公开(公告)号：US20200248034A1

公开(公告)日：2020-08-06

申请号：US16648764

申请日：2018-09-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jitendra S. Rathore ,  Babu N. Gaddam ,  George W. Griesgraber ,  Kevin M. Lewandowski ,  Stephen B. Roscoe

IPC: C09J7/25 ,  C08G77/388 ,  C08J5/18 ,  C09J7/38

Abstract: Silicone-based elastomeric materials, articles containing the silicone-based elastomeric materials, reaction mixtures used to form the silicone-based elastomeric materials, and methods of making the silicone-based elastomeric materials are described. The silicone-based elastomeric materials are prepared by polymerizing silicone compounds having at least two ethylenically unsaturated groups in the presence of actinic radiation and a controlled radical initiator. The controlled radical initiators are bis-dithiocarbamate or bis-dithiocarbonate compounds having a single carbon between the two dithiocarbamate or dithiocarbonate groups. The silicone-based elastomeric materials typically have improved mechanical properties compared to silicone-based elastomeric materials formed by free radical polymerization reactions in the presence of conventional photoinitiators.

公开(公告)号：US20200087547A1

公开(公告)日：2020-03-19

申请号：US16471630

申请日：2017-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Stephen B. Roscoe ,  Deepti Gopalakrishnan ,  Stefan H. Gryska ,  George W. Griesgraber ,  Serkan Yurt ,  Duane D. Fansler ,  Kevin M. Lewandowski ,  Joon Chatterjee ,  Hae-Seung Harry Lee ,  Babu N. Gaddam

IPC: C09J7/38 ,  C08F265/06 ,  C09J11/08

Abstract: Crosslinkable compositions are provided that contain a) a polymeric material having at least two terminal dithiocarbamate groups or two terminal dithiocarbonate groups and b) a monomer composition that includes at least a crosslinking monomer having two or more ethylenically unsaturated groups. The polymeric materials in the crosslinkable compositions undergo chain extension and crosslinking reactions when exposed to actinic radiation in the ultraviolet region of the electromagnetic spectrum. Additionally, crosslinked compositions, articles that contain the crosslinkable compositions or the crosslinked compositions, and methods of making the articles are provided.

公开(公告)号：US20190249044A1

公开(公告)日：2019-08-15

申请号：US16392332

申请日：2019-04-23

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jason D. Clapper ,  Arlin L. Weikel ,  Thu-Van T. Tran ,  Kevin M. Lewandowski ,  David A. Gries ,  Daniel J. Renninger

IPC: C09J133/08 ,  C09J7/38 ,  C09J7/10 ,  C08F230/08 ,  C08L33/10 ,  C08K3/36 ,  C08L33/08

CPC classification number: C09J133/08 ,  C08F230/08 ,  C08K3/36 ,  C08L33/08 ,  C08L33/10 ,  C09J7/10 ,  C09J7/385 ,  C09J2423/00 ,  C09J2433/00 ,  C09J2433/006 ,  Y10T428/2848 ,  Y10T428/2891 ,  Y10T428/31692 ,  Y10T428/31938 ,  C08L23/20

Abstract: This disclosure relates to viscoelastic damping materials and constructions which may demonstrate low temperature performance and adhesion and which may be used in making vibration damping composites. Viscoelastic damping materials and constructions may include polymers or copolymers of monomers according to formula I: CH2═CHR1—COOR2  [I] wherein R1 is H, CH3 or CH2CH3 and R2 is a branched alkyl group containing 12 to 32 carbon atoms.

公开(公告)号：US20190092936A1

公开(公告)日：2019-03-28

申请号：US16202281

申请日：2018-11-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jonathan E. Janoski ,  Anthony F. Schultz ,  Keith R. Lyon ,  Ronald S. Steelman ,  Kevin M. Lewandowski ,  Corinne E. Lipscomb ,  Terry R. Hobbs ,  Arlin L. Weikel ,  Jayshree Seth ,  Duane D. Fansler ,  Hidetoshi Abe

IPC: C08L29/14 ,  B32B27/08 ,  B32B27/30 ,  C08L33/06 ,  C08J5/18 ,  C09D133/08

Abstract: A film is described comprising a (meth)acrylic polymer and a polyvinyl acetal (e.g. butyral) resin. In some embodiments, the film has a glass transition temperature (i.e. Tg) ranging from 30° C. to 60° C. In some embodiments, the film has a gel content of at least 20% or greater. In some embodiments, the film has an elongation at break of at least 175%. The film typically comprises photoinitiator as a result of the method by which the film was made. The film may be a monolithic film or a layer of a multilayer film.

