公开(公告)号：US4895910A

公开(公告)日：1990-01-23

申请号：US161822

申请日：1988-02-29

Applicant: Osamu Isozaki ,  Noboru Nakai

Inventor： Osamu Isozaki ,  Noboru Nakai

IPC: C08G59/32 ,  C08F8/42 ,  C08G59/20 ,  C08G59/40 ,  C08G59/70 ,  C08J7/04 ,  C08L63/00 ,  C08L83/04 ,  C08L83/07 ,  C09D4/02 ,  C09D155/00 ,  C09D183/07

CPC classification number: C08F8/42 ,  C09D155/005

Abstract: This invention provides a resin composition curable at a low temperature and characterized in that the composition comprises:(a) a copolymer prepared from a polysiloxane macromonomer and an epoxy-containing monomer both containing ethylenically unsaturated groups,the polysiloxane macromonomer being prepared by reacting 70 to 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 is an aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl, and R.sub.2, R.sub.3 and R.sub.4 are each alkoxyl having 1 to 4 carbon atoms or hydroxyl with 30 to 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 is a hydrogen atom or methyl, R.sub.6, R.sub.7 and R.sub.8 are each hydroxyl, alkoxyl having 1 to 4 carbon atoms or an aliphatic hydrocarbon group having 1 to 8 carbon atoms, at least one of R.sub.6, R.sub.7 and R.sub.8 being hydroxyl or alkoxyl, and n is an integer of 1 to 6, the polysiloxane macromonomer having per molecule at least two functional groups selected from hydroxyl and the alkoxyl and being 400 to 100000 in number average molecular weight,the epoxy-containing monomer having at its terminal end the group ##STR3## wherein (Z) forms an alicyclic group with the C--C bond, and (b) a 6-coordinate organoaluminum chelate compound and/or an 8-coordinate organozirconium chelate compound.

Abstract translation: 本发明提供了一种在低温下可固化的树脂组合物，其特征在于该组合物包括：（a）由聚硅氧烷大分子单体和含有烯键式不饱和基团的含环氧基的单体制备的共聚物，所述聚硅氧烷大分子单体通过使70与 99.999摩尔％的由式（I）表示的化合物（A），其中R1是具有1-8个碳原子的脂族烃基或苯基，R2，R3和R4分别是具有1至4个碳原子的烷氧基 或具有30至0.001摩尔％的由式（II）表示的化合物（B）的羟基，其中R 5是氢原子或甲基，R 6，R 7和R 8各自是羟基，具有1至4个碳原子的烷氧基或 具有1至8个碳原子的脂族烃基，R 6，R 7和R 8中的至少一个为羟基或烷氧基，n为1至6的整数，每分子至少两个选自羟基的官能团的聚硅氧烷大分子单体 1，烷氧基，数均分子量为400〜100000，含环氧基的单体末端为基团，其中（Z）与CC键形成脂环族基团，（b）6- 配位有机铝螯合物和/或8-配位有机锆螯合物。

公开(公告)号：US4514471A

公开(公告)日：1985-04-30

申请号：US594434

申请日：1984-03-29

Applicant: Kenji Sugimoto ,  Osamu Isozaki

Inventor： Kenji Sugimoto ,  Osamu Isozaki

IPC: B28B11/04 ,  C04B28/14 ,  C04B41/48 ,  C04B41/63 ,  B05D3/06

CPC classification number: C04B41/009 ,  C04B28/146 ,  C04B41/48 ,  C04B41/63

Abstract: Disclosed is a process for the preparation of an electron beam curing gypsum panel which comprises subjecting a hydrated gypsum slurry containing or free of an additive, fibrous material, fine aggregates, water, etc. to defoaming, setting and drying to form a gypsum substrate, coating an electron beam curing resin composition on the surface of the gypsum substrate to form a coated film, and irradiating accelerated electron beam on the coated film thereby to be cured.

Abstract translation: 公开了一种制备电子束固化石膏板的方法，该方法包括使含有或不含添加剂，纤维材料，细骨料，水等的水合石膏浆料脱泡，固化和干燥以形成石膏基材， 在石膏基材的表面上涂布电子束固化树脂组合物以形成涂膜，并将加速的电子束照射在涂膜上，从而进行固化。

公开(公告)号：US4033920A

公开(公告)日：1977-07-05

申请号：US585770

申请日：1975-06-10

Applicant: Osamu Isozaki ,  Tadashi Watanabe ,  Masahiro Sakamoto

Inventor： Osamu Isozaki ,  Tadashi Watanabe ,  Masahiro Sakamoto

IPC: C08F8/14 ,  C08F290/12 ,  C08L33/02

CPC classification number: C08F290/12 ,  C08F8/14 ,  C08F2810/30

Abstract: A process for producing an aqueous emulsion of unsaturated resin suitable for radiation curing coating compositions comprises the steps of: synthesizing polyvinyl resin having an acid value of 50 to 230 by solution polymerization, adding a monomer having both epoxy group and reactive unsaturated group to said polyvinyl resin, if necessary further mixing a monomer of above 190.degree. C in boiling point having reactive unsaturated group(s) to the above adduct, removing solvent under reduced pressure, neutralizing residual acid groups with base and dispersing the neutralized product into water.

