公开(公告)号：US20190336954A1

公开(公告)日：2019-11-07

申请号：US15967896

申请日：2018-05-01

Applicant: Pacific Industrial Development Corporation

Inventor： Wei Wu ,  Geng Zhang ,  De Gao ,  David Shepard ,  Yunkui Li ,  Jeffery Lachapelle

IPC: B01J29/76 ,  B01J29/70 ,  B01J35/00 ,  B01J35/10 ,  B01J37/30 ,  B01J37/02 ,  B01D53/94 ,  F01N3/20

Abstract: A crystalline, core-shell hybrid Chabazite (CHA) material for use as a catalyst has a core with a silicon to aluminum ratio (SAR) that is less than 25 and a shell that at least partially encapsulates the core, the shell having an SAR of about 25 or greater. The crystalline, core-shell hybrid Chabazite is prepared by forming a first chabazite (CHA) material having a silicon to aluminum ratio (SAR) that is less than 25, placing the first CHA material into an aqueous reaction mixture comprising one or more precursors capable of forming a second chabazite (CHA) material having an SAR that is 25 or greater, growing the second CHA material on the surface of the first CHA material, and collecting the core-shell hybrid CHA material.

公开(公告)号：US10328421B2

公开(公告)日：2019-06-25

申请号：US14669187

申请日：2015-03-26

Applicant: Pacific Industrial Development Corporation

Inventor： Manjola Mancka ,  Yunkui Li ,  Jeffery LaChapelle ,  Wei Wu ,  David Shepard

IPC: B01D53/86 ,  B01J29/70 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  C01B39/08 ,  C01B39/48 ,  B01J29/72 ,  B01D53/94

Abstract: The present disclosure generally provides novel STT-type zeolite materials called PIDC-120501, PIDC-120502, and PIDC-120805/120806 or PIDC-type zeolites and a method of making these zeolites. The present disclosure also provides for the use of these zeolite materials as a catalyst and a method of preparing said catalyst. The PIDC-type zeolites or STT-type zeolite materials may be used as a catalyst, such as in Selective Catalytic Reduction (SCR) applications.

公开(公告)号：US10232348B2

公开(公告)日：2019-03-19

申请号：US15184247

申请日：2016-06-16

Applicant: Pacific Industrial Development Corporation

Inventor： Wei Wu ,  Yunkui Li ,  Jeffery Lachapelle ,  David Shepard

IPC: B01J23/10 ,  B01J23/72 ,  B01J35/10 ,  B01D53/94 ,  B01J23/22 ,  B01J23/83 ,  B01J37/00

Abstract: A catalyst support material (D-CZMLA) with oxygen storage capacity corresponds to the formula vD:x(Ce1-wZrwO2):yM:zL:(1-v-x-y-z)Al2O3, wherein w is a molar ratio between 0.1-0.8 and v, x, y, and z are weight ratios, such that v is between 0.005-0.15, x is between 0.05-0.80, and y and z are between 0.001-0.10. M is an interactive promoter for oxygen storage, L is a stabilizer (L) for the Al2O3 support; and D is an oxidizing dopant. The catalyst support material can be incorporated into a wash coat that combines platinum group metals (PGM), an adhesive, and a mixture of (α)RE-Ce—ZrO2+(β)CZMLA+(1−α−β)RE-Al2O3, wherein RE-Ce—ZrO2 is a rare earth element stabilized ceria zirconia having a weight ratio (α) between 0-0.7; CZMLA is the doped catalyst support material having a weight ratio (β) between 0.2-1, such that (α+β)≤1; and RE-Al2O3 is rare earth element stabilized alumina having a weight ratio equal to (1−α−β).

公开(公告)号：US20250125334A1

公开(公告)日：2025-04-17

申请号：US18702101

申请日：2022-10-12

Applicant: Pacific Industrial Development Corporation

Inventor： Bing Tan ,  Yuhao Liao ,  Andrew Rajewski ,  Wei Wu

IPC: H01M4/131 ,  H01M4/02 ,  H01M4/133 ,  H01M4/36 ,  H01M4/505 ,  H01M4/66 ,  H01M10/0565

Abstract: A cell for use in an electrochemical cell, that includes a positive electrode having a current collector, a pre-lithiated active cathode material according to the formula F-1 of Li1+xMn2O4, wherein x is in the range of 0.1 to 1.0, and an optional additional active cathode material; a negative electrode having a current collector and an optional carbonaceous material that exhibits a negligible capacity, wherein negligible capacity is defined as being a reversible capacity ratio between the carbonaceous material and the pre-lithiated active cathode material of

