摘要:
The present invention relates to a polymer for use as a bleach activator, comprising the monomer units where n is an integer from 1 to 4 and R is a branched or unbranched, saturated hydrocarbyl radical having from 1 to 20 carbon atoms, to processes for the preparation and to the use thereof as laundry detergents, cleaning compositions and disinfectant compositions, and also in textile bleaching and paper bleaching.
摘要:
The invention relates to novel choline ascorbate-containing formulations; processes for their preparation and their use in human or animal foods, or human or animal food supplements or pharmaceuticals.
摘要:
The present invention relates to a process for the preparation of N-phosphonomethylglycine by reacting a hexahydrotriazine derivative with a triacyl phosphite. The process gives N-phosphonomethylglycine in high yield and in a simple and inexpensive manner.
摘要:
The invention describes a process for the preparation of (S,S)-N,N′-ethylenediaminedisuccinic acid or analogous compounds or their salts by reaction of L-aspartic acid, L-glutamic acid or L-cysteic acid with 1,2-bissulfooxyethane, 1,3,2-dioxathiolane 2,2-dioxide or mixtures thereof or 1,3-bissulfooxy-2-hydroxypropane in the presence of a base, and optional subsequent acidification with an acid. Also described is a process for the preparation of (S,S)-N,N′-ethylenediaminedisuccinic acid or analogous compounds or their salts by reaction of N-(2-sulfooxyethyl)-L-aspartic acid or its salts with L-aspartic acid or corresponding compounds based on L-glutamic acid, L-cysteic acid and/or 1,3-bissulfooxy-2-hydroxypropane in the presence of a base, and optional subsequent acidification with an acid.
摘要:
Inorganic per compounds may be activated with oxime carbonates of the formula (I), A—O—CO—OR3, a hydroximide ester of formula (II): or polymeric hydroximide esters.
摘要:
A process for preparing vicinal diols or polyols from an organic reaction mixture containing formic esters of vicinal diols or polyols, in which water is added to the reaction mixture, without addition of bases, and the formic esters are hydrolyzed in a subsequent thermal treatment, the aqueous formic acid is removed, and vicinal diols or polyols remain behind.
摘要:
In a process for preparing an alkoxylated amide of the formula (I)R.sup.1 --CO--NR.sup.2 --CHR.sup.3 --CHR.sup.4 --O--(CHR.sup.5 --CHR.sup.6 --O).sub.n --H (I)(1) glycerides of the fatty acids, specified later on, of the formula (II):R.sup.1 --COOH (II)are reached with amines of the formula (III)HNR.sup.2 R.sup.7 (III)to give amides of the formula (IV)R.sup.1 --CO--NR.sup.2 --R.sup.7 (IV)and glycerol,(2) then the glycerol which has been formed is separated off by adding of aqueous acid solution to the reaction mixture until it has a pH in the range 1-7, in order to bring about phase separation into a glycerol-containing aqueous phase and an organic phase containing amides of the formula (IV), and separating off the aqueous phase, and(3) subsequently the amide of the formula (IV) is reacted with ethylene oxide and/or propylene oxide and/or butylene oxide to give alkoxylated amides of the formula (I).
摘要:
Glycine-N,N-diacetic acid derivatives I ##STR1## where R is unsubstituted or substituted alkyl, alkenyl, alkoxylate groups, phenylalkyl, phenyl, a heterocyclic ring or a radical of the formula ##STR2## where A is an alkylene bridge or a chemical bond, and M is hydrogen, alkali metal, alkaline earth metal, ammonium or substituted ammonium in the appropriate stoichiometric amounts, are prepared by reacting A) corresponding 2-substituted glycines or 2-substituted glycinonitriles or doubled glycines of the formula ##STR3## or doubled glycinonitriles of the formula ##STR4## or precursors of the glycine derivatives named as starting material with formaldehyde and hydrogen cyanide in aqueous medium at a pH of from 0 to 11 or B) iminodiacetonitrile or iminodiacetic acid with appropriate monoaldehydes of the formula R--CHO or dialdehydes of the formula OHC--A--CHO and hydrogen cyanide in aqueous medium at a pH of from 0 to 11 and, where appropriate, subsequent hydrolysis of nitrile functionalities which are present, where the starting material used comprises unpurified raw material derived from the industrial synthesis of glycine derivatives or their precursors or of iminodiacetonitrile or iminodiacetic acid, or mother liquors produced in such syntheses.
摘要:
Glycine-N, N-diacetic acid derivatives are prepared by reacting corresponding 2-substituted glycines, 2-substituted glycinonitriles, doubled glycines, or precursors of the glycine derivatives with formaldehyde and alkali metal cyanide. The reaction is conducted in an aqueous medium at a pH of 8 to 14. From 0, 5 to 30% of the amount of alkali metal cyanide required for the reaction are added to the glycine derivatives or precursors thereof Subsequently, the remaining amount of alkali metal cyanide and the formaldehyde are simultaneously metered in over a period of from 0.5 to 12 hours.
摘要:
Disclosed is the use of glycine-N,N-diacetic acid derivatives as their alkali metal, alkaline earth metal, ammonium and substituted ammonium salts as complexing agents for alkaline earth and heavy metal ions, except with .alpha.-alanine-N,N-diacetic acid, as textile detergent builders in powdered detergent formulations and as calcium sequestering agents in oral hygiene products.