公开(公告)号：US09879123B2

公开(公告)日：2018-01-30

申请号：US14372078

申请日：2013-01-17

申请人： TORAY INDUSTRIES, INC.

发明人： Kentaro Sano ,  Noriyuki Hirano ,  Masato Honma ,  Atsuki Tsuchiya

IPC分类号： C08J5/04 ,  D06M15/55 ,  C08J5/24 ,  C08L23/08 ,  C08L23/10 ,  C08J5/06 ,  D06M101/40 ,  C08L23/26

CPC分类号： C08J5/042 ,  C08J5/043 ,  C08J5/06 ,  C08J5/24 ,  C08J2323/12 ,  C08J2423/00 ,  C08J2423/14 ,  C08J2423/36 ,  C08K7/06 ,  C08K9/04 ,  C08L23/0846 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  D06M15/55 ,  D06M2101/40 ,  D10B2101/06 ,  Y10T428/249944 ,  Y10T428/249948 ,  Y10T428/2929

摘要： A molded article excellent in dynamic characteristics and water degradation resistance can be obtained by using a fiber-reinforced polypropylene resin composition including a carbodiimide-modified polyolefin (a), a polypropylene resin (b) and reinforcing fibers (c), wherein the content of the carbodiimide group contained in a resin component in the fiber-reinforced polypropylene resin composition is 0.0005 to 140 mmol based on 100 g of a matrix resin component, and the reinforcing fibers (c) are sizing-treated with a polyfunctional compound (s); and a molding material using the fiber-reinforced polypropylene resin composition.

公开(公告)号：US20180016740A1

公开(公告)日：2018-01-18

申请号：US15211814

申请日：2016-07-15

申请人： GM Global Technology Operations LLC

发明人： Hamid G. Kia ,  Nicole D. Ellison ,  Selina X. Zhao

IPC分类号： D06M15/55 ,  B26D1/22 ,  D06H7/02 ,  D06M101/40

CPC分类号： D06M15/55 ,  B26D1/225 ,  B32B3/266 ,  C08J5/042 ,  C08J5/24 ,  D06H7/02 ,  D06M2101/40 ,  D10B2101/12 ,  D10B2505/02 ,  Y10T428/24314

摘要： Methods and components produced from carbon fiber pre-impregnated composite precursor materials (pre-preg) having enhanced flowability and moldability are provided. Discontinuous cut regions are introduced into a pre-preg. A sheet of pre-preg may be contacted with a patterned surface having a plurality of non-contiguous staggered cutters, so that the contacting creates discontinuous cuts in the pre-preg. A plurality of staggered discontinuous cut regions are formed in the plurality of continuous carbon fibers that define a first plurality of carbon fibers having a first length and a second plurality of carbon fibers having a second distinct length. The patterned surface may be provided on a cutter device that is a roller or a plate having the non-contiguous staggered cutters formed or disposed thereon. The discontinuous cut regions that are formed in the pre-preg reduce stiffness and improve moldability/flowability when forming carbon fiber polymeric composites, while retaining high strength levels.

公开(公告)号：US09862824B2

公开(公告)日：2018-01-09

申请号：US14240161

申请日：2012-08-21

申请人： Kouki Wakabayashi ,  Naoki Sugiura ,  Masahiro Hata ,  Shigekazu Takeda ,  Keigo Yoshida ,  Shuuichi Nakamura

发明人： Kouki Wakabayashi ,  Naoki Sugiura ,  Masahiro Hata ,  Shigekazu Takeda ,  Keigo Yoshida ,  Shuuichi Nakamura

IPC分类号： C08L75/04 ,  D06M15/55 ,  D06M15/564 ,  C08L63/00 ,  C08J5/06 ,  C08J5/24 ,  D06M101/40 ,  C08L67/02 ,  D06M15/507 ,  D06M13/11 ,  D06M13/224 ,  C08J5/04 ,  C09D163/10

CPC分类号： C08L75/04 ,  C08J5/042 ,  C08J5/06 ,  C08J2300/24 ,  C08L63/00 ,  C09D163/10 ,  D06M13/11 ,  D06M13/2246 ,  D06M15/55 ,  D06M15/564 ,  D06M2101/40

摘要： The present invention provides: a carbon fiber sizing agent that can obtain a carbon fiber bundle having a superior effect of improving mechanical properties when composited using a resin; an aqueous dispersion thereof; a carbon fiber bundle; a sheet-shaped article having a carbon fiber bundle; and a composite material. The carbon fiber sizing agent contains: a compound (A) that is an ester of an unsaturated monobasic acid and an epoxy compound having a plurality of epoxy groups in the molecule, and that has at least one epoxy group in the molecule; a urethane acrylate oligomer (B) that is bifunctional and that has a tensile elongation rate of the cured product of at least 40%; and a polyurethane resin (C) having a tensile elongation rate of a dried coating film of 350-900% inclusive. The amounts of A-C contained satisfy the conditions described in the description. The aqueous dispersion disperses the sizing agent. The carbon fiber bundle contains 0.6-3.0 mass % inclusive of the sizing agent. The sheet-shaped article and a pultruded composite material contain the carbon fiber bundle. The composite material contains the sheet-shaped article.

