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公开(公告)号：US20090198014A1
公开(公告)日：2009-08-06
申请号：US12160001
申请日：2006-12-07
CPC分类号： C08G63/47 , C07C29/80 , C07C2601/14 , C08G63/199 , C08G64/42 , C09D175/16 , C07C31/276
摘要： A mixture of compounds useful to make a polymer or a prepolymer, the mixture of compounds including compounds having the formula I; wherein R1 is H, acryloyl, methacryloyl or vinyl, wherein R2 is acryloyl, methacryloyl or vinyl, wherein compounds having the formula I consist of a mixture of cis and trans-1,3- and 1,4-substituted cyclohexane and wherein the trans-1,4-substituted cyclohexane content of the compounds having the formula I is less than forty mole percent. A process for producing a mixture of compounds including compounds having the formula II: wherein compounds having the formula II consist of a mixture of cis and trans-1,3- and 1,4-methanol substituted cyclohexane and wherein the trans-1,4-methanol substituted cyclohexane content of the compounds having the formula II is less than twenty five mole percent.
摘要翻译： 可用于制备聚合物或预聚物的化合物的混合物，化合物的混合物包括具有式I的化合物; 其中R 1是H，丙烯酰基，甲基丙烯酰基或乙烯基，其中R 2是丙烯酰基，甲基丙烯酰基或乙烯基，其中具有式I的化合物由顺式和反式-1,3-和1,4-取代的环己烷的混合物组成， 具有式I的化合物的-1,4-取代的环己烷含量小于40摩尔％。 一种制备包括具有式II化合物的化合物的混合物的方法：其中具有式II的化合物由顺式和反式-1,3-和1,4-甲醇取代的环己烷的混合物组成，其中反式-1,4 具有式II的化合物的甲醇取代的环己烷含量小于25摩尔％。
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公开(公告)号：US20090192286A1
公开(公告)日：2009-07-30
申请号：US11991276
申请日：2006-09-26
IPC分类号： C08G63/123
CPC分类号： C08G18/423 , C08G63/199 , C08G2150/20 , C09D167/02 , C09D175/06 , Y10T428/31504
摘要： A polymer containing a polyester polymer unit having the formula —(I-III-II)—, wherein III is derived form a di-carboxylic acid, wherein I is derived from 1,3 cyclohexanedimethanol, wherein II is derived from 1,4 cyclohexanedimethanol and wherein the polymer is a solid at room temperature.
摘要翻译： 含有具有式 - （I-III-II） - 的聚酯聚合物单元的聚合物，其中III衍生自二羧酸，其中I衍生自1,3-环己烷二甲醇，其中II衍生自1,4-环己烷二甲醇 并且其中所述聚合物在室温下为固体。
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公开(公告)号：US20080103263A1
公开(公告)日：2008-05-01
申请号：US11660775
申请日：2005-09-02
IPC分类号： C08L63/00
CPC分类号： C08G18/753 , C08G18/706 , C08G18/757 , C08G18/792 , C09D175/04
摘要： The present invention is to emulsifiable polyisocyanate compositions comprising the reaction product of (i) an aliphatic polyisocyanate and (ii) an emulsifier wherein the polyisocyanate comprises a mixture of two or more isomers of cis-1,3-bis(isocyanatomethyl)cyclohexane, trans-1,3-bis(isocyanatomethyl)cyclohexane, cis-1,4-bis(isocyanatomethyl)cyclohexane or trans-1,4-bis(isocyanatomethyl)cyclohexane, with the proviso said isomeric mixture comprises at least about 5 weight percent of said trans-1,4-bis(isocyanatomethyl)cyclohexane. The emulsifiable polyisocyanates are particularly in formulations for producing paints and varnishes, coatings, adhesives, impregnating materials and sealants.
