Nitroaminophenols and their use in dyeing keratinous fibres.
    26.
    发明授权
    Nitroaminophenols and their use in dyeing keratinous fibres. 失效
    硝基苯酚及其在染色角质纤维中的应用。

    公开(公告)号:US4749379A

    公开(公告)日:1988-06-07

    申请号:US850692

    申请日:1986-04-11

    CPC classification number: A61K8/418 A61K8/4973 A61Q5/065 C07D317/66 C09B51/00

    Abstract: New nitroaminophenols, the process for preparation thereof and their use in dyeing keratinous fibres, and new intermediate nitroaminobenzenes and their use in dyeing keratinous fibres.The invention relates to a nitroaminophenol of formula: ##STR1## in which Z denotes --CH.sub.2 W, W denoting H, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 hydroxyalkyl, C.sub.2 -C.sub.6 polyhydroxyalkyl, (C.sub.1 -C.sub.3), alkoxy(C.sub.1 -C.sub.6)alkyl or (C.sub.1 -C.sub.3)hydroxyalkoxy(C.sub.1 -C.sub.6)-alkyl and R denotes H, (C.sub.1 -C.sub.6)alkyl, C.sub.1 -C.sub.6 hy-droxyalkyl, C.sub.2 -C.sub.6 polyhydroxyalkyl or (C.sub.1 -C.sub.3)-alkoxy(C.sub.1 -C.sub.6)alkyl, and the process for preparation thereof, and the intermediate compound of formula: ##STR2## in which R' denotes C.sub.1 -C.sub.6 hydroxyalkyl, C.sup.2 -C.sub.6 polyhydroxyalkyl or (C.sub.1 -C.sub.3)alkoxy(C.sub.1 -C.sub.6)alkyl and the process for preparation thereof.The dyes of formulae (I) and (II') can be used in direct dyeing of keratinous fibres, in particular, human hair.

    Abstract translation: 新的硝基氨基酚,其制备方法及其在染色角质纤维中的用途,以及新的中间硝基氨基苯及其在染色角质纤维中的用途。 本发明涉及下式的硝基氨基苯酚:其中Z表示-CH2W,W表示H,C1-C6烷基,C1-C6羟烷基,C2-C6多羟基烷基,(C1-C3),烷氧基(C1 -C 1-6)烷基或(C 1 -C 3)羟基烷氧基(C 1 -C 6) - 烷基,R表示H,(C 1 -C 6)烷基,C 1 -C 6羟基烷基,C 2 -C 6多羟基烷基或(C 1 -C 3) - 烷氧基 (C 1 -C 6)烷基及其制备方法,以及下式的中间体化合物:其中R'表示C 1 -C 6羟基烷基,C 2 -C 6多羟基烷基或(C 1 -C 3)烷氧基(C 1 -C 6) -C 6)烷基及其制备方法。 式(I)和(II')的染料可用于角质纤维,特别是人类头发的直接染色。

    3-benzylidene-camphors, process for their preparation and their use in
protection against UV rays
    28.
    发明授权
    3-benzylidene-camphors, process for their preparation and their use in protection against UV rays 失效
    3-亚苄基 - 樟脑,其制备方法及其在防紫外线中的应用