公开(公告)号：US09834650B2

公开(公告)日：2017-12-05

申请号：US15122275

申请日：2015-03-05

申请人： Mitsubishi Rayon Co., Ltd.

发明人： Tadashi Ohtani ,  Atsushi Takahashi ,  Saki Fujita ,  Akira Harada

IPC分类号： C08K7/02 ,  C08J5/06 ,  D06M13/17 ,  D06M13/224 ,  D06M15/227 ,  D06M15/263 ,  D06M15/53 ,  D06M15/564 ,  C08J5/24 ,  D06M15/59 ,  D06M15/285 ,  C08J5/04 ,  C08K7/06 ,  C08K9/04 ,  B29B15/12 ,  D06M101/40 ,  C08L23/10

CPC分类号： C08J5/06 ,  B29B15/122 ,  C08F255/02 ,  C08J5/042 ,  C08J5/24 ,  C08J2300/22 ,  C08J2323/00 ,  C08J2323/12 ,  C08J2377/00 ,  C08J2433/24 ,  C08J2451/06 ,  C08J2471/02 ,  C08K7/06 ,  C08K9/04 ,  C08L23/10 ,  D06M13/17 ,  D06M13/224 ,  D06M15/227 ,  D06M15/263 ,  D06M15/285 ,  D06M15/53 ,  D06M15/564 ,  D06M15/59 ,  D06M2101/40 ,  D06M2200/50 ,  C08F222/06

摘要： A carbon fiber bundle for resin reinforcement, wherein there are adhered by 0.1-5.0 mass % to a carbon fiber bundle in which multiple lengths of filament are bundled, a mixture created by mixing an organic polymer (A) having a mass-average molecular weight of 10000 or more and an organic compound (B) the thermal reduction rate specified in claim 1 of which is 5 mass % or more or an organic compound (B) the thermal reduction rate specified in claim 2 of which is 0.8 mass % or more, the amount of the organic polymer (A) adhered being 0.1 mass % or more.

公开(公告)号：US09828477B2

公开(公告)日：2017-11-28

申请号：US13195989

申请日：2011-08-02

申请人： Nobuyuki Arai ,  Norimitsu Natsume ,  Kenichi Yoshioka ,  Junko Kawasaki ,  Hiroshi Takezaki

发明人： Nobuyuki Arai ,  Norimitsu Natsume ,  Kenichi Yoshioka ,  Junko Kawasaki ,  Hiroshi Takezaki

IPC分类号： B32B5/26 ,  B32B5/28 ,  B32B27/38 ,  C08J5/24 ,  C08L63/00 ,  B32B5/22 ,  B32B27/12 ,  B32B5/02 ,  D06M11/74 ,  D06M11/83 ,  D06M15/53 ,  D06M15/63 ,  D06M101/40

CPC分类号： C08J5/24 ,  B32B5/022 ,  B32B5/22 ,  B32B5/26 ,  B32B27/12 ,  B32B2255/02 ,  B32B2255/26 ,  B32B2260/021 ,  B32B2260/046 ,  B32B2262/106 ,  B32B2264/0214 ,  B32B2264/105 ,  B32B2264/108 ,  B32B2305/076 ,  B32B2305/08 ,  B32B2307/202 ,  B32B2307/558 ,  B32B2603/00 ,  B32B2605/18 ,  C08J2363/00 ,  C08J2477/00 ,  C08L63/00 ,  C08L2201/02 ,  D06M11/74 ,  D06M11/83 ,  D06M15/53 ,  D06M15/63 ,  D06M2101/40 ,  D06M2200/00 ,  Y10T428/24 ,  Y10T428/24994 ,  Y10T428/249942 ,  Y10T428/249948 ,  Y10T428/249949 ,  Y10T428/24995 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T442/2418 ,  Y10T442/2426 ,  Y10T442/645

摘要： A prepreg containing a carbon fiber [A] and a thermosetting resin [B], and in addition, satisfying at least one of the following (1) and (2). (1) a thermoplastic resin particle or fiber [C] and a conductive particle or fiber [D] are contained, and weight ratio expressed by [compounding amount of [C] (parts by weight)]/[compounding amount of [D] (parts by weight)] is 1 to 1000. (2) a conductive particle or fiber of which thermoplastic resin nucleus or core is coated with a conductive substance [E] is contained.

