公开(公告)号：US07202194B2

公开(公告)日：2007-04-10

申请号：US11263353

申请日：2005-10-31

Applicant: Mamoun Muhammed ,  Othan Adamopoulos ,  Tassilo Bog ,  Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Matthias Feger ,  Egbert Lox ,  Thomas Kreuzer

Inventor： Mamoun Muhammed ,  Othan Adamopoulos ,  Tassilo Bog ,  Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Matthias Feger ,  Egbert Lox ,  Thomas Kreuzer

IPC: B01J23/00 ,  B01J23/10

CPC classification number: C01G25/00 ,  B01D53/945 ,  B01D2255/206 ,  B01D2255/908 ,  B01J23/002 ,  B01J23/10 ,  B01J37/03 ,  B01J2523/00 ,  B82Y30/00 ,  C01B13/0262 ,  C01B13/0281 ,  C01F17/0018 ,  C01F17/0043 ,  C01G25/006 ,  C01P2002/50 ,  C01P2002/60 ,  C01P2004/64 ,  C01P2006/12 ,  Y02T10/22 ,  B01J2523/23 ,  B01J2523/3712 ,  B01J2523/31 ,  B01J2523/48 ,  B01J2523/3706

Abstract: An oxygen storage material comprising cerium oxide and at least one second oxide of a metal M1 is disclosed as well as a process for manufacturing the material and the use of this material in an exhaust gas cleaning catalyst. In a preferred embodiment the oxygen storage material comprises particles from a Ce/M1 mixed oxide solid solution coated with an oxide of another metal M2. Metal M1 e.g. can be calcium or zirconium while metal M2 most preferably is aluminum.

Abstract translation: 公开了一种包含氧化铈和至少一种金属M 1 O 2的第二氧化物的储氧材料，以及用于制造材料的方法以及在废气清洁催化剂中使用该材料。 在优选的实施方案中，储氧材料包含涂覆有另一种金属M 2 O 2的氧化物的Ce / M 1混合氧化物固溶体的颗粒。 金属M 1，例如 可以是钙或锆，而金属M 2最优选是铝。

公开(公告)号：US06576207B1

公开(公告)日：2003-06-10

申请号：US09056795

申请日：1998-04-08

Applicant: Lothar Mussmann ,  Renee Van Yperen ,  Dieter Lindner ,  Thomas Kreuzer ,  Egbert Lox

Inventor： Lothar Mussmann ,  Renee Van Yperen ,  Dieter Lindner ,  Thomas Kreuzer ,  Egbert Lox

IPC: B01J800

CPC classification number: B01D53/945 ,  B01D2255/908 ,  B01J20/06 ,  B01J21/06 ,  B01J21/066 ,  B01J23/10 ,  B01J35/1014 ,  B01J37/0201 ,  B01J37/031 ,  C01B13/02 ,  Y02T10/22

Abstract: An oxygen storing material with high thermal stability is disclosed which contains cerium oxide and at least one stabilizer from the group praseodymium oxide, lanthanum oxide, yttrium oxide and neodymium oxide, wherein the stabilizer(s) and optionally cerium oxide are present in highly dispersed form on the specific surface area of a high surface area support material from the group aluminum oxide, zirconium oxide, titanium oxide, silicon dioxide, cerium oxide and mixed oxides thereof and the oxygen storing material still has a specific surface area of more than 20, preferably more than 30 m2/g, after calcination in air at 900° C. for a period of 10 hours.

Abstract translation: 公开了一种具有高热稳定性的储氧材料，其含有氧化铈和至少一种氧化镨，氧化镧，氧化钇和氧化钕的稳定剂，其中稳定剂和任选的氧化铈以高分散形式存在 在氧化铝，氧化锆，氧化钛，二氧化硅，氧化铈及其混合氧化物的高表面积载体材料的比表面积上，氧储存材料的比表面积优选为20以上， 在900℃下在空气中煅烧10小时后，超过30m 2 / g。

公开(公告)号：US06348430B1

公开(公告)日：2002-02-19

申请号：US09100251

申请日：1998-06-19

Applicant: Dieter Lindner ,  Renee Van Yperen ,  Lothar Mussmann ,  Egbert Lox ,  Thomas Kreuzer

