 to 30 mol % of one or more fatty acids and/or fatty acid derivatives and/or benzoic acid, c) from 10 to 70 mol % of one or more aliphatic or cycloaliphatic diols having from 2 to 18 carbon atoms or alkoxylates thereof, d) from 2 to 50 mol % of a higher-functional polyol selected from the group consisting of glycerol, alkoxylated glycerol, trimethylolpropane, alkoxylated trimethylolpropane, pentaerythritol and alkoxylated pentaerythritol, wherein at least 200 mmol, preferably at least 500 mmol and particularly preferably at least 800 mmol, of polyols d) having an OH functionality of 2.9 are reacted per kg of polyester polyol.

    摘要翻译： 包含a）10-70mol％二羧酸组合物的酯化产物的聚酯多元醇，其包含a1）50-100mol％的基于对苯二甲酸的材料，其选自对苯二甲酸，对苯二甲酸二甲酯，聚对苯二甲酸亚烷基酯和混合物 a2）0〜50摩尔％的邻苯二甲酸，邻苯二甲酸酐或间苯二甲酸，a3）0〜50摩尔％的一种或多种二羧酸，b）2〜30摩尔％的一种或多种脂肪酸和 /或脂肪酸衍生物和/或苯甲酸，c）10至70mol％的一种或多种具有2至18个碳原子的脂族或脂环族二醇或其烷氧基化物，d）2-50mol％ 选自甘油，烷氧基化甘油，三羟甲基丙烷，烷氧基化三羟甲基丙烷，季戊四醇和烷氧基化季戊四醇的官能多元醇，其中至少200mmol，优选至少500mmol，特别优选至少800mmol， 的多官能度为2.9的多元醇d）与每千克聚酯多元醇反应。

    METHOD FOR THE CONTINUOUS PRODUCTION OF BIODEGRADABLE POLYESTERS
    14.
    发明申请
    METHOD FOR THE CONTINUOUS PRODUCTION OF BIODEGRADABLE POLYESTERS 有权
    连续生产可生物降解聚酯的方法

    公开(公告)号：US20110039999A1

    公开(公告)日：2011-02-17

    申请号：US12988127

    申请日：2009-04-07

    申请人： Uwe Witt ,  Motonori Yamamoto

    发明人： Uwe Witt ,  Motonori Yamamoto

    IPC分类号： C08K5/20 ,  C08G63/46 ,  C08G75/24 ,  C08G18/00 ,  C08L67/02

    CPC分类号： C08G63/181 ,  C08G18/4219 ,  C08G18/4241 ,  C08G18/73 ,  C08G63/127 ,  C08G63/16 ,  C08G63/20 ,  C08G63/60 ,  C08G63/78 ,  C08G2230/00

    摘要： The present invention relates to a process for the continuous production of a biodegradable polyester based on aliphatic or aliphatic and aromatic dicarboxylic acids and on aliphatic dihydroxy compounds, wherea mixture composed of the aliphatic dihydroxy compounds, of the aliphatic and aromatic dicarboxylic acids, and, if appropriate, of further comonomers (component C) is mixed, without addition of a catalyst, to give a paste, or, as an alternative, the liquid esters of the dicarboxylic acids are fed into the system, as also are the dihydroxy compound and, if appropriate, further comonomers, without addition of any catalyst, and i) in a first stage, this mixture, together with the entire amount or with a portion of the catalyst, is continuously esterified or, respectively, transesterified; ii) in a second stage, the transesterification or, respectively, esterification product obtained in i) is continuously precondensed if appropriate with the remaining amount of catalyst to an intrinsic viscosity of from 20 to 70 cm3/g to DIN 53728; iii) in a third stage, the product obtainable from ii) is continuously polycondensed to an intrinsic viscosity of from 60 to 170 cm3/g to DIN 53728, and iv) in a fourth stage, the product obtainable from iii) is reacted continuously with a chain extender D in a polyaddition reaction to an intrinsic viscosity of from 150 to 320 cm3/g to DIN 53728. The invention further relates to biodegradable polyesters which are accessible for the first time by this process.