公开(公告)号：US11904303B2

公开(公告)日：2024-02-20

申请号：US17292753

申请日：2019-11-08

Applicant: Pacific Industrial Development Corporation

Inventor： De Gao ,  Yunkui Li ,  David Shepard ,  Jeffery Lachapelle ,  Wei Wu

IPC: F01N3/28 ,  B01J29/76 ,  B01D53/94 ,  B01J37/02 ,  B01J37/30 ,  C01B39/48

CPC classification number: B01J29/76 ,  B01D53/9418 ,  B01J37/0207 ,  B01J37/30 ,  C01B39/48 ,  B01D2255/20761 ,  B01D2255/50 ,  B01J2229/18 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/38 ,  F01N3/2803 ,  F01N2370/04

Abstract: A method of forming an AFX zeolite in a hydrothermal synthesis that exhibits a silica to alumina (SiO2AI2O3) molar ratio (SAR) that is between 8:1 and 26:1; has a morphology that includes one or more of cubic, spheroidal, or rhombic particles with a crystal size that is in the range of about 0.1 micrometer (μm) to 10 μm. This AFX zeolite also exhibits a Brönsted acidity that is in the range of 1.2 mmol/g to 3.6 mmol/g as measured by ammonia temperature programmed desorption. A catalyst formed by substituting a metal into the framework of the zeolite exhibits about a 100% conversion of NO emissions over the temperature range of 300° C. to 650° C.

公开(公告)号：US11635009B2

公开(公告)日：2023-04-25

申请号：US16959465

申请日：2019-01-07

Applicant: Pacific Industrial Development Corporation

Inventor： Anatoly Bortun ,  Mila Bortun ,  David Shepard ,  Yunkui Li ,  Jin Cho ,  Wei Wu ,  Jeffery Lachapelle

IPC: B01J23/00 ,  F01N3/10 ,  B01J23/04 ,  B01J35/00 ,  B01J35/10 ,  B01J37/03 ,  B01J37/08

Abstract: A method of making an oxygen storage material (OSM) with developed mesoporosity having a small fraction of pores

公开(公告)号：US20190381477A1

公开(公告)日：2019-12-19

申请号：US16430916

申请日：2019-06-04

Applicant: Pacific Industrial Development Corporation

Inventor： David Shepard ,  Christopher Zyskowski ,  Jessica Brown ,  Jeffery Lachapelle ,  Wei Wu

IPC: B01J20/08 ,  B01J20/06 ,  B01J20/28 ,  B01J23/72 ,  B01J23/745 ,  B01J23/75 ,  B01J21/06 ,  B01J35/02 ,  B01J35/10 ,  B01J35/04 ,  B01D53/94 ,  B01D53/04

Abstract: An inorganic oxide material doped with nano-rare earth oxide particles that is capable of trapping one or more of NOx or SOx at a temperature that is less than 400° C. The nano-rare earth oxide particles have a particle size that is less than 10 nanometers. The catalyst support can trap at least 0.5% NO2 at a temperature less than 350° C. and/or at least 0.4% SO2 at a temperature less than 325° C. The catalyst support can trap at least 0.5% NO2 and/or at least 0.2% SO2 at a temperature that is less than 250° C. after being aged at 800° C. for 16 hours in a 10% steam environment. The catalyst support exhibits at least a 25% increase in capacity for at least one of NOx or SOx trapping at a temperature that is less than 400° C. when compared to a conventional rare earth doped support in a 10% steam environment.

公开(公告)号：US20190112198A1

公开(公告)日：2019-04-18

申请号：US16088858

申请日：2017-03-30

Applicant: Pacific Industrial Development Corporation

Inventor： Anatoly Bortun ,  David Shepard ,  Yunkui Li ,  Wei Wu ,  Jeffery Lachapelle

IPC: C01G25/00

Abstract: Mesoporous, zirconium-based mixed oxides and a method of making the same comprises: injecting a polyvalent metal-containing solution into an electrolyte solution to form a mother liquor; forming a precipitate; aging the precipitate in the mother liquor to form the mixed oxides; washing the mixed oxides with an aqueous medium; drying and collecting the mixed oxides. The pH of the electrolyte solution exceeds the isoelectric point for zirconium-based mixed oxides. The mixed oxides exhibit a single particle size distribution, improved Ce02 reducibility in the presence of Rhodium, a decrease in surface area after calcination (800-1 100° C.) that is not more than 55%, and a tetragonal/cubic structure after calcination. After calcination at 1 100° C. for 10 hours in air, the mixed oxides exhibit a surface area >25 m2/g, a pore volume >0.20 cm3/g, an average pore size >30 nm, and an average crystallite size between 8-15 nm.