    公开(公告)号:US4654434A

    公开(公告)日:1987-03-31

    申请号:US825932

    申请日:1986-02-04

    Abstract: The invention relates to new 3-benzylidene-camphor derivatives of the formula: ##STR1## in which R.sub.1 denotes H or SO.sub.3.sup..crclbar. M.sup..sym., with M=H, an alkali metal or N.sup..sym. (R.sub.3).sub.4, with R.sub.3 =H or C.sub.1 -C.sub.4 alkyl or hydroxyalkyl; R.sub.2 denotes C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and n=0-4; and Z denotes ##STR2## in which R.sub.4 has the same meaning as R.sub.1 and can be identical or different, or alternatively ##STR3## in which R.sub.5 denotes H, optionally substituted aryl, C.sub.1 -C.sub.4 alkyl, --CN, --C00R7 or ##STR4## and R.sub.6 denotes --COOR.sub.8 or ##STR5## in which R.sub.7 and R.sub.8, which are identical or different, denote alkyl, alkenyl, cycloalkyl or aralkyl and R.sub.9 and R.sub.10, which are identical or different, denote H, alkyl, alkenyl or cycloalkyl; if R.sub.5 =H, alkyl or aryl, R.sub.6 can represent --COO.sup..crclbar. M.sup..sym. ; the methylidene-camphor radical, on the one hand, and the radical Z, on the other hand, are in the meta or para position. These derivatives act as sun filters.

    Abstract translation: 本发明涉及下式的新的3-亚苄基 - 樟脑衍生物:其中R 1表示H或SO 3( - )M(+),其中M = H,碱金属或N(+)( R3)4,其中R3 = H或C1-C4烷基或羟烷基; R2表示C1-C4烷基或C1-C4烷氧基,n = 0-4; 并且Z表示其中R 4具有与R 1相同的含义并且可以相同或不同,或者其中R 5表示H,任选取代的芳基,C 1 -C 4烷基,-CN,-COOR 7或

    Quaternized polymers; process for preparing the same; and cosmetic
compositions containing the same
    30.
    发明授权
    Quaternized polymers; process for preparing the same; and cosmetic compositions containing the same 失效
    季铵化聚合物; 制备方法; 和含有它们的化妆品组合物

    公开(公告)号:US4608250A

    公开(公告)日:1986-08-26

    申请号:US490852

    申请日:1983-05-02

    Abstract: A quaternized polymer having recurring units of the formula ##STR1## wherein X.sup..crclbar. represents an anion derived from an organic or mineral acid;R'.sub.2 is an aliphatic radical having a maximum of 20 carbon atoms;R'.sub.1 is an aliphatic, alicyclic or arylaliphatic radical containing a minimum of 2 carbon atoms and a maximum of 20 carbon atoms, or R'.sub.1 and R'.sub.2 together with the nitrogen atom to which they are attached form a ring capable of containing a second heteroatom other than said nitrogen;A represents a divalent group of the formula ##STR2## wherein x, y and t are whole numbers ranging from 0 to 11 and being such that the sum (x+y+t) is greater than or equal to 0 and less than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms;B represents a divalent group of the formula ##STR3## --CH.sub.2 --CHOH--CH.sub.2 --, --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n -- or ##STR4## wherein D and G represent hydrogen or an aliphatic radical having less than 18 carbon atoms and v, z, and u are whole numbers ranging from 0 to 11, two of them being able to be simultaneously equal to 0 such that the sum (v+z+u) is greater than or equal to 1 and lower than 18, and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, and n is a whole number equal to 2 or 3.The polymers are usefully employed in cosmetic compositions for application to the hair or skin.

    Abstract translation: 具有式“IMAGE”的重复单元的季铵化聚合物,其中X( - )表示衍生自有机或无机酸的阴离子; R'2是具有最多20个碳原子的脂族基团; R'1是含有最少2个碳原子和最多20个碳原子的脂族,脂环族或芳基脂族基团,或者R 1和R 2与它们所连接的氮原子一起形成能够含有 除所述氮之外的第二杂原子; A表示式(1)的二价基团,其中x,y和t为0〜11的整数,并且使(x + y + t)之和大于等于0且小于18, 并且E和K表示氢或具有少于18个碳原子的脂族基团; B表示下式的二价基团:-CH 2 -CHOH-CH 2 - , - (CH 2)n O-(CH 2)n - 或者其中D和G表示氢或具有少于18个碳原子的脂族基团 并且v,z和u是从0到11的整数,它们中的两个能够同时等于0,使得(v + z + u)大于等于1且小于18, 并且当和(x + y + t)之和等于0时,和(v + z + u)大于1,n是等于2或3的整数。聚合物可用于化妆品 适用于头发或皮肤的组合物。

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