摘要翻译： 本发明涉及可乳化的多异氰酸酯组合物，其包含（i）脂族多异氰酸酯和（ii）乳化剂的反应产物，其中所述多异氰酸酯包含顺式-1,3-双（异氰酸酯基甲基）环己烷的两种或多种异构体的混合物，反式 1,3-双（异氰酸根合甲基）环己烷，顺式-1,4-双（异氰酸甲酯基）环己烷或反式-1,4-双（异氰酸甲酯基）环己烷，条件是所述异构体混合物包含至少约5重量％ 反式-1,4-双（异氰酸甲酯基）环己烷。 可乳化的多异氰酸酯特别是用于制备油漆和清漆，涂料，粘合剂，浸渍材料和密封剂的制剂。
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公开(公告)号：US07232859B2
公开(公告)日：2007-06-19
申请号：US10531944
申请日：2003-10-28
CPC分类号： C08G18/757 , C08G18/0823 , C08G18/12 , C08G18/283 , C08G18/4018 , C08G18/4277 , C08G18/4854 , C08G18/664 , C08G18/6692 , Y10T428/31551 , C08G18/302 , C08G18/3234 , C08G18/3228
摘要： The present invention is to a polyurethane dispersion and products produced therefrom wherein the dispersion contains a polyurethane prepolymer produced from the a reaction of an excess of a polyisocyanate with an isocyanate reactive molecule wherein the polyisocyanate is a bis(isocyanatomethyl)cyclohexane. Preferably the isocyanate comprises (i) trans-1,4-bis(isocyanatomethyl)cyclohexane or (ii) an isomeric mixture of two or more of cis-1,3-bis(isocyanatomethyl)cyclohexane, trans-1,3-bis(isocyanatomethyl)cyclohexane, cis-1,4-bis(isocyanatomethyl)cyclohexane and trans-1,4-bis(isocyanatomethyl)cyclohexane, with the proviso said isomeric mixture comprises at least about 5 weight percent of said trans-1,4-bis(isocyanatomethyl)cyclohexane.
摘要翻译： 本发明涉及聚氨酯分散体及其制备的产品，其中分散体含有由过量的多异氰酸酯与异氰酸酯反应性分子的反应生成的聚氨酯预聚物，其中多异氰酸酯是双（异氰酸酯基甲基）环己烷。 优选地，异氰酸酯包含（i）反式-1,4-双（异氰酸甲酯基）环己烷或（ii）顺式-1,3-双（异氰酸甲酯基）环己烷，反式-1,3-双（异氰酸根合甲基） 异氰酸酯基甲基）环己烷，顺式-1,4-双（异氰酸甲酯基）环己烷和反式-1,4-双（异氰酸甲酯基）环己烷，条件是所述异构体混合物包含至少约5重量％的所述反式-1,4-双 （异氰酸甲酯基）环己烷。
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公开(公告)号：US5952530A
公开(公告)日：1999-09-14
申请号：US17456
申请日：1998-02-02
IPC分类号： B01J31/18 , B01J31/40 , C07B63/00 , C07C45/50 , C07C45/80 , C07C47/02 , C07C51/373 , C07C51/48 , C07C59/147 , C07F9/02 , C07F9/144 , C07F9/145 , C07F9/50 , C07F9/6574
CPC分类号： B01J31/0259 , B01J31/0267 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/2404 , B01J31/4015 , B01J31/4046 , B01J31/4053 , C07C45/50 , B01J2231/32 , B01J2231/321 , B01J2231/52 , B01J2231/641 , B01J2531/822 , B01J2531/90 , Y02P20/582 , Y02P20/584
摘要： This invention relates to a process for separating one or more products from a reaction product fluid comprising a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a nonpolar solvent and said one or more products, wherein said process comprises (1) mixing said reaction product fluid with a polar solvent to obtain by phase separation a non-polar phase comprising said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and said nonpolar solvent and a polar phase comprising said one or more products and polar solvent, and (2) recovering said polar phase from said nonpolar phase; wherein said organophosphorus ligand has a partition coefficient between the nonpolar solvent and the polar solvent of greater than about 5, and said one or more products have a partition coefficient between the polar solvent and the nonpolar solvent of greater than about 0.5.