公开(公告)号：US09597666B2

公开(公告)日：2017-03-21

申请号：US15179122

申请日：2016-06-10

Applicant: Pacific Industrial Development Corporation

Inventor： Wei Wu ,  Yunkui Li ,  Jeffery Lachapelle

IPC: B01J23/10 ,  B01J23/63 ,  B01J21/04 ,  B01J35/10 ,  B01J35/02 ,  B01J37/04 ,  B01J37/00 ,  B01J37/06 ,  B01J37/03 ,  B01J37/02 ,  B01J37/08 ,  B01D53/94

CPC classification number: B01J23/63 ,  B01D53/945 ,  B01D2255/102 ,  B01D2255/1023 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2068 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/908 ,  B01J21/04 ,  B01J21/066 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1028 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/009 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0215 ,  B01J37/0221 ,  B01J37/0236 ,  B01J37/031 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J2523/00 ,  Y02A50/2324 ,  Y02T10/22 ,  B01J2523/31 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/3725 ,  B01J2523/48

Abstract: A wash coat is formed by combining platinum group metals (PGM) and an adhesive with a mixture of catalyst support materials according to the relationship (α)RE-Ce—ZrO2+(β)CZMLA+(1−α−β)RE-Al2O3. The RE-Ce—ZrO2 is a commercial material of rare earth elements stabilized ceria zirconia having a weight ratio (α) ranging from 0 to about 0.7; CZMLA is a catalyst support material comprising a core support powder coated with a solid solution and has a weight ratio (β) ranging from about 0.2 to about 1 such that (α+β)≦1. RE-Al2O3 is rare earth element stabilized alumina having a weight ratio equal to (1−α−β). The wash coat exhibits a lower activation temperature compared with traditional wash coat formulations by at least 50° C. This wash coat also requires less RE-Ce—ZrO2 oxide and/or less PGM in the formulation for use as an emission control catalyst for gasoline and diesel engines.

公开(公告)号：US20160296910A1

公开(公告)日：2016-10-13

申请号：US15184247

申请日：2016-06-16

Applicant: Pacific Industrial Development Corporation

Inventor： Wei Wu ,  Yunkui Li ,  Jeffery Lachapelle ,  David Shepard

IPC: B01J23/10 ,  B01J23/72 ,  B01D53/94 ,  B01J35/00 ,  B01J35/10 ,  B01J35/02 ,  B01J21/04 ,  B01J23/40

CPC classification number: B01J23/10 ,  B01D53/945 ,  B01D2255/102 ,  B01D2255/2042 ,  B01D2255/2061 ,  B01D2255/2063 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20746 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/407 ,  B01D2255/908 ,  B01J23/22 ,  B01J23/72 ,  B01J23/83 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0018 ,  B01J2523/00 ,  Y02A50/2324 ,  Y02T10/22 ,  B01J2523/17 ,  B01J2523/36 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/48

Abstract: A catalyst support material (D-CZMLA) with oxygen storage capacity corresponds to the formula vD:x(Ce1-wZrwO2):yM:zL:(1−v−x−y−z)Al2O3, wherein w is a molar ratio between 0.1-0.8 and v, x, y, and z are weight ratios, such that v is between 0.005-0.15, x is between 0.05-0.80, and y and z are between 0.001-0.10. M is an interactive promoter for oxygen storage, L is a stabilizer (L) for the Al2O3 support; and D is an oxidizing dopant. The catalyst support material can be incorporated into a wash coat that combines platinum group metals (PGM), an adhesive, and a mixture of (α)RE-Ce—ZrO2+(β)CZMLA+(1−α−β)RE-Al2O3, wherein RE-Ce—ZrO2 is a rare earth element stabilized ceria zirconia having a weight ratio (α) between 0-0.7; CZMLA is the doped catalyst support material having a weight ratio (β) between 0.2-1, such that (α+β)≦1; and RE-Al2O3 is rare earth element stabilized alumina having a weight ratio equal to (1−α−β).

Abstract translation: 具有储氧能力的催化剂载体材料（D-CZMLA）对应于式vD：x（Ce1-wZrwO2）：yM：zL：（1-v-x-y-z）Al2O3，其中w是 0.1-0.8和v，x，y和z是重量比，使得v在0.005-0.15之间，x在0.05-0.80之间，y和z在0.001-0.10之间。 M是氧储存的交互式促进剂，L是Al2O3载体的稳定剂（L）; D是氧化性掺杂剂。 催化剂载体材料可以结合到组合铂族金属（PGM），粘合剂和（α）RE-Ce-ZrO 2 +（β）CZMLA +（1-α-β）RE-Al 2 O 3的混合物的洗涤涂层中， 其中RE-Ce-ZrO 2是重量比（α）在0-0.7之间的稀土元素稳定的氧化铈氧化锆; CZMLA是重量比（β）在0.2-1之间的掺杂催化剂载体材料，使得（α+β）≤1; RE-Al2O3是重量比等于（1-α-β）的稀土元素稳定的氧化铝。