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    Pyridyl insecticidally active cyano compounds
    27.
    发明授权
    Pyridyl insecticidally active cyano compounds 失效
    吡啶类杀虫活性氰化合物

    公开(公告)号：US5066808A

    公开(公告)日：1991-11-19

    申请号：US584398

    申请日：1990-09-14

    申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Ikuro Honda ,  Yumi Hattori ,  Katsuhiko Shibuya

    发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Ikuro Honda ,  Yumi Hattori ,  Katsuhiko Shibuya

    IPC分类号： C07D237/08 ,  A01N47/40 ,  C07D213/38 ,  C07D213/40 ,  C07D213/61 ,  C07D213/74 ,  C07D231/12 ,  C07D239/26 ,  C07D239/30 ,  C07D241/12 ,  C07D261/08 ,  C07D263/34 ,  C07D271/10 ,  C07D277/20 ,  C07D277/28 ,  C07D277/32 ,  C07D333/28 ,  C07D521/00

    CPC分类号： C07D213/40 ,  C07D213/61 ,  C07D239/26 ,  C07D241/12 ,  C07D277/32

    摘要： A cyano compound useful as an insecticide, of the formula (I) ##STR1## wherein R.sup.1 is hydrogen, cyano or C.sub.1-4 alkyl, m is 0 or 1,R.sup.2 is hydrogen, C.sub.1-6 alkyl, C.sub.3-4 alkenyl optionally substituted by halogen,C.sub.3-4 alkynyl, C.sub.3-8 cycloalkyl optionally substituted by methyl, optionally substituted phenyl, optionally substituted benzyl, hydroxy, C.sub.1-4 alkoxy or --CH.sub.2 --Z, in which Z has the same meanings as stated below,R.sup.3 is ##STR2## in which R.sup.4 is C.sub.1-6 alkyl, C.sub.3-4 alkenyl, C.sub.3-4 alkynyl, C.sub.3-8 cycloalkyl, optionally substituted phenyl, optionally substituted benzyl or --(CH.sub.2)n-Z, in which n is 1 or 2 andZ has the same meanings as stated below, andR.sup.5 and R.sup.6 are hydrogen, C.sub.1-9 alkyl optionally substituted by at least one selected from a group consisting of halogen, hydroxy, mercapto, C.sub.1-2 alkoxy, C.sub.1-2 alkylthio, C.sub.3-6 cycloalkyl, amino, C.sub.1-2 monoalkylamino, C.sub.2-4 (in total)di-alkylamino, carboxy, C.sub.1-2 alkoxy-carbonyl and cyano, C.sub.3-4 alkenyl optionally substituted by halogen, C.sub.3-4 alkynyl, optionally substituted phenyl, optionally substituted benzyl, C.sub.1-4 alkoxy, hydroxy, formyl, C.sub.1-4 alkoxy-carbonyl, C.sub.1-4 alkylamino, C.sub.2-4 (in total)di-alkylamino, amino, acyl or ##STR3## in which R.sup.1 and m have the same meanings as stated above, and Z has the same meanings as stated below, and in addition,R.sup.5 and R.sup.6 may form, together with the N-atom to which they are bonded, a 3 to 7 membered ring which may be substituted by C.sub.1-2 alkyl and may contain N, O or S as the member of said ring, besides the N-atom to which they are bonded, andZ is a substituted 5 or 6 membered heterocyclic group which contains at least one heteroatom selected from N, O and S as a ring member, provided that where Z is pyridyl substituted by halogen, m is 1, R.sup.2 is C.sub.1-6 alkyl and R.sup.3 is --S--alkyl(C.sub.1-6) or --S--benzyl, then R.sup.1 is cyano or C.sub.1-4 alkyl.

