METHOD FOR THE PRODUCTION OF A SUBSTRATE HAVING A COATING COMPRISING COPPER, AND COATED SUBSTRATE AND DEVICE PREPARED BY THIS METHOD
    22.
    发明申请
    METHOD FOR THE PRODUCTION OF A SUBSTRATE HAVING A COATING COMPRISING COPPER, AND COATED SUBSTRATE AND DEVICE PREPARED BY THIS METHOD 有权
    用于生产包含铜的涂层的基材的方法和涂覆的基材和通过该方法制备的装置

    公开(公告)号:US20130062768A1

    公开(公告)日:2013-03-14

    申请号:US13232569

    申请日:2011-09-14

    Abstract: A method for producing a substrate with a copper or a copper-containing coating is disclosed. The method comprises a first step wherein a first precursor, a second precursor and a substrate are provided. The first precursor is a copper complex that contains no fluorine and the second precursor is selected from a ruthenium complex, a nickel complex, a palladium complex or mixtures thereof. In the second step, a layer is deposited at least on partial regions of a surface of the substrate by using the first precursor and the second precursor by means of atomic layer deposition (ALD). The molar ratio of the first precursor:second precursor used for the ALD extends from 90:10 to 99.99:0.01. The obtained layer contains copper and at least one of ruthenium, nickel and palladium. Finally, a reduction is performed step in which a reducing agent acts on the substrate obtained after depositing the copper-containing layer.

    Abstract translation: 公开了一种用铜或含铜涂层制造衬底的方法。 该方法包括第一步骤,其中提供第一前体,第二前体和基底。 第一前体是不含氟的铜络合物,第二前体选自钌络合物,镍络合物,钯络合物或其混合物。 在第二步骤中,通过使用第一前体和第二前体借助于原子层沉积(ALD),至少在衬底的表面的部分区域上沉积一层。 用于ALD的第一前体:第二前体的摩尔比从90:10延伸至99.99:0.01。 所得层含有铜和钌,镍和钯中的至少一种。 最后,进行还原反应,其中还原剂作用于在沉积含铜层之后获得的基板上。

    Phenothiazines, S-Oxides, And S,S-Dioxides As Well As Phenoxazines As Emitters For Oleds
    24.
    发明申请
    Phenothiazines, S-Oxides, And S,S-Dioxides As Well As Phenoxazines As Emitters For Oleds 有权
    吩噻嗪,S-氧化物和S,S-二氧化物以及苯并恶嗪作为Oleds的发射体

    公开(公告)号:US20100308714A1

    公开(公告)日:2010-12-09

    申请号:US11720274

    申请日:2005-11-25

    Abstract: The use of phenoxazine, phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivatives as emitter substances in organic light-emitting diodes, an organic light-emitting diode comprising a light-emitting layer, the light-emitting layer comprising at least one phenoxazine, phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivative as an emitter substance, and a light-emitting layer comprising or consisting of the aforementioned phenoxazine, phenothiazine-phenothiazine, phenothiazine S-oxide or phenothiazine S,S-dioxide derivative as an emitter substance, a hole- and exciton-blocking layer comprising or consisting of the aforementioned phenoxazine derivative, phenothiazine derivative, phenothiazine S-oxide derivative or phenothiazine S,S-dioxide derivative, and a device which comprises an inventive organic light-emitting diode. The present invention further relates to specific phenothiazine S,S-dioxide derivatives, phenothiazine S-oxide derivatives and phenothiazine derivatives and production processes thereof, and to their use in organic light-emitting diodes.

    Abstract translation: 在有机发光二极管中使用吩恶嗪,吩噻嗪,吩噻嗪S-氧化物或吩噻嗪S,S-二氧化物衍生物作为发射物质,包含发光层的有机发光二极管,至少包含发光层 一种吩恶嗪,吩噻嗪,吩噻嗪S-氧化物或吩噻嗪S,S-二氧化物衍生物作为发射体物质,以及由上述吩恶嗪,吩噻嗪 - 吩噻嗪,吩噻嗪S-氧化物或吩噻嗪S组成或组成的发光层,S- 作为发射体物质的二氧化物衍生物,包含前述吩恶嗪衍生物,吩噻嗪衍生物,吩噻嗪S-氧化物衍生物或吩噻嗪S,S-二氧化物衍生物或包含本发明有机光的器件的空穴 - 和激子阻断层 发光二极管。 本发明还涉及特定的吩噻嗪S,S-二氧化物衍生物,吩噻嗪S-氧化物衍生物和吩噻嗪衍生物及其制备方法,以及它们在有机发光二极管中的应用。

