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公开(公告)号：US20240001344A1
公开(公告)日：2024-01-04
申请号：US18208929
申请日：2023-06-13
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Xiaoying Bao , Chuansheng Bai
CPC classification number: B01J23/626 , B01J23/02 , B01J37/08 , B01J37/18 , B01J37/14
Abstract: Processes for calcining a catalyst. The process can include subjecting a synthesized catalyst that includes Pt disposed on a support to an initial calcination that includes exposing the catalyst to a first reducing gas or a first oxidizing gas to produce an initial calcined catalyst. The process can optionally include subjecting the initial calcined. catalyst to a cycle calcination that includes exposing the initial calcined catalyst to a second reducing gas and a second oxidizing gas to produce a cycle calcined catalyst. The process can optionally include subjecting the initial or the cycle calcined catalyst to a final calcination that includes exposing the initial or the cycle calcined catalyst to a third reducing gas or a third oxidizing gas. At least one of the cycle and the final calcination can be carried out. A calcined catalyst can be obtained at the end of the cycle or the final calcination.
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公开(公告)号：US10981845B2
公开(公告)日：2021-04-20
申请号：US16337271
申请日：2017-09-28
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Christine N. Elia , Wenyih F. Lai , Hari Nair , Joshua I. Cutler , Chuansheng Bai , Nicholas S. Rollman
IPC: C07C4/18 , B01J29/26 , B01J29/48 , B01J29/78 , B01J29/80 , B01J35/02 , B01J37/20 , C07C6/12 , C10G35/095
Abstract: Disclosed are processes for conversion of a feedstock comprising C8+ aromatic hydrocarbons to lighter aromatic products in which the feedstock and optionally hydrogen are contacted in the presence of the catalyst composition under conversion conditions effective to dealkylate and transalkylate said C8+ aromatic hydrocarbons to produce said lighter aromatic products comprising benzene, toluene and xylene. The catalyst composition comprises a zeolite, a first metal, and a second metal, and is treated with a source of sulfur and/or a source of steam.
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23.发明申请公开(公告)号：US20180319722A1
公开(公告)日：2018-11-08
申请号：US15949104
申请日：2018-04-10
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Larry L. Iaccino , Xiaoying Bao , Chuansheng Bai , Jeremy W. Bedard , Jocelyn A. Gilcrest , Wenyih F. Lai
CPC classification number: C07C5/387 , B01J29/44 , B01J29/46 , B01J35/026 , B01J35/08 , C07C2529/44 , C07C2529/46 , C07C2601/08 , C07C2601/10
Abstract: Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, including cyclopentadiene, and formulated catalyst compositions for use in such process. The process comprises contacting the feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form the product. The catalyst composition comprises a microporous crystalline metallosilicate, a Group 10 metal or compound thereof, a binder, optionally, a metal selected from the group consisting of rare earth metals, metals of Groups 8, 9, or 11, mixtures or combinations thereof, or a compound thereof, in combination with a Group 1 alkali metal or a compound thereof and/or a Group 2 alkaline earth metal or a compound thereof.
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公开(公告)号：US09943829B2
公开(公告)日：2018-04-17
申请号：US14916727
申请日：2014-09-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Chuansheng Bai , Jean W. Beeckman , Adrienne J. Thornburg , Natalie A. Fassbender , Sabato Miseo , Stuart L. Soled
IPC: C07C29/149 , B01J23/46 , B01J37/02 , B01J37/08 , B01J37/10 , B01J37/18 , B01J23/42 , B01J23/44 , B01J31/12 , B01J35/00 , B01J35/10 , C07C67/303 , B01J21/08 , B01J27/24
CPC classification number: B01J23/462 , B01J21/08 , B01J23/42 , B01J23/44 , B01J23/464 , B01J27/24 , B01J31/123 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J35/1061 , B01J37/0203 , B01J37/0207 , B01J37/0209 , B01J37/0242 , B01J37/0244 , B01J37/08 , B01J37/10 , B01J37/18 , B01J2531/821 , B01J2540/62 , C07C29/149 , C07C67/303
Abstract: A method of preparing a hydrogenation catalyst, for example, a phthalate hydrogenation catalyst, comprising contacting a silica support having a median pore size of at least about 10 nm with a silylating agent to form an at least partially coated silica support, calcining said coated silica support to form a treated silica support, and depositing a noble metal, preferably ruthenium, on the treated silica support, and optionally contacting the treated silica support with an optional chelating agent to form the hydrogenation catalyst; a hydrogenation catalyst prepared by that method; and a method of hydrogenating unsaturated hydrocarbons, such as phthalates, in which an unsaturated hydrocarbon is contacted with hydrogen gas in the presence of the hydrogenation catalyst of the invention.