    Pesticidal nitro-substituted heterocyclic compounds
    28.
    发明授权
    Pesticidal nitro-substituted heterocyclic compounds 失效
    杀虫硝基取代的杂环化合物

    公开(公告)号：US4876263A

    公开(公告)日：1989-10-24

    申请号：US208421

    申请日：1988-06-17

    申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

    发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Shoko Sasaki ,  Koichi Moriya ,  Yumi Hattori ,  Katsuhiko Shibuya

    IPC分类号： A01N43/90 ,  A01N47/12 ,  A01N47/18 ,  C07D471/04 ,  C07D487/04 ,  C07D498/04 ,  C07D513/04

    CPC分类号： C07D471/04 ,  A01N43/90 ,  A01N47/18 ,  C07D487/04 ,  C07D513/04

    摘要： Nitro-subsliluted heterocyclic compounds of the formula (I) ##STR1## wherein R is hydrogen or alkyl, Z is an optionally substituted aryl or optionally subtituted heterocyclic groun containing at least one atom selected from N, O and S,A is optionally substituted ethylene or optionally substituted trimethylene, andB stands for 2 or 3 members of a heterocyclic ring which is formed, together with the adjacent C-atom and N-aom and at least one of said members may represent a hetero atom and may be optionally substituted, provided that when B stands for 3 members, two of which are carbon atoms and the other one is a nitrogen atom which is located in the middle of the three members, then at least one of said two carbon atoms must be substituted by a keto group. Such compounds being useful as insecticides.

    摘要翻译： 硝基亚稀释的式（I）的杂环化合物其中R是氢或烷基，Z是任选取代的芳基或含有至少一个选自N，O和S的原子的任选取代的杂环化合物，A是 任选取代的乙烯或任选取代的三亚甲基，B代表杂环的2或3个成员，其与相邻的C原子和N-aom一起形成，并且所述成员中的至少一个可以表示杂原子，并且可以是 任选取代，条件是当B代表3个成员时，其中两个是碳原子，另一个是位于三个成员中间的氮原子，则所述两个碳原子中的至少一个必须被 一个酮基。 这些化合物可用作杀虫剂。

    Insecticidal heterocyclic compounds
    29.
    发明授权
    Insecticidal heterocyclic compounds 失效
    杀虫杂环化合物

    公开(公告)号：US06344453B1

    公开(公告)日：2002-02-05

    申请号：US09294099

    申请日：1999-04-19

    申请人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Katsuhiko Shibuya

    发明人： Kozo Shiokawa ,  Shinichi Tsuboi ,  Koichi Moriya ,  Katsuhiko Shibuya

    IPC分类号： A61K31549

    CPC分类号： C07D401/06 ,  A01N47/40 ,  A01N51/00 ,  C07D401/14 ,  C07D403/06 ,  C07D405/06 ,  C07D409/06 ,  C07D413/06 ,  C07D417/06 ,  C07D419/06

    摘要： Insecticidal heterocyclic compounds of the formula wherein A represents a five-membered or six-membered heteroaryl group containing one to three hetero atoms selected from the group consisting of S, O and N, said heteroaryl group being unsubstituted or substituted by a halogen atom or C1-4 alkyl group, Z represents a three-membered straight chain, each member being selected from the group consisting of CH2—, O, S and N—R2 with at least one of said three members being O, S or N—R2, E represents CH2, O, S or N—R2, wherein R2 represents a hydrogen atom, a C1-4 alkyl group, a C1-4 alkoxy group or the group  wherein R3 represents a hydrogen atom or halogen atom, X represents CH or N, Y represents a nitro group or cyano group, and R1 represents a hydrogen atom or methyl group.

    摘要翻译： 甲基脲A的杀虫杂环化合物表示含有一至三个选自S，O和N的杂原子的五元或六元杂芳基，所述杂芳基未被取代或被卤素原子或C1- 4个烷基，Z表示三元直链，每个成员选自CH 2 - ，O，S和N-R 2，所述三个成员中的至少一个为O，S或N-R2，E 表示CH2，O，S或N-R2，其中R2表示氢原子，C1-4烷基，C1-4烷氧基或R3表示氢原子或卤原子的基团，X表示CH或N， Y表示硝基或氰基，R 1表示氢原子或甲基。