    Cyclic compounds and the use thereof as light absorbers, light emitters, or complex ligands
    28.
    发明申请
    Cyclic compounds and the use thereof as light absorbers, light emitters, or complex ligands 审中-公开
    环化合物及其作为光吸收剂,光发射体或复合配体的用途

    公开(公告)号:US20050167637A1

    公开(公告)日:2005-08-04

    申请号:US10509944

    申请日:2003-04-04

    Abstract: The use of cyclic compounds of the formula (I) where n is a number in the range from 1 to 7, X-Y-Z, in each case independently of one another, is O—C═N, N═C—O, NR5—C═N, N═C—NR5, N+R52—C═N, N═C—N+R52, O—C═N+R5, N+R5═C—O, S—C═N+R5, N+R5═C—S, S—C═N, N═C—S, R1, R2 and R3 each independently are, for example, H or a substituent or corresponding heterocyclic compounds in which at least one group —CR1═, —CR2═, CR3═ is replaced by —N, R5 in each case independently are, for example, H or a substituent R7, in each case independently of one another, are H, C1-12-alkyl or C6-12-aryl, or metal complexes of the cyclic compounds or complexes of the cyclic compounds with mineral acids, chloride, sulfate, bisulfate, phosphate, hydrogen phosphate, nitrate, BF4− or methanesulfonate being present as opposite ions X− in the case of cationic cyclic structures, as light absorbers, materials for hole injection layers in OLEDs, light-emitting compounds in OLED, phase-transfer catalysts or synergistic agents for the dispersing of pigments or for optical data storage, is described.

    Abstract translation: 使用式(I)的环状化合物,其中n为1至7的数,XYZ在每种情况下彼此独立地为OCN,NCO,NR 5 -CN ,NC-NR 5,N + 5,...,5,...,...,N N + > 5 5 2,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... > 5-CO,SCN +,...,5,...,...,...,... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ... ,NCS,R 1,R 2和R 3各自独立地为例如H或取代基或相应的杂环化合物,其中在 至少一个基团-CR 1, - CR 2 - , - CR 3 - 被-N,R 5, 在每种情况下,各自独立地是H或取代基R 7,在每种情况下彼此独立地为H,C 1-12 - 烷基或 C 6-12芳基或环状化合物的金属络合物或环状化合物与无机酸,氯化物,硫酸盐,硫酸氢盐,磷酸盐的络合物 在阳离子环状结构的情况下,作为阳离子环状结构存在,作为相反离子存在的磷酸根,硝酸根,BF 4 - 或 - 甲磺酸盐作为光 吸收剂,OLED中的空穴注入层的材料,OLED中的发光化合物,相转移催化剂或用于颜料分散或光学数据存储的协同剂。

    Preparation of DI- or triarylmethane dyes by oxidation
    29.
    发明授权
    Preparation of DI- or triarylmethane dyes by oxidation 失效
    通过氧化制备二 - 或三芳基甲烷染料

    公开(公告)号:US5347022A

    公开(公告)日:1994-09-13

    申请号:US38865

    申请日:1993-03-29

    CPC classification number: C09B11/18 C09B11/02

    Abstract: A process for preparing di- or triarylmethane dyes by oxidation of di- or triarylmethanes in the presence of a diluent and of an oxygen transfer catalyst that contains a complexed heavy metal ion or of a catalyst based on molybdenic acid and vanadium compounds comprises using as oxidizing agent peroxomonosulfuric acid or a salt thereof.

    Abstract translation: 通过在稀释剂和含有复合重金属离子或基于钼酸和钒化合物的催化剂的氧转移催化剂存在下氧化二芳基甲烷或三芳基甲烷制备二芳基甲烷或三芳基甲烷染料的方法包括使用氧化 代谢过氧硫酸或其盐。

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