摘要翻译： 本发明涉及从反应产物流体中分离一种或多种产物的方法，该反应产物流体包括金属 - 有机磷配体配合物催化剂，任选的游离有机磷配体，非极性溶剂和所述一种或多种产物，其中所述方法包括（1）将 反应产物流体与极性溶剂通过相分离获得包含所述金属 - 有机磷配体配合物催化剂，任选的游离有机磷配体和所述非极性溶剂的非极性相和包含所述一种或多种产物和极性溶剂的极性相，和（ 2）从所述非极性相中回收所述极性相; 其中所述有机磷配体在非极性溶剂和极性溶剂之间的分配系数大于约5，并且所述一种或多种产物在极性溶剂和非极性溶剂之间具有大于约0.5的分配系数。
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26.发明授权Polyurethane dispersion, method of producing the same, coated articles, and method for coating articles 有权聚氨酯分散体，其制造方法，涂布制品和涂布物品的方法公开(公告)号：US09512262B2
公开(公告)日：2016-12-06
申请号：US13262572
申请日：2010-02-08
申请人： Bedri Erdem , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Paul Foley , Debkumar Bhattacharjee
发明人： Bedri Erdem , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Paul Foley , Debkumar Bhattacharjee
IPC分类号： C08G18/08 , C08G18/36 , C08G18/66 , C09D175/04 , B32B27/40
CPC分类号： C08G18/6662 , B32B27/40 , C08G18/0819 , C08G18/0823 , C08G18/36 , C09D175/04
摘要： The instant invention is a polyurethane dispersion, method of producing the same, coated articles, and method for coating articles. The polyurethane dispersion according to the present inventions includes (a) one or more polyurethane units derived from one or more prepolymers wherein the one or more prepolymers comprise the reaction product of a mixture dissolved in dipropylene glycol dimethyl ether in the presence of one or more first surfactants with one or more isocyanates, wherein the mixture comprises one or more natural oil based polyols, and one or more adipate polyols, and optionally one or more short diols; and (b) water.
摘要翻译： 本发明是一种聚氨酯分散体，其制备方法，涂覆制品和用于涂覆制品的方法。 根据本发明的聚氨酯分散体包括（a）一种或多种衍生自一种或多种预聚物的聚氨酯单元，其中一种或多种预聚物包含溶解在二丙二醇二甲醚中的混合物的反应产物，在一种或多种第一 具有一种或多种异氰酸酯的表面活性剂，其中所述混合物包含一种或多种天然油基多元醇，和一种或多种己二酸酯多元醇，以及任选的一种或多种短二醇; 和（b）水。
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公开(公告)号：US09018334B2
公开(公告)日：2015-04-28
申请号：US13639535
申请日：2011-03-15
申请人： Steven Montgomery , Shawn Brown , Mark F. Sonnenschein , Paul Foley , Phillip S. Athey , Juan Carlos Medina , John N. Argyropoulos , Benjamin L. Wendt , Cecile Boyer
发明人： Steven Montgomery , Shawn Brown , Mark F. Sonnenschein , Paul Foley , Phillip S. Athey , Juan Carlos Medina , John N. Argyropoulos , Benjamin L. Wendt , Cecile Boyer
IPC分类号： C08G18/00 , C08G64/02 , C08G18/08 , C08G18/12 , C08G18/44 , C08G18/66 , C08G18/75 , C08G64/30 , C09D175/06
CPC分类号： C08G64/0216 , C08G18/0823 , C08G18/12 , C08G18/44 , C08G18/664 , C08G18/6659 , C08G18/755 , C08G64/305 , C09D175/06 , C08G18/3231 , C08G18/3228
摘要： Embodiments of the invention provide for a polycarbonate polyol including the reaction product of at least one polyol composition and a carbonate. The polycarbonate is one of an amorphous liquid and an amorphous solid at room temperature. The polyol composition includes at least one of a mixture of 1,3-cyclohexanedimethanol and 1,4-cyclohexanedimethanol in a weight ratio from about 60:40 to about 5:95 and a polyol derived from a natural oil fatty acid or natural oil fatty acid methyl ester.
摘要翻译： 本发明的实施方案提供了包含至少一种多元醇组合物和碳酸酯的反应产物的聚碳酸酯多元醇。 聚碳酸酯是室温下的无定形液体和无定形固体之一。 多元醇组合物包括重量比为约60:40至约5:95的1,3-环己烷二甲醇和1,4-环己烷二甲醇的混合物中的至少一种和衍生自天然油脂肪酸或天然油脂肪酸的多元醇 酸甲酯。
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28.发明授权Polyurethane dispersion, method of producing the same, coated articles, and method for coating articles 有权聚氨酯分散体，其制造方法，涂布制品和涂布物品的方法公开(公告)号：US08927646B2
公开(公告)日：2015-01-06
申请号：US13262574
申请日：2010-03-31
申请人： Bedri Erdem , Debkumar Bhattacharjee , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Suresh Subramonian
发明人： Bedri Erdem , Debkumar Bhattacharjee , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Suresh Subramonian
IPC分类号： C08G18/36 , C09D175/04 , C08G18/08 , C08G18/32
CPC分类号： C08G18/36 , C08G18/0823 , C08G18/0866 , C08G18/3212 , C08G18/3228 , C09D175/04 , Y10T428/31551
摘要： The instant invention is a polyurethane dispersion, method of producing the same, coated articles, and method of coating articles. The polyurethane dispersion according to the instant invention comprises (a) one or more polyurethane units derived from one or more prepolymers, wherein the one or more prepolymers comprise the reaction product of one or more natural oil based polyols dissolved in dipropylene glycol dimethyl ether in the presence of one or more first surfactants with one or more isocyanates; and (b) water.