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Patent Agency Ranking
公开(公告)号：US09861960B2
公开(公告)日：2018-01-09
申请号：US14916707
申请日：2014-09-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Chuansheng Bai , Jean W. Beeckman , Adrienne J Thornburg , Natalie A. Fassbender , Theodore E. Datz
IPC: B01J21/08 , B01J23/38 , B01J23/42 , B01J23/44 , B01J23/46 , B01J35/00 , B01J35/02 , B01J37/02 , B01J37/34 , B01J27/24 , B01J37/18 , C07C29/149 , C07C209/72 , C07C67/303 , B01J27/25 , B01J37/00
CPC classification number: B01J23/462 , B01J21/08 , B01J23/42 , B01J23/44 , B01J23/464 , B01J27/24 , B01J27/25 , B01J35/008 , B01J35/023 , B01J37/0045 , B01J37/0213 , B01J37/18 , B01J37/343 , B01J2531/821 , C07C29/149 , C07C67/303 , C07C209/72
Abstract: A method of preparing a hydrogenation catalyst, for example, a phthalate hydrogenation catalyst, comprising nebulizing a liquid containing a noble metal and a chelating agent comprising at least one nitrogen-containing functional group to form a nebulized liquid, and contacting the nebulized liquid with silica particles; a hydrogenation catalyst prepared by that method; and a method of hydrogenating unsaturated hydrocarbons, such as phthalates, in which an unsaturated hydrocarbon is contacted with hydrogen gas in the presence of the hydrogenation catalyst of the invention.
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26.发明申请公开(公告)号：US20160221895A1
公开(公告)日：2016-08-04
申请号：US15004623
申请日：2016-01-22
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Wenyih F. Lai , Christine N. Elia , Jane C. Cheng , Shifang L. Luo , Hari Nair , Joshua I. Cutler , Doron Levin , Chuansheng Bai
CPC classification number: B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , Y02P20/52
Abstract: Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a mordenite zeolite synthesized from TEA or MTEA, optionally at least one first metal of Group 10 of the IUPAC Periodic Table, and optionally at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
Abstract translation: 公开了一种催化剂组合物及其在用于转化含有C8 +芳族烃的原料以产生轻芳香族产物（包括苯，甲苯和二甲苯）的方法中的用途。 催化剂组合物包含由TEA或MTEA，IUPAC元素周期表第10组的至少一种第一金属和IUPAC元素周期表中第11至15族的至少一种第二金属合成的丝光沸石，其中所述丝光沸石 具有大于30m 2 / g的中孔表面积，并且所述丝光沸石包括由初级晶体组成的附聚物，其中所述初级晶体具有通过TEM测量的平均初晶尺寸小于80nm并且纵横比小于2 。
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公开(公告)号：US20160176785A1
公开(公告)日：2016-06-23
申请号：US14957332
申请日：2015-12-02
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Michael Salciccioli , Jihad M. Dakka , Emiel de Smit , Neeraj Sangar , Scott J. Weigel , Sumathy Raman , Terry E. Helton , Lorenzo C. DeCaul , Christine N. Ella , Chuansheng Bai , Ranjita Ghose
CPC classification number: C07C5/2737 , C07C2/66 , C07C2/74 , C07C2/82 , C07C2/86 , C07C5/2735 , C07C5/367 , C07C2521/02 , C07C2521/04 , C07C2521/10 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C07C2529/78 , C07C2601/14 , C07C15/14 , C07C13/28
Abstract: A process is described for converting at least one isomer of a dialkyl-substituted biphenyl compound, such as at least one 2,X′ dialkylbiphenyl isomer (where X′ is 2′, 3′ and/or 4′), into at least one different isomer, 3,3′, 3,4′ and/or 4,4′ dialkylbiphenyl isomer. The process comprises contacting a feed comprising the dialkyl-substituted biphenyl compound isomer with an acid catalyst under isomerization conditions.