Inventor： Dieter Lindner ,  Renee Van Yperen ,  Lothar Mussmann ,  Egbert Lox ,  Thomas Kreuzer

IPC: B01J2106

CPC classification number: B01D53/945 ,  B01J23/63 ,  B01J37/0244 ,  Y02T10/22 ,  Y10S502/514

Abstract: A catalyst for treating the exhaust gas from internal combustion engines is provided, wherein the catalyst contains two catalytically active layers supported on a support. The first catalytically active layer contains a platinum group metal in close contact with all of the constituents of the first catalytically active layer, wherein the constituents of the first catalytically active layer include particulate aluminum oxide; particulate oxygen storage material, such as cerium oxide, cerium/zirconium and zirconium/cerium mixed oxides, and alkaline earth metal oxides. The second catalytically active layer, which is in direct contact with the exhaust gas, contains particulate aluminum oxide and at least one particulate oxygen storage material, such as cerium oxide, cerium/zirconium and zirconium/cerium mixed oxides. Rhodium is supported on part of the aluminum oxides in the second catalytically active layer or on the particulate oxygen storage material in the second catalytically active layer. By providing the platinum group metal in close contact with all of the constituents of the first catalytically active layer, improved conversion efficiency of the impurities in the exhaust gas can be achieved.

Abstract translation: 提供了一种用于处理来自内燃机的废气的催化剂，其中催化剂含有两个负载在载体上的催化活性层。 第一催化活性层包含与第一催化活性层的所有成分紧密接触的铂族金属，其中第一催化活性层的组分包括颗粒状氧化铝; 颗粒状储氧材料，如氧化铈，铈/锆和锆/铈混合氧化物和碱土金属氧化物。 与废气直接接触的第二催化活性层含有颗粒状氧化铝和至少一种颗粒状储氧材料，例如氧化铈，铈/锆和锆/铈混合氧化物。 铑负载在第二催化活性层中的一部分氧化铝上或第二催化活性层中的颗粒储氧材料上。 通过提供与第一催化活性层的所有成分紧密接触的铂族金属，可以实现废气中杂质的转化效率的提高。

公开(公告)号：US06294140B1

公开(公告)日：2001-09-25

申请号：US09409744

申请日：1999-10-01

Applicant: Lothar Mussmann ,  Dieter Lindner ,  Michael Harris ,  Thomas Kreuzer ,  Egbert Lox

Inventor： Lothar Mussmann ,  Dieter Lindner ,  Michael Harris ,  Thomas Kreuzer ,  Egbert Lox

IPC: B01D5394

CPC classification number: B01D53/945 ,  B01J23/58 ,  B01J23/63 ,  B01J35/04 ,  B01J37/0244 ,  B01J37/0248 ,  Y02T10/22 ,  Y10S502/514

Abstract: A catalyst for treating exhaust gas from an internal combustion engine includes a carrier body coated with an inner layer and an outer layer. The inner layer includes platinum deposited on a first support material and on a first oxygen storage component, and the outer layer includes platinum and rhodium deposited on a second support material and on a second oxygen storage component. The first and second support materials may be the same or different, and may be selected from the group of: silica, alumina, titania, zirconia, mixed oxides or mixtures thereof, and zirconia-rich zirconia/ceria mixed oxide. The first and second oxygen storage components may include ceria-rich ceria/zirconia mixed oxide compounds, optionally including praseodymia, yttria, neodymia, lanthana or mixtures thereof.