摘要翻译： 本发明是聚氨酯分散体，其制造方法，涂布制品，以及涂布物品的方法。 根据本发明的聚氨酯分散体包含（a）一种或多种衍生自一种或多种预聚物的聚氨酯单元，其中一种或多种预聚物包含一种或多种溶于二丙二醇二甲醚中的天然油基多元醇的反应产物 一种或多种第一表面活性剂与一种或多种异氰酸酯的存在; 和（b）水。
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29.发明授权Ambient temperature curable isocyanate-free compositions for preparing crosslinked polyurethanes 有权用于制备交联聚氨酯的环境可固化异氰酸酯的组合物公开(公告)号：US08653174B2
公开(公告)日：2014-02-18
申请号：US13160604
申请日：2011-06-15
申请人： Jeffrey R. Anderson , John N. Argyropoulos , Debkumar Bhattacharjee , Paul Foley , Gary E. Spilman , Huiqing Zhang
发明人： Jeffrey R. Anderson , John N. Argyropoulos , Debkumar Bhattacharjee , Paul Foley , Gary E. Spilman , Huiqing Zhang
CPC分类号： C08G18/3831 , C08G18/792 , C09D175/04 , C09D175/12
摘要： The present invention provides a multicomponent composition that is substantially isocyanate-free and comprises a polycarbamate as a first component and a polyaldehyde or an acetal or hemiacetal thereof as a second component and further comprises an effective amount of a triggering agent such that the first and second components to cure at a temperature of from 0C to less than 80C to form a crosslinked polyurethane. The multicomponent composition forms an ambient temperature curable composition when all of its components are combined that has a pH of 7.0 or less. The present invention also provides processes crosslinked polyurethanes, and the crosslinked polyurethanes prepared by the processes.
摘要翻译： 本发明提供了一种多组分组合物，其基本上不含异氰酸酯，并且包含作为第一组分的聚氨基甲酸酯和作为第二组分的聚甲醛或缩醛或半缩醛，并且还包含有效量的引发剂，使得第一和第二 组分在0℃至小于80℃的温度下固化以形成交联的聚氨酯。 当其组分的所有组分的pH为7.0或更低时，多组分组合物形成环境温度可固化的组合物。 本发明还提供交联聚氨酯和通过该方法制备的交联聚氨酯的方法。
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公开(公告)号：US08318834B2
公开(公告)日：2012-11-27
申请号：US12988874
申请日：2009-05-04
IPC分类号： C08G59/60
CPC分类号： C09D163/00 , C08G59/226 , C08G59/38 , C08L63/00
摘要： An epoxy resin reactive diluent composition comprises an epoxy resin diluent (A) and a resin compound (B), wherein the epoxy resin diluent (A) comprises a cis, trans-1,3- and -1,4-cyclohexanedimethylether moiety; and wherein the resin compound (B) comprises one or more epoxy resins other than the epoxy resin diluent (A). A curable epoxy resin composition comprises the epoxy resin reactive diluent composition and a curing agent and/or curing catalyst therefore. A cured epoxy resin is prepared by curing the curable epoxy resin composition.
摘要翻译： 环氧树脂反应性稀释剂组合物包含环氧树脂稀释剂（A）和树脂化合物（B），其中环氧树脂稀释剂（A）包含顺式，反式-1,3-和-1,4-环己烷二甲醚部分; 并且其中所述树脂化合物（B）包含除环氧树脂稀释剂（A）以外的一种或多种环氧树脂。 因此，可固化环氧树脂组合物包含环氧树脂反应性稀释剂组合物和固化剂和/或固化催化剂。 通过固化可固化环氧树脂组合物制备固化的环氧树脂。
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