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    SYNTHESIS OF CYCLOPHANES FROM A SELF-ASSEMBLY REACTION
    23.
    发明申请
    SYNTHESIS OF CYCLOPHANES FROM A SELF-ASSEMBLY REACTION 有权
    从自组装反应合成环己烷

    公开(公告)号：US20160137598A1

    公开(公告)日：2016-05-19

    申请号：US14944584

    申请日：2015-11-18

    申请人： University of Oregon

    发明人： Darren W. Johnson ,  Mary Collins

    IPC分类号： C07C321/16 ,  C07D251/24

    CPC分类号： C07D251/24 ,  C07C321/16 ,  C07D341/00 ,  C07D495/22

    摘要： Disclosed herein is a novel method for preparing cyclophanes, comprising forming a disulfide cyclophane by contacting a linker moiety which includes two or more thiol groups, with a metal salt and an oxidant. The disulfide cyclophane is then desulfurized to form a thiacyclophane comprising thioether bridges. This thiacyclophane optionally may be further desulfurized to form an unsaturated hydrocarbon cyclophane, which can then be reduced to form a saturated hydrocarbon cyclophane. The various cyclophanes can be synthesized in a ring form, such as a dimer, trimer or tetramer etc., or they can be synthesized in a tetrahedral or larger structure. Also disclosed are novel cyclophanes formed by the disclosed method.

    摘要翻译： 本文公开了一种制备环庚烷的新方法，包括通过使包含两个或更多个硫醇基团的连接体部分与金属盐和氧化剂接触形成二硫化物环烷烃。 然后将二硫化环己烷脱硫形成包含硫醚桥的硫辛环。 任选地可以将该硫辛酸盐进一步脱硫以形成不饱和烃环烷烃，然后将其还原形成饱和烃环烷烃。 各种环戊二烯可以以二聚体，三聚体或四聚体等环形式合成，或者它们可以四面体或更大结构合成。 还公开了通过所公开的方法形成的新型环庚烷。