Abstract translation: 用于处理来自内燃机的废气的催化剂包括涂覆有内层和外层的载体。 内层包括沉积在第一支撑材料上的铂和第一储氧部件，外层包括沉积在第二支撑材料上的铂和铑以及第二储氧部件。 第一和第二载体材料可以相同或不同，并且可以选自二氧化硅，氧化铝，二氧化钛，氧化锆，混合氧化物或其混合物，以及富含氧化锆的氧化锆/二氧化铈混合氧化物。 第一和第二氧气存储组分可以包括富铈氧化铈/氧化锆混合氧化物化合物，任选地包括镨，氧化钇，氧化钕，氧化镧或其混合物。

公开(公告)号：US6080375A

公开(公告)日：2000-06-27

申请号：US967984

申请日：1997-11-12

Applicant: Lothar Mussmann ,  Dieter Lindner ,  Renee Van Yperen ,  Egbert Lox ,  Thomas Kreuzer

Inventor： Lothar Mussmann ,  Dieter Lindner ,  Renee Van Yperen ,  Egbert Lox ,  Thomas Kreuzer

IPC: B01D53/94 ,  B01J23/63 ,  B01J29/068 ,  B01J29/08 ,  B01J29/12 ,  B01J29/40 ,  B01J29/44 ,  B01J29/80 ,  B01J37/02 ,  F01N3/28 ,  B01J8/02

CPC classification number: B01D53/945 ,  B01D53/944 ,  B01J23/63 ,  B01J29/068 ,  B01J37/0246 ,  F01N3/2803 ,  B01D2255/902 ,  B01J29/084 ,  B01J29/40 ,  B01J29/80 ,  F01N2370/04 ,  F01N2570/12 ,  Y02T10/22

Abstract: An exhaust gas purification catalyst with improved hydrocarbon conversion is disclosed, which contains metals from the platinum group as its catalytically active components. Two superposed functional layers are applied to one support. The catalyst has a first functional layer with a mixture of a first catalyst with at least one zeolite and the second functional layer applied to the first functional layer which contains a mixture of a second catalyst and at least one zeolite. The zeolites exhibit a molar ratio of silicon dioxide/aluminum oxide of more than 40 and in that at least palladium and rhodium are present as the platinum group metals and are each contained separately from one another in only one of the two catalysts. The catalyst is distinguished by particularly good suppression of hydrocarbon emissions during cold-starting and exhibits particularly good long-term stability.

Abstract translation: 公开了一种具有改进的烃转化率的废气净化催化剂，其包含来自铂族的金属作为其催化活性组分。 两个叠加的功能层被应用于一个支撑。 催化剂具有第一功能层，其具有第一催化剂与至少一种沸石的混合物，第二功能层施加到含有第二催化剂和至少一种沸石的混合物的第一功能层。 沸石表现出二氧化硅/氧化铝的摩尔比大于40，并且至少钯和铑作为铂族金属存在，并且在两种催化剂中的仅一种中彼此分开包含。 催化剂的特征在于在冷起动期间特别好的碳氢化合物排放的抑制，并且具有特别好的长期稳定性。

公开(公告)号：US5874638A

公开(公告)日：1999-02-23

申请号：US755853

申请日：1996-12-02

Applicant: Yves Chauvin ,  Helene Olivier ,  Lothar Mussmann

Inventor： Yves Chauvin ,  Helene Olivier ,  Lothar Mussmann

IPC: B01J31/16 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07C47/12

CPC classification number: C07C45/50

Abstract: A hydroformylation process for unsaturated compounds such as monoolefins and diolefins is carried out in an ionic medium in which the catalytic species is dissolved, but in which the reaction products (aldehydes) formed are only slightly soluble or are insoluble. The ionic medium is liquid at a temperature below 90.degree. C. and comprises at least one quaternary ammonium and/or phosphonium cation and at least one anion which is preferably selected from the group formed by tetrafluoroborate when the cation is ammonium, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, perfluoroalkylsulphonates, fluorosulphonate, bis-perfluoroalkylsulphonyl amides or dichlorocuprate, tetrachlorocuprate, tetrachloroaluminate, or trichlorozincate. At the end of the reaction, the organic phase is separated out and the polar phase containing the catalyst is used again.