公开(公告)号：US20170298566A1

公开(公告)日：2017-10-19

申请号：US15513426

申请日：2015-08-03

申请人： E I DU PONT DE NEMOURS AND COMPANY

发明人： Bryan Benedict Sauer ,  Owen C. Compton ,  Soonjoo Son

IPC分类号： D06M11/38 ,  D06M15/59 ,  D06M15/564 ,  C08J5/06 ,  D06M101/40

CPC分类号： D06M11/38 ,  B29B15/125 ,  B29B15/127 ,  C08J5/06 ,  C08J2377/00 ,  C08J2377/02 ,  D01F11/14 ,  D06M15/564 ,  D06M15/59 ,  D06M23/06 ,  D06M2101/40

摘要： Provided are treated carbon fibers particularly suited for making thermoplastic composites with polyamide resin, and methods to make such treated carbon fibers.

公开(公告)号：US20170166712A1

公开(公告)日：2017-06-15

申请号：US15443551

申请日：2017-02-27

申请人： UT-Battelle, LLC

发明人： Frederic VAUTARD ,  Soydan Ozcan

IPC分类号： C08J5/06 ,  D06M15/55

CPC分类号： C08J5/06 ,  C08J2367/06 ,  D06M14/36 ,  D06M15/263 ,  D06M15/273 ,  D06M15/55 ,  D06M2101/40 ,  D06M2200/40 ,  D06M2400/01

摘要： A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said cros slinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.

公开(公告)号：US09617398B2

公开(公告)日：2017-04-11

申请号：US14107416

申请日：2013-12-16

申请人： UT-Battelle, LLC

发明人： Frederic Vautard ,  Soydan Ozcan

IPC分类号： C08K9/00 ,  C08J5/06 ,  D06M15/55 ,  D06M101/40

CPC分类号： C08J5/06 ,  C08J2367/06 ,  D06M14/36 ,  D06M15/263 ,  D06M15/273 ,  D06M15/55 ,  D06M2101/40 ,  D06M2200/40 ,  D06M2400/01

摘要： A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said crosslinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.

公开(公告)号：US20170073854A1

公开(公告)日：2017-03-16

申请号：US15121942

申请日：2015-02-20

申请人： HERAKLES

发明人： Chrystel HUGUET ,  Sylvie LOISON ,  Hervé EVRARD

IPC分类号： D02G3/16 ,  D06M15/643 ,  C04B35/634 ,  C04B35/638 ,  C04B35/628 ,  C04B35/80

CPC分类号： D02G3/16 ,  C04B35/62844 ,  C04B35/62863 ,  C04B35/62868 ,  C04B35/62873 ,  C04B35/62894 ,  C04B35/62897 ,  C04B35/634 ,  C04B35/63448 ,  C04B35/638 ,  C04B35/806 ,  C04B2235/5244 ,  C04B2235/5248 ,  D06M15/643 ,  D06M2101/40 ,  D06M2200/40 ,  D10B2505/02

摘要： A sized yarn for subjecting to a textile operation, the yarn including a plurality of ceramic and/or carbon fibers; an interphase coating covering the fibers; and a film covering the interphase coating and including a linear polysiloxane.

摘要翻译： 用于进行织物操作的尺寸纱线，所述纱线包括多个陶瓷和/或碳纤维; 覆盖纤维的相间涂层; 以及覆盖相间涂层并包含线性聚硅氧烷的膜。

公开(公告)号：US20170044689A1

公开(公告)日：2017-02-16

申请号：US15304192

申请日：2014-08-04

申请人： POSCO ,  POSTECH ACADEMY-INDUSTRY FOUNDATION

发明人： Kun-Hong LEE ,  Jaegeun LEE ,  A Lum JUNG

IPC分类号： D01D5/00 ,  D01F9/21 ,  D01D10/02

CPC分类号： D01D5/00 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/16 ,  D01D10/02 ,  D01F9/127 ,  D01F9/21 ,  D06M13/192 ,  D06M15/263 ,  D06M2101/40 ,  D10B2101/122

摘要： The present invention relates to carbon nanotube fiber and a producing method thereof. The carbon nanotube fiber has a tensile strength which exceeds 5 GPa, and the producing method includes: producing a carbon nanotube fiber precursor consisting of carbon nanotubes; evenly dispersing a cross-linking agent on the carbon nanotube fiber precursor; and acquiring carbon nanotube fiber by thermally treating the carbon nanotube fiber precursor wherein the cross-linking agent is evenly dispersed, wherein the acquired carbon nanotube fiber has cross-linking between wall surfaces of the carbon nanotubes each other.

摘要翻译： 碳纳米管纤维及其制造方法技术领域本发明涉及碳纳米管纤维及其制造方法。 碳纳米管纤维的拉伸强度超过5GPa，制造方法包括：制造由碳纳米管构成的碳纳米管纤维前体; 均匀分散在碳纳米管纤维前体上的交联剂; 并且通过热处理所述交联剂均匀分散的碳纳米管纤维前体获得碳纳米管纤维，其中所述获得的碳纳米管纤维在所述碳纳米管的壁表面之间具有交联。