Method for reactivating a catalyst for cyclizing hydrolysis of an aminonitrile into a lactam and use of the regenerated catalyst for making lactams
    21.
    发明授权
    Method for reactivating a catalyst for cyclizing hydrolysis of an aminonitrile into a lactam and use of the regenerated catalyst for making lactams 失效
    使催化剂再活化以使氨基腈水解成内酰胺的方法,以及使用再生催化剂制备内酰胺

    公开(公告)号:US06677448B1

    公开(公告)日:2004-01-13

    申请号:US09744157

    申请日:2001-06-11

    IPC分类号: B01J3812

    摘要: The present invention relates to a process for regenerating a catalyst for the cyclizing hydrolysis of an aminonitrile for the manufacture of lactams. It relates more particularly to the regeneration of the solid catalysts used in the processes for producing lactams by the cyclizing hydrolysis of aminonitriles. This regeneration process consists in treating the spent catalyst or the catalyst at the end of the cycle at a temperature of between 300° C. and 600° C. with an oxidizing atmosphere.

    摘要翻译: 本发明涉及用于再生用于制备内酰胺的氨腈的环化水解催化剂的方法。 更具体地涉及通过氨基腈的环化水解制备内酰胺的方法中所用的固体催化剂的再生。 该再生方法包括在循环结束时在300℃至600℃的温度下用氧化气氛处理废催化剂或催化剂。

    TREATMENTS OF TAIL GAS FROM A CLAUS UNIT OVER AN OPTIMIZED SEQUENCE OF CATALYSTS
    24.
    发明申请
    TREATMENTS OF TAIL GAS FROM A CLAUS UNIT OVER AN OPTIMIZED SEQUENCE OF CATALYSTS 有权
    来自一个条件单元的尾气处理优于催化剂序列

    公开(公告)号:US20100284879A1

    公开(公告)日:2010-11-11

    申请号:US12740408

    申请日:2008-10-29

    IPC分类号: B01D53/48

    摘要: For the conversion of sulphur-containing compounds present in a gas comprising H2S and sulphur-containing compounds into additional H2S, a step A for bringing said gas into contact with a reducing gas in the presence of a hydrogenation catalyst comprising at least cobalt, molybdenum and an alumina support, the sum of the quantities of cobalt and molybdenum, calculated in the oxide form, being in the range of 3% to 25% by weight, the surface area of said alumina being more than 140 m2/g. In step B at least a fraction of effluent gas from step A is contacted with a catalyst comprising at least one alkaline-earth element, at least one dopant being iron, cobalt or molybdenum and at least one compound of the group constituted by titanium oxide and zirconium oxide, said catalyst for step B) being either in the form of a bulk oxide comprising only said oxides or in the form of a supported oxide.

    摘要翻译: 为了将包含H 2 S和含硫化合物的气体中存在的含硫化合物转化为另外的H 2 S,在步骤A中,使氢气催化剂存在下使所述气体与还原气体接触,所述氢化催化剂至少包含钴,钼和 氧化铝载体,以氧化物形式计算的钴和钼的量的总和在3重量%至25重量%的范围内,所述氧化铝的表面积大于140m 2 / g。 在步骤B中,将来自步骤A的至少一部分流出气体与包含至少一种碱土元素,至少一种掺杂剂为铁,钴或钼的至少一种掺杂剂和至少一种由氧化钛和 氧化锆,用于步骤B)的所述催化剂为仅包含所述氧化物或以负载氧化物形式的本体氧化物的形式。

    Alumina agglomerates and preparation method thereof
    26.
    发明授权
    Alumina agglomerates and preparation method thereof 有权
    氧化铝附聚物及其制备方法

    公开(公告)号:US07090825B2

    公开(公告)日:2006-08-15

    申请号:US10473938

    申请日:2002-03-27

    摘要: The invention relates to alumina agglomerates of the type obtained by dehydrating an aluminium oxyhydroxide or hydroxide, agglomerating the alumina thus obtained, hydrothermally treating the agglomerates and calcinating same. Said agglomerates are characterised in that: the V37 Å thereof is greater than or equal to 75 ml/100 g, preferably greater than or equal to 80 ml/100 g and, better still, greater than or equal to 85 ml/100 g; the V0.1 μm thereof is less than or equal to 31 ml/100 g; and the V0.2 μm thereof is less than or equal to 20 ml/100 g, preferably less than or equal to 15 ml/100 g and, better still, less than or equal to 10 ml/100 g. The invention also relates to a catalyst carrier, an intrinsic catalyst or an absorbent, in particular for use in the petroleum and petrochemical industry, comprising such alumina agglomerates. Moreover, the invention relates to methods for preparing said agglomerates.