公开(公告)号：US20160304753A1

公开(公告)日：2016-10-20

申请号：US15198437

申请日：2016-06-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jason D. Clapper ,  Kevin M. Lewandowski ,  Zhong Chen ,  Steffen Traser ,  Francois C. D'Haese

IPC: C09J133/08 ,  C09J7/02

CPC classification number: C09J133/08 ,  C09J7/385 ,  C09J133/10 ,  C09J2433/00 ,  Y10T428/2891

Abstract: Pressure-sensitive adhesive compositions and articles containing the pressure-sensitive adhesives are provided. The pressure-sensitive adhesives contain an (meth)acrylic-based elastomeric material prepared an alkyl (meth)acrylate having an alkyl groups that is branched and that contains at least 14 carbon atoms.

Abstract translation: 提供压敏粘合剂组合物和含有压敏粘合剂的制品。 压敏粘合剂含有（甲基）丙烯酸类弹性体材料，其制备具有支链和含有至少14个碳原子的烷基的（甲基）丙烯酸烷基酯。

公开(公告)号：US09458327B2

公开(公告)日：2016-10-04

申请号：US14243049

申请日：2014-04-02

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Kevin M. Lewandowski ,  Larry R. Krepski ,  Yizhong Wang ,  Joel D. Oxman ,  Peiwang Zhu ,  Brian N. Holmes ,  Thomas P. Klun ,  Bryan V. Hunt

IPC: C09D4/00 ,  C08F22/22 ,  C08F222/22 ,  C07C219/06 ,  C07C229/16 ,  C07C271/16 ,  C07D233/60 ,  C08F222/10

CPC classification number: C09D4/00 ,  C07C219/06 ,  C07C229/16 ,  C07C271/16 ,  C07D233/60 ,  C08F22/22 ,  C08F222/1006 ,  C08F222/22

Abstract: A multifunctional polymerizable ionic liquid is described comprising an anion and a cationic group having at least two ethylenically unsaturated polymerizable groups, each bonded to the cationic group via a divalent non-alkyl linking group. The multifunctional linking groups independently comprise a heteroatom such as oxygen or nitrogen. The linking groups may independently comprise one or more linkages such as an amide, urea, and more typically a urethane or ester linkage. The ethylenically unsaturated polymerizable groups are typically (meth)acrylate groups. Coatings and coated articles are also described.

Abstract translation: 描述了一种多功能可聚合离子液体，其包含具有至少两个烯属不饱和可聚合基团的阴离子和阳离子基团，各自通过二价非烷基连接基团与阳离子基团键合。 多官能连接基团独立地包含杂原子如氧或氮。 连接基团可以独立地包含一个或多个键，例如酰胺，脲，更典型的是氨基甲酸酯或酯键。 烯键式不饱和可聚合基团通常为（甲基）丙烯酸酯基团。 还描述了涂层和涂层制品。

公开(公告)号：US09422964B2

公开(公告)日：2016-08-23

申请号：US14276070

申请日：2014-05-13

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Joseph D. Rule ,  Kevin M. Lewandowski

IPC: F16B19/06 ,  F16B1/00 ,  B29C61/02 ,  B29C65/68 ,  B29C65/60 ,  B29C65/00

CPC classification number: F16B19/06 ,  B29C61/02 ,  B29C65/604 ,  B29C65/68 ,  B29C66/21 ,  B29C66/304 ,  B29C66/8322 ,  B29C66/91411 ,  B29C66/91943 ,  F16B1/0014 ,  Y10T29/49865

Abstract: Fasteners for producing double blind joints where the fastener is not visible or accessible are provided. The fasteners comprise a shape memory polymer that may be used to fasten workpieces by heating the fasteners, inducing recovery of the original, permanent shape of the fasteners.

Abstract translation: 提供紧固件不可见或可接近的用于生产双盲接头的紧固件。 紧固件包括形状记忆聚合物，其可以用于通过加热紧固件来紧固工件，从而引起紧固件的原始永久形状的恢复。

公开(公告)号：US20160017187A1

公开(公告)日：2016-01-21

申请号：US14767732

申请日：2014-04-11

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Corinne E. Lipscomb ,  Duane D. Fansler ,  Kevin M. Lewandowski ,  Jonathan E. Janoski ,  Jayshree Seth ,  Arlin L. Weikel ,  John W. Vanderzanden

IPC: C09J133/08 ,  B05D1/42 ,  B05D3/06 ,  C08K3/36 ,  C08K7/28

CPC classification number: C09J133/08 ,  B05D1/42 ,  B05D3/067 ,  C08K3/36 ,  C08K7/28 ,  C08L2312/06 ,  C09J7/385 ,  C09J2205/31 ,  C09J2433/00 ,  Y10T428/1452