    摘要翻译： 本发明涉及一种连续生产基于脂族或脂族和芳族二羧酸的可生物降解聚酯和脂族二羟基化合物的方法，其中脂族和芳族二羧酸由脂肪族二羟基化合物组成的混合物， 如果合适，将另外的共聚单体（组分C）混合，而不加入催化剂，得到糊剂，或者作为替代方案，将二羧酸的液体酯进料到体系中，二羟基化合物和 如果合适的话，进一步的共聚单体，不加任何催化剂，和i）在第一阶段，该混合物连同全部量或与一部分催化剂连续酯化或分别酯交换; ii）在第二阶段中，如果合适的话，在i）中得到的酯交换反应或酯化产物分别连续地预冷凝，其余的催化剂量根据DIN 53728的特性粘度为20至70cm 3 / g; iii）在第三阶段中，可从ii）获得的产品连续缩聚至对于DIN 53728为60至170cm 3 / g的特性粘度，以及iv）在第四阶段中，可从iii）获得的产物与 在根据DIN 53728的特性粘度为150至320cm 3 / g的加聚反应中的扩链剂D。本发明还涉及可通过该方法首次访问的可生物降解的聚酯。

    Compatibilized polyester polyol blend from phthalic anhydride bottoms
    16.
    发明授权
    Compatibilized polyester polyol blend from phthalic anhydride bottoms 失效
    来自邻苯二甲酸酐底部的相容的聚酯多元醇共混物

    公开(公告)号：US4615822A

    公开(公告)日：1986-10-07

    申请号：US711629

    申请日：1985-03-13

    申请人： George Magnus

    发明人： George Magnus

    IPC分类号： C08G18/32 ,  C08G18/42 ,  C08G63/127 ,  C09K3/00 ,  C08K5/10

    CPC分类号： C08G18/4208 ,  C08G18/3221 ,  C08G63/127

    摘要： A new and highly useful resin prepolymer blend of (a) polyester polyols prepared by esterifying phthalic anhydride bottoms with aliphatic polyols; (b) aliphatic polyol, (c) compatibilizing polyalkoxylated compound, and (d) (optionally) polyalkoxylated amine or amide diol. This blend can be reacted with organic isocyanates in the presence of fluorocarbon blowing agent and preferably catalysts to produce cellular polymeric structures.

    摘要翻译： 一种新的和非常有用的树脂预聚物共混物（a）通过酯化邻苯二甲酸酐底物与脂族多元醇制备的聚酯多元醇; （b）脂族多元醇，（c）相容性聚烷氧基化化合物和（d）（任选地）聚烷氧基化胺或酰胺二醇。 这种共混物可以在有机异氰酸酯的存在下在氟碳发泡剂的存在下反应，优选与催化剂反应生成多孔聚合物结构。

    Molded resin product and process for producing same
    17.
    发明授权
    Molded resin product and process for producing same 失效
    成型树脂制品及其制造方法

    公开(公告)号：US4382137A

    公开(公告)日：1983-05-03

    申请号：US232996

    申请日：1981-02-09

    申请人： Johann G. Schulz ,  Walter P. Barie, Jr. ,  James T. Eurich

    发明人： Johann G. Schulz ,  Walter P. Barie, Jr. ,  James T. Eurich

    IPC分类号： C08G63/127 ,  C08G63/12

    CPC分类号： C08G63/127 ,  Y10S264/59 ,  Y10S264/64 ,  Y10S264/65

    摘要： Novel resin products produced by reacting unique polycyclic, aromatic, polycarboxylic acid products with low molecular weight polyols display satisfactory toughness properties and good Barcol hardness values. The process for preparing these novel resin products first involves preparing an intimate, finely divided mixture comprising the acid product derived from the nitric acid oxidation of naturally occurring solid carbonaceous material, a roughly equivalent amount of a liquid polyol, and a suitable acid catalyst. The mixture is then subjected to a precure step which involves heating at temperatures between 80.degree. and 150.degree. C. for from about fifteen minutes to about four hours. The precured mixture may thereafter be subjected to suitable molding conditions at a temperature below about 220.degree. C.