    摘要翻译: 本发明涉及通过使羟基氧化铝或氢氧化钠脱水得到的类型的氧化铝附聚物,使由此获得的氧化铝凝聚,热固化处理附聚物并进行煅烧。 所述附聚物的特征在于:其V 37是大于或等于75ml / 100g,优选大于或等于80ml / 100g,更好地仍大于或大于 等于85ml / 100g; 其0.1%以上的小于或等于31ml / 100g; 并且其0.2μm的小于或等于20ml / 100g,优选小于或等于15ml / 100g,更好的是小于或等于10ml / 100 G。 本发明还涉及一种催化剂载体,本征催化剂或吸收剂,特别是用于石油和石化工业中,包括这种氧化铝附聚物。 此外,本发明涉及制备所述附聚物的方法。

    Alumina agglomerates, the preparation method thereof and use of same as an absorbent or catalyst carrier
    28.
    发明申请
    Alumina agglomerates, the preparation method thereof and use of same as an absorbent or catalyst carrier 有权
    氧化铝附聚物,其制备方法和作为吸收剂或催化剂载体的用途

    公开(公告)号:US20050079126A1

    公开(公告)日:2005-04-14

    申请号:US10473938

    申请日:2002-03-27

    摘要: The invention relates to alumina agglomerates of the type obtained by dehydrating an aluminium oxyhydroxide or hydroxide, agglomerating the alumina thus obtained, hydrothermally treating the agglomerates and calcinating same. Said agglomerates are characterised in that: the V37 Å thereof is greater than or equal to 75 ml/100 g, preferably greater than or equal to 80 ml/100 g and, better still, greater than or equal to 85 ml/100 g; the V0.1 μm thereof is less than or equal to 31 ml/100 g; and the V0.2 μm thereof is less than or equal to 20 ml/100 g, preferably less than or equal to 15 ml/100 g and, better still, less than or equal to 10 ml/100 g. The invention also relates to a catalyst carrier, an intrinsic catalyst or an absorbent, in particular for use in the petroleum and petrochemical industry, comprising such alumina agglomerates. Moreover, the invention relates to methods for preparing said agglomerates.

    摘要翻译: 本发明涉及通过使羟基氧化铝或氢氧化钠脱水得到的类型的氧化铝附聚物,使由此获得的氧化铝凝聚,热固化处理附聚物并进行煅烧。 所述附聚物的特征在于:其V 37大于或等于75ml / 100g,优选大于或等于80ml / 100g,更优选大于或等于85ml / 100g; 其V0.1mum小于或等于31ml / 100g; 并且其V0.2μm小于或等于20ml / 100g,优选小于或等于15ml / 100g,更好的是小于或等于10ml / 100g。 本发明还涉及一种催化剂载体,本征催化剂或吸收剂,特别是用于石油和石化工业中,包括这种氧化铝附聚物。 此外,本发明涉及制备所述附聚物的方法。

    Process for treating gas or liquids that are obtained from catalytic reforming
    29.
    发明授权
    Process for treating gas or liquids that are obtained from catalytic reforming 有权
    用于处理从催化重整获得的气体或液体的方法

    公开(公告)号:US06409910B1

    公开(公告)日:2002-06-25

    申请号:US09344361

    申请日:1999-06-25

    申请人: Christophe Nedez

    发明人: Christophe Nedez

    IPC分类号: C10G6706

    摘要: The invention relates to a process for eliminating halogenated compounds that are contained in a gas or a liquid that comprises hydrogen and unsaturated hydrocarbons, in which the gas or the liquid is successively brought into contact with: at least one catalyst for hydrogenation, then at least one adsorbent of halogenated compounds. This gas or this liquid can be obtained from. a regenerative-type catalytic reforming.

    摘要翻译: 本发明涉及一种消除包含在气体或液体中的卤代化合物的方法,该方法包括氢气和不饱和烃,其中气体或液体依次与:至少一种用于氢化的催化剂接触,然后至少一种 卤化物的吸附剂。这种气体或这种液体可以从中获得。 再生型催化重整。

    Method for eliminating inhibitors of polymerization of monomer mixtures using an alumina with optimized form
    30.
    发明授权
    Method for eliminating inhibitors of polymerization of monomer mixtures using an alumina with optimized form 失效
    使用优化形式的氧化铝消除单体混合物聚合抑制剂的方法

    公开(公告)号:US06174480B1

    公开(公告)日:2001-01-16

    申请号:US09341956

    申请日:1999-09-09

    申请人: Christophe Nedez

    发明人: Christophe Nedez

    IPC分类号: B28B320

    CPC分类号: C07B63/00

    摘要: The invention relates to a process for adsorption of polymerization inhibitors from ethylenically unsaturated monomers, in which these inhibitors are placed in contact with an alumina produced by forming by drop coagulation or by extrusion-blending.

    摘要翻译: 本发明涉及一种从烯属不饱和单体中吸附聚合抑制剂的方法,其中这些抑制剂与通过液滴凝结或挤出共混形成的氧化铝接触。