摘要:
A catalytic reforming process is disclosed using a catalyst containing a Group VIII metal, low amounts of bismuth, and a zeolite L. The catalyst is a non-acidic, monofunctional reforming catalyst. Preferably, the catalyst contains one or more halogens. Preferably, the feed includes C.sub.8 hydrocarbons. The addition of small amounts of bismuth increase or substantially maintain catalyst stability. Unexpectedly low dealkylation rates are achieved using the catalyst while reforming to produce aromatics, especially to produce xylenes such as paraxylene.
摘要:
A high temperature treatment process is disclosed for increasing conversion and reducing the fouling rate of reforming catalysts. The process comprises reducing the catalyst in a reducing gas atmosphere at a temperature below 1025.degree. F. and then treating the reduced catalyst at a temperature of from 1025.degree. F. to 1275.degree. F. in an inert gas atmosphere.
摘要:
Color change devices which are capable of undergoing a color change on bending. The devices comprise a flexible substrate having a color generating metal (e.g. a valve metal such as Ta or Nb) at at least one surface and an intimately contacting optically thin anodic film covering the color generating metal and generating a visible color by light interference and absorption effects. The thin anodic film is produced by anodizing the color generating metal in the presence of an adhesion-reducing agent (e.g. a fluoride) for weakening the normally tenacious bond between the anodic film and the metal. Devices of this kind capable of being activated by bending, as well as by separation of the constituent layers, are produced by carrying out the anodization step in the presence of a particular concentration of the adhesion reducing agent from a narrow range (e.g. 40-350 ppm of fluoride). The devices can be used as tamper evident labels and the like which show evidence of removal of the labels from articles to which they are originally attached as an indication of tampering.
摘要:
A process for the alkylation or transalkylation of an aromatic hydrocarbon which comprises contacting the aromatic hydrocarbon with a C.sub.2 to C.sub.4 olefin alkylating agent or a polyalkyl aromatic hydrocarbon transalkylating agent, under at least partial liquid phase conditions, and in the presence of a catalyst comprising zeolite beta.
摘要:
Apparatus and procedure for applying a paint or like coating to an elongated strip article using a coating head having an open-sided slot to which coating material is supplied under pressure, and a support such as a roll around which the strip is advanced past the head for receiving from the slot a layer of paint metered between the head and the strip, wherein a load is continuously exerted on the head during operation for urging the head against the applied paint layer on the strip so as to maintain a uniform metering gap between the head and the coated strip surface. The load may be exerted by devices such as air cylinders acting on the head and capable of adjustment to vary the magnitude of the load for different coating operations.
摘要:
A continuous length of aluminum is anodized during passage through an anodizing electrolyte and then colored during passage through an inorganic coloring electrolyte, in which a counterelectrode is immersed. In the electrolytic coloring stage alternating current with a superimposed D.C. compound is preferably passed between the anodized aluminum and the counterelectrode when the electrolyte is appropriate for such treatment. The alternating current circuit for the electrolytic coloring stage is preferably completed via an electrode immersed in the anodizing electrolyte at a position facing substantially unanodized aluminum so as to effect a liquid contact.
摘要:
A process for preparing acrylonitrile which comprises passing a gaseous mixture comprising propylene, ammonia and molecular oxygen and an ammoxidation catalyst through a reaction zone while controlling the superficial linear gas velocity and solids feeds rate to achieve a state of fast fluidization.
摘要:
A process is set forth for reacting impure toluene to obtain benzene, toluene and a para-rich xylene stream, which are substantially free of close-boiling non-aromatics. The impure toluene comprises at least 70 wt % toluene and between about 0.2 wt % and about 5 wt % close-boiling non-aromatics. The process may also comprise aromatizing a naphtha over a non-acidic catalyst. The impure toluene from the aromatization step is passed over an acidic intermediate pore zeolite to produce a para-rich xylene stream and chemically pure benzene.
摘要:
There are herein disclosed an L-type zeolite catalyst which is obtainable by supporting a platinum component, one or more halogen components and one or more metal components selected from the group Ib of the periodic table on an L-type zeolite, the support amount of one or more metal components selected from the group Ib being in the range of 0.001 to 3% by weight based on the total weight of the catalyst in terms of the metal, a molar ratio of one or more metal components selected from the group Ib/platinum being in the range of 0.01 to 1; and a method for producing aromatic hydrocarbons or a gasoline having a high octane number which comprises the step of bringing one or more fractions selected from a C6 fraction, a C7 fraction, and a C8.sup.+ fraction into contact with this catalyst. According to the present invention, there are provided a catalyst containing an L-type zeolite as a carrier which is desirable as a catalyst for the production of aromatic hydrocarbons or a gasoline having a high octane number and which can inhibit a cracking activity and the formation of coke and can improve an aromatic selectivity and a liquid yield.