    摘要翻译： 通过使独特的多环芳烃，多元羧酸产物与低分子量多元醇反应生成的新型树脂产品显示出令人满意的韧性和良好的Barcol硬度值。 制备这些新型树脂产品的方法首先包括制备紧密细碎的混合物，其包含衍生自天然固体碳质材料的硝酸氧化的酸产物，大约相当量的液体多元醇和合适的酸催化剂。 然后将混合物进行预固化步骤，其包括在80℃至150℃的温度下加热约15分钟至约4小时。 此后，预固化混合物可以在低于约220℃的温度下进行合适的成型条件。

    Acid-capped polyester resins
    18.
    发明授权
    Acid-capped polyester resins 失效
    酸封聚酯树脂

    公开(公告)号：US4379895A

    公开(公告)日：1983-04-12

    申请号：US343619

    申请日：1982-01-28

    申请人： Harlan W. Frerking, Jr. ,  Mellis M. Kelley

    发明人： Harlan W. Frerking, Jr. ,  Mellis M. Kelley

    IPC分类号： C08G63/00 ,  C08G63/127 ,  C08G63/20 ,  C08G63/88 ,  C08F283/00 ,  C08G63/76

    CPC分类号： C08G63/127 ,  C08G63/20

    摘要： A polyester resin having a low intrinsic viscosity and suitable for use as a powdered resin is modified by being capped with organic acids. The resins are made from the reaction of diesters with diols with up to 30 mole percent of the diester being replaced with various diacids. The polyester is capped following the condensation reaction stage, but before any finishing stage. The polyester resins have an acid number of from 1 to 100 and allow greater flexibility in the type of acid functionality than previously available.

    摘要翻译： 具有低特性粘度且适合用作粉末状树脂的聚酯树脂通过用有机酸封端而改性。 这些树脂由二酯与二醇的反应制成，高达30摩尔％的二酯被各种二酸代替。 在缩合反应阶段之后，但在任何整理阶段之前，聚酯被封盖。 聚酯树脂的酸值为1至100，并且比以前可获得的酸功能类型具有更大的灵活性。

    Process for preparing fiberglass preforms
    19.
    发明授权
    Process for preparing fiberglass preforms 失效
    制备光纤预制件的方法

    公开(公告)号：US3715233A

    公开(公告)日：1973-02-06

    申请号：US3715233D

    申请日：1970-09-18

    申请人： STANDARD OIL CO

    发明人： HARRIER J

    IPC分类号： C03C25/26 ,  C03C25/32 ,  C08G63/127 ,  C08G63/54 ,  B32B17/04

    CPC分类号： C03C25/323 ,  C03C25/26 ,  C08G63/127 ,  C08G63/54

    摘要： An improved process for the preparation of a polyester resin that can be solubilized in water as formed, and, when partially cured is insoluble in, but permeable to, polymerizable monomers such as styrene which comprises admixing a mixture of polycarboxyl-affording substances with a polyhydroxyl-affording substance and heating the mixture in the temperature range of 300*-450*F. until a thin sample of the material cures at 392*F. in from about 10 to about 40 seconds. The method of binding glass fibers into a mass suitable for reinforced-fiber molding purposes which comprises the steps of treating fibrous glass with the resin solubilized in water to form a resin-fiberglass composite and partially curing said composite at a temperature above about 200*F. until a water-insoluble, styrene-insoluble but styrene permeable composite is formed.

    摘要翻译： 一种制备聚酯树脂的改进方法，其可以在形成的水中溶解，并且当部分固化时不溶于但可渗透的可聚合单体如苯乙烯，其包括将多羧基提供物质的混合物与多羟基 并在300°-450°F的温度范围内加热该混合物，直至材料的薄样品在392°F左右固化，约为10至40秒。 将玻璃纤维粘合成适用于增强纤维成型目的的方法，该方法包括以下步骤：用溶解在水中的树脂处理纤维状玻璃以形成树脂 - 玻璃纤维复合材料，并在高于约200°F的温度下部分固化所述复合材料 直到形成水不溶性的苯乙烯不溶性但苯乙烯可渗透的复合材料。