Process for the reduction of gasoline benzene content by alkylation with dilute ethylene
    23.
    发明授权
    Process for the reduction of gasoline benzene content by alkylation with dilute ethylene 有权
    用稀乙烯烷基化还原汽油苯含量的方法

    公开(公告)号:US08895793B2

    公开(公告)日:2014-11-25

    申请号:US12813533

    申请日:2010-06-11

    IPC分类号: C07C2/66

    摘要: The process converts ethylene in a dilute ethylene stream and dilute benzene in an aromatic containing stream via alkylation to heavier hydrocarbons. The catalyst may be a zeolite such as UZM-8. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, and hydrogen and selectively converts benzene. At least 40 wt-% of the ethylene in the dilute ethylene stream and at least 20 wt-% of the benzene in the dilute benzene stream can be converted to heavier hydrocarbons.

    摘要翻译: 该方法将稀乙烯流中的乙烯和通过烷基化的含芳烃的物流中的苯稀释成较重的烃。 催化剂可以是沸石如UZM-8。 该催化剂耐受诸如硫化氢,碳氧化物和氢气的杂质,并选择性地转化苯。 稀乙烯流中至少40重量%的乙烯和稀苯流中至少20重量%的苯可以转化为较重的烃。

    PROCESS FOR THE REDUCTION OF GASOLINE BENZENE CONTENT BY ALKYLATION WITH DILUTE ETHYLENE
    25.
    发明申请
    PROCESS FOR THE REDUCTION OF GASOLINE BENZENE CONTENT BY ALKYLATION WITH DILUTE ETHYLENE 有权
    通过与稀释乙烯进行烷基化还原汽油苯含量的方法

    公开(公告)号:US20110306809A1

    公开(公告)日:2011-12-15

    申请号:US12813533

    申请日:2010-06-11

    IPC分类号: C07C2/66 C07C2/02

    摘要: The process converts ethylene in a dilute ethylene stream and dilute benzene in an aromatic containing stream via alkylation to heavier hydrocarbons. The catalyst may be a zeolite such as UZM-8. The catalyst is resistant to feed impurities such as hydrogen sulfide, carbon oxides, and hydrogen and selectively converts benzene. At least 40 wt-% of the ethylene in the dilute ethylene stream and at least 20 wt-% of the benzene in the dilute benzene stream can be converted to heavier hydrocarbons.

    摘要翻译: 该方法将稀乙烯流中的乙烯和通过烷基化的含芳烃的物流中的苯稀释成较重的烃。 催化剂可以是沸石如UZM-8。 该催化剂耐受诸如硫化氢,碳氧化物和氢气的杂质,并选择性地转化苯。 稀乙烯流中至少40重量%的乙烯和稀苯流中至少20重量%的苯可以转化为较重的烃。

    Process for alkylation of aromatic hydrocarbons using UZM-35
    28.
    发明授权
    Process for alkylation of aromatic hydrocarbons using UZM-35 有权
    使用UZM-35烷基化芳烃的方法

    公开(公告)号:US08071830B1

    公开(公告)日:2011-12-06

    申请号:US13151780

    申请日:2011-06-02

    IPC分类号: C07C2/52

    摘要: Alkylation processes such as the alkylation of aromatics, are catalyzed by the UZM-35 family of crystalline aluminosilicate zeolites represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolites are active and selective in alkylation processes.

    摘要翻译: 烷基化方法如芳族化合物的烷基化由UZM-35族结晶硅铝酸盐沸石催化,其经验式为Mmn + Rr + Al(1-x)ExSiyOz,其中M表示钾和钠可交换阳离子的组合, R是单电荷的有机铵阳离子,例如二甲基二丙基铵阳离子,E是骨架元素如镓。 这些UZM-35沸石在烷基化过程中是活性的和选择性的。