Abstract translation: 用于不饱和化合物如单烯烃和二烯烃的加氢甲酰化方法在其中溶解催化物质的离子介质中进行，但其中形成的反应产物（醛）仅仅是微溶或不溶解的。 离子介质在低于90℃的温度下是液体，并且包含至少一种季铵和/或鏻阳离子和至少一种阴离子，当阳离子是铵，六氟磷酸盐，六氟锑酸盐时，优选选自四氟硼酸盐形成的基团， 六氟砷酸盐，全氟烷基磺酸盐，氟磺酸盐，双全氟烷基磺酰胺或二氯磷酸盐，四氯磷酸盐，四氯铝酸盐或三氯酸锌。 在反应结束时，分离有机相，再次使用含有催化剂的极性相。

公开(公告)号：US08695329B2

公开(公告)日：2014-04-15

申请号：US12808088

申请日：2008-12-12

Applicant: Lothar Mussmann ,  Ingo Lappas ,  Andreas Geisselmann ,  Wilfried Mueller

Inventor： Lothar Mussmann ,  Ingo Lappas ,  Andreas Geisselmann ,  Wilfried Mueller

IPC: F01N3/20

CPC classification number: B01D53/9495 ,  B01D53/9418 ,  B01D53/9431 ,  B01D53/9477 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/20738 ,  B01D2255/407 ,  B01D2255/50 ,  B01D2255/91 ,  B01D2257/404 ,  B01D2258/012 ,  F01N3/035 ,  F01N3/0814 ,  F01N3/0842 ,  F01N3/0885 ,  F01N3/2006 ,  F01N3/208 ,  F01N13/009 ,  F01N2240/02 ,  F01N2560/026 ,  F01N2560/06 ,  F01N2610/02 ,  Y02A50/2325 ,  Y02T10/24 ,  Y02T10/26

Abstract: The adherence to future legally obligatory exhaust gas limit values for diesel vehicles in Europe, North America and Japan requires not only the removal of particles but also effective removal of nitrogen oxides from the exhaust gas (‘deNOx’). The ‘active SCR process’ is the preferred method for this. The nitrogen oxide conversions achieved by means of this process are particularly high when an optimal NO2/NOx ratio, preferably 0.5, is set upstream of the SCR catalyst. The invention proposes a process which solves the problem of supplying NO2 in accordance with requirements by means of temperature control of the precatalyst which is decoupled from the operating state of the engine. In an associated apparatus, a precatalyst (1) which contains at least one oxidation component and whose temperature can be controlled independently of the operating state of the engine and an active SCR stage comprising an SCR catalyst (3c) with upstream metering facility (3b) for a reducing agent from an external source (3a) are arranged in series. A particle filter (2) can be arranged between precatalyst and metering facility. The precatalyst preferably additionally contains a nitrogen oxide storage material.

Abstract translation: 欧洲，北美和日本的柴油车辆遵守未来法定义务的废气限值不仅需要除去颗粒物，而且还要有效地从废气中除去氮氧化物（“脱硝”）。 “主动SCR过程”是其中的首选方法。 当在SCR催化剂的上游设置最佳NO 2 / NO x比，优选0.5时，通过该方法实现的氮氧化物转化率特别高。 本发明提出了一种解决根据需要通过与发动机的运行状态分离的预催化剂的温度控制来供应NO 2的问题的方法。 在相关设备中，包含至少一种氧化组分并且可以独立于发动机的运行状态控制温度的预催化剂（1）和包括具有上游计量设备（3b）的SCR催化剂（3c）的主动SCR级， 用于来自外部源（3a）的还原剂被串联布置。 颗粒过滤器（2）可以布置在预催化剂和计量设备之间。 预催化剂优选另外含有氮氧化物储存材料。

公开(公告)号：US20070191220A1

公开(公告)日：2007-08-16

申请号：US11784622

申请日：2007-04-09

Applicant: Tassilo Bog ,  Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Matthias Feger ,  Egbert Lox ,  Thomas Kreuzer ,  Mamouns Muhammed ,  Othon Adamopoulos

Inventor： Tassilo Bog ,  Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Matthias Feger ,  Egbert Lox ,  Thomas Kreuzer ,  Mamouns Muhammed ,  Othon Adamopoulos