Abstract: A pressure sensitive adhesive composition is described comprising at least 50 wt-% of polymerized units derived from alkyl meth(acrylate) monomer(s); and 0.2 to 15 wt-% of at least one crosslinking monomers comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In another embodiment, an adhesive composition is described comprising a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl(meth)acrylate monomers; wherein the syrup comprises at least one crosslinking monomer or the (meth)acrylic solute polymer comprises polymerized units derived from at least one crosslinking monomer, the crosslinking monomer comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In yet other embodiments, methods of preparing adhesive compositions are described

Abstract translation: 描述了一种压敏粘合剂组合物，其包含至少50重量％的衍生自（甲基）丙烯酸烷基酯单体的聚合单元; 和0.2至15重量％的至少一种包含（甲基）丙烯酸酯基团和C 6 -C 20烯烃基团的交联单体，烯烃基团任选被取代。 在另一个实施方案中，描述了包含糖浆的粘合剂组合物，其包含i）可自由基聚合的溶剂单体; 和ii）包含衍生自一种或多种（甲基）丙烯酸烷基酯单体的聚合单元的溶质（甲基）丙烯酸聚合物; 其中所述糖浆包含至少一种交联单体或所述（甲基）丙烯酸溶质聚合物包含衍生自至少一种交联单体的聚合单元，所述交联单体包含（甲基）丙烯酸酯基团和C 6 -C 20烯烃基团，所述烯烃基团为 任选取代。 在其它实施方案中，描述了制备粘合剂组合物的方法

公开(公告)号：US20150183975A1

公开(公告)日：2015-07-02

申请号：US14416877

申请日：2013-07-10

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Jason D. Clapper ,  Arlin L. Weikel ,  Thu-Van T. Tran ,  David A. Gries ,  Daniel J. Renninger ,  Kevin M. Lewandowski ,  Yorinobu Takamatsu

IPC: C08L33/06 ,  C09J7/02 ,  B32B15/082 ,  C08K3/36 ,  B32B7/12 ,  B32B27/18

CPC classification number: C08L33/06 ,  B32B7/12 ,  B32B15/082 ,  B32B27/18 ,  B32B2307/56 ,  C08K3/36 ,  C08L21/00 ,  C08L33/10 ,  C08L2205/22 ,  C08L2207/53 ,  C09J7/22 ,  C09J7/24 ,  C09J7/38 ,  C09J133/04 ,  C09J2201/128 ,  C09J2201/606 ,  C09J2433/00 ,  C09J2433/006 ,  Y10T428/28 ,  Y10T428/2848 ,  Y10T428/2891 ,  Y10T428/31699 ,  Y10T428/31935

Abstract: This disclosure relates to viscoelastic damping materials and constructions which may demonstrate low temperature performance and adhesion and which may be used in making vibration damping composites. Viscoelastic damping materials and constructions may include polymers or copolymers of monomers according to formula (I): CH 2═CHR1—COOR2 wherein R1 is H, CH3 or CH2CH3 and R2 is a branched alkyl group containing 12 to 32 carbon atoms.

Abstract translation: 本公开涉及粘弹性阻尼材料和结构，其可以显示低温性能和粘合性，并且其可用于制造减振复合材料。 粘弹性阻尼材料和结构可以包括根据式（I）的单体的聚合物或共聚物：CH 2 = CHR 1 -COOR 2，其中R 1是H，CH 3或CH 2 CH 3，R 2是含有12至32个碳原子的支链烷基。

公开(公告)号：US20150033985A1

公开(公告)日：2015-02-05

申请号：US14387596

申请日：2013-03-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Maureen A. Kavanagh ,  Kevin M. Lewandowski

IPC: C08K5/1535 ,  C08K5/11 ,  C07D307/12

CPC classification number: C08K5/1535 ,  C07D307/12 ,  C07D405/12 ,  C07D405/14 ,  C08K5/11

Abstract: Compositions containing tetrahydrofurfuryl and/or alkyl-substituted tetrahydrofurfuryl esters of citric acid are provided. These esters of citric acid can be formed from renewable materials and can be used, for example, as plasticizers for various polymeric materials. The tetrahydrofurfuryl and/or alkyl-substituted tetrahydrofurfuryl esters of citric acid typically have a low odor, have good compatibility with a variety of polymeric materials, and can be used at temperatures often encountered during hot melt processing of polymeric materials.

Abstract translation: 提供了含有柠檬酸的四氢糠基和/或烷基取代的四氢糠酯的组合物。 这些柠檬酸酯可以由可再生材料形成，并且可以用作例如各种聚合材料的增塑剂。 柠檬酸的四氢糠基和/或烷基取代的四氢糠酯通常具有低气味，与各种聚合物材料具有良好的相容性，并且可以在聚合物材料的热熔融加工期间经常遇到的温度下使用。