Abstract translation: 描述了将至少一种二烷基取代的联苯化合物，例如至少一种2，X'二烷基联苯异构体（其中X'为2'，3'和/或4'）的至少一种异构体转化成至少一种 不同的异构体，3,3'，3,4'和/或4,4'-二烷基联苯异构体。 该方法包括在异构化条件下使包含二烷基取代的联苯化合物异构体的进料与酸催化剂接触。
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28.发明授权Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers 有权甲基取代联苯化合物，其生产及其在制造增塑剂中的应用公开(公告)号：US09328053B2
公开(公告)日：2016-05-03
申请号：US14201226
申请日：2014-03-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Chuansheng Bai , Jihad M. Dakka , Lorenzo C. DeCaul
CPC classification number: C07C67/08 , C07C2/74 , C07C2/76 , C07C5/367 , C07C2521/04 , C07C2521/08 , C07C2523/42 , C07C2523/62 , C07C2529/74 , C07C2529/76 , C07C2601/14 , C07C69/76 , C07C13/28 , C07C15/14
Abstract: In a process for producing a methyl-substituted biphenyl compound, at least one methyl-substituted cyclohexylbenzene compound of the formula: is contacted with a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising at least one methyl-substituted biphenyl compound, wherein each of m and n is independently an integer from 1 to 3 and wherein the dehydrogenation catalyst comprises (i) an element or compound thereof from Group 10 of the Periodic Table of Elements and (ii) tin or a compound thereof.
Abstract translation: 在制备甲基取代的联苯化合物的方法中，至少一种下式的甲基取代的环己基苯化合物在有效产生包含至少一种甲基取代的联苯化合物的脱氢反应产物的条件下与脱氢催化剂接触，其中 m和n各自独立地为1至3的整数，并且其中脱氢催化剂包含（i）元素周期表第10族元素或其化合物和（ii）锡或其化合物。
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29.发明申请Methyl-Substituted Biphenyl Compounds, Their Production and Their Use in the Manufacture of Plasticizers 有权甲基取代的联苯化合物，其生产及其在增塑剂的制造中的应用公开(公告)号：US20140275606A1
公开(公告)日：2014-09-18
申请号：US14201226
申请日：2014-03-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Chuansheng Bai , Jihad M. Dakka , Lorenzo C. DeCaul
CPC classification number: C07C67/08 , C07C2/74 , C07C2/76 , C07C5/367 , C07C2521/04 , C07C2521/08 , C07C2523/42 , C07C2523/62 , C07C2529/74 , C07C2529/76 , C07C2601/14 , C07C69/76 , C07C13/28 , C07C15/14
Abstract: In a process for producing a methyl-substituted biphenyl compound, at least one methyl-substituted cyclohexylbenzene compound of the formula: is contacted with a dehydrogenation catalyst under conditions effective to produce a dehydrogenation reaction product comprising at least one methyl-substituted biphenyl compound, wherein each of m and n is independently an integer from 1 to 3 and wherein the dehydrogenation catalyst comprises (i) an element or compound thereof from Group 10 of the Periodic Table of Elements and (ii) tin or a compound thereof.
Abstract translation: 在制备甲基取代的联苯化合物的方法中，至少一种下式的甲基取代的环己基苯化合物在有效产生包含至少一种甲基取代的联苯化合物的脱氢反应产物的条件下与脱氢催化剂接触，其中 m和n各自独立地为1至3的整数，并且其中脱氢催化剂包含（i）元素周期表第10族元素或其化合物和（ii）锡或其化合物。
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