IPC: C01F17/00

CPC classification number: C01G25/00 ,  B01D53/945 ,  B01D2255/206 ,  B01D2255/908 ,  B01J23/002 ,  B01J23/10 ,  B01J37/03 ,  B01J2523/00 ,  B82Y30/00 ,  C01B13/0262 ,  C01B13/0281 ,  C01F17/0018 ,  C01F17/0043 ,  C01G25/006 ,  C01P2002/50 ,  C01P2002/60 ,  C01P2004/64 ,  C01P2006/12 ,  Y02T10/22 ,  B01J2523/23 ,  B01J2523/3712 ,  B01J2523/31 ,  B01J2523/48 ,  B01J2523/3706

Abstract: An oxygen storage material comprising cerium oxide and at least one second oxide of a metal M1 is disclosed as well as a process for manufacturing the material and the use of this material in an exhaust gas cleaning catalyst. In a preferred embodiment the oxygen storage material comprises particles from a Ce/M1 mixed oxide solid solution coated with an oxide of another metal M2. Metal M1 e.g. can be calcium or zirconium while metal M2 most preferably is aluminum.

公开(公告)号：US06875725B2

公开(公告)日：2005-04-05

申请号：US09928470

申请日：2001-08-14

Applicant: Dieter Lindner ,  Lothar Mussmann ,  Martin Votsmeier ,  Egbert Lox ,  Thomas Kreuzer

Inventor： Dieter Lindner ,  Lothar Mussmann ,  Martin Votsmeier ,  Egbert Lox ,  Thomas Kreuzer

IPC: F01N3/10 ,  B01D53/94 ,  B01J23/58 ,  B01J23/63 ,  B01J35/10 ,  B01J37/02 ,  F01N3/28 ,  B01J8/02 ,  B01J23/44 ,  B01J23/54 ,  B01J23/56

CPC classification number: B01D53/945 ,  B01J23/58 ,  B01J23/63 ,  B01J35/0013 ,  B01J35/006 ,  B01J37/0244 ,  Y02A50/2324 ,  Y02T10/22

Abstract: A starter catalyst for the purification of the exhaust gases from internal combustion engines, which include palladium on aluminum oxide and of barium oxide, as well as a process for its production. The barium oxide and palladium are together deposited in a finely divided state on the supporting material aluminum oxide and the average particle size of the palladium crystallites is between 3 and 7 nm. The small crystallite size of palladium and the barium oxide likewise deposited in finely divided state on the supporting material impart to the catalyst a high activity and long-term stability to high temperature stresses.

Abstract translation: 用于净化来自内燃机的废气的起动催化剂，其包括氧化铝上的钯和氧化钡，以及其生产方法。 氧化钡和钯一起以细分的状态沉积在载体材料的氧化铝上，钯微晶的平均粒度为3〜7nm。 同样以细分散状态沉积在支撑材料上的钯和氧化钡的小微晶尺寸赋予催化剂高的活性和对高温应力的长期稳定性。

公开(公告)号：US06524992B2

公开(公告)日：2003-02-25

申请号：US09818998

申请日：2001-03-28

Applicant: Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Egbert Lox ,  Thomas Kreuzer

Inventor： Lothar Mussmann ,  Dieter Lindner ,  Martin Votsmeier ,  Egbert Lox ,  Thomas Kreuzer

IPC: B01J2310

CPC classification number: B01D53/945 ,  B01J23/42 ,  B01J23/464 ,  B01J23/63 ,  B01J37/0248 ,  Y02T10/22

Abstract: A single layer high performance catalyst containing on an inert carrier body a catalytic coating comprising platinum, rhodium and various oxide materials. The catalyst contains a catalytic coating having at least one first support material selected from the group having a first active alumina, a ceria rich ceria/zirconia mixed oxide and a zirconia component, said at least one first support material being catalyzed with a first part of the total platinum amount of the catalyst, and a second support material catalyzed with the second part of the total platinum amount and with rhodium said second support material being a second active alumina.

Abstract translation: 在惰性载体上含有铂，铑和各种氧化物材料的催化涂层的单层高性能催化剂。 该催化剂含有具有至少一种选自具有第一活性氧化铝，富铈二氧化铈/氧化锆混合氧化物和氧化锆组分的第一载体材料的催化涂层，所述至少一种第一载体材料被第一部分催化 催化剂的总铂量，以及以总铂量的第二部分催化的第二载体材料，并且所述第二载体材料为第二活性氧化铝。