Abstract translation: 适用于辐射固化涂料组合物的不饱和树脂水乳液的制备方法包括以下步骤：通过溶液聚合合成酸值为50至230的聚乙烯基树脂，将具有环氧基和反应性不饱和基团的单体加入到所述聚乙烯 树脂，如果需要，将具有反应性不饱和基团的沸点高于190℃的单体与上述加合物进一步混合，减压除去溶剂，用碱中和残留的酸基，并将中和产物分散在水中。

公开(公告)号：US3974303A

公开(公告)日：1976-08-10

申请号：US490753

申请日：1974-07-22

Applicant: Seigo Iwase ,  Osamu Isozaki ,  Naozumi Iwasawa ,  Tadashi Watanabe

Inventor： Seigo Iwase ,  Osamu Isozaki ,  Naozumi Iwasawa ,  Tadashi Watanabe

IPC: C09D5/00 ,  B05D3/06 ,  C08G18/32 ,  C08G18/67 ,  C08J3/28 ,  C09D4/00 ,  C09D5/03 ,  C09D175/16 ,  B05B5/02

CPC classification number: C08G18/3206 ,  B05D3/067 ,  B05D3/068 ,  C08G18/672 ,  C08J3/28 ,  C09D175/16 ,  B05D2401/32 ,  C08G2150/20

Abstract: A method for forming coating films which can provide coating films having good surface appearance and being excellent in such properties as impact resistance, adhesion to the substrate article, flexibility and chemical resistance, said method comprising coating a powdery composition of a thermoplastic resin having 0.5 to 3.5 polymerizable unsaturated bonds per 1000 of the molecular weight on an article to be coated, heat-melting the powdery resinous composition, and curing the molten film under application of ionizing radiation or ultraviolet radiation.

Abstract translation: 一种形成涂膜的方法，其可以提供具有良好的表面外观并且具有优异的耐冲击性，对基材制品的粘附性，柔韧性和耐化学性的性能的涂膜，所述方法包括将具有0.5的热塑性树脂的粉末组合物涂覆至 3.5可聚合的不饱和键，每1000个待涂覆的物品上的分子量，对粉末状树脂组合物进行加热熔融，并在施加电离辐射或紫外线辐射下固化熔融膜。

公开(公告)号：US08575383B2

公开(公告)日：2013-11-05

申请号：US13122789

申请日：2009-09-09

Applicant: Akinori Nagai ,  Yoshiaki Chino ,  Masami Kobata ,  Osamu Isozaki

Inventor： Akinori Nagai ,  Yoshiaki Chino ,  Masami Kobata ,  Osamu Isozaki

IPC: C07F7/10 ,  C08F2/46

CPC classification number: C09D143/04 ,  C07F7/21 ,  C08F230/08 ,  C08G77/04 ,  C08G77/20 ,  C08G77/26

Abstract: To provide a composition comprising a silsesquioxane compound that is capable of producing a coating film with excellent heat resistance and scratch resistance, and that has excellent compatibility with general polymerizable unsaturated compounds as well as polymerizable unsaturated compounds with high polarity.A silsesquioxane compound comprising organic groups each directly attached to a silicon atom of the compound, at least one of the organic groups being an organic group having one or more urethane bonds and one (meth)acryloyloxy group.

Abstract translation: 本发明提供一种能够制造耐热性，耐划伤性优异的涂膜的倍半硅氧烷化合物，与一般的聚合性不饱和化合物以及具有高极性的聚合性不饱和化合物的相容性优异的组合物。 包含与化合物的硅原子直接相连的有机基团的倍半硅氧烷化合物，所述有机基团中的至少一个为具有1个以上的氨基甲酸酯键和1个（甲基）丙烯酰氧基的有机基团。

公开(公告)号：US06902674B2

公开(公告)日：2005-06-07

申请号：US10602591

申请日：2003-06-25

Applicant: Tadamasa Hattori ,  Masahide Kawaraya ,  Osamu Isozaki ,  Naonori Miyata

Inventor： Tadamasa Hattori ,  Masahide Kawaraya ,  Osamu Isozaki ,  Naonori Miyata

IPC: C02F1/28 ,  C02F1/30 ,  C02F1/32 ,  C02F1/78 ,  C02F3/00 ,  C02F3/02 ,  C02F3/28 ,  C02F9/00

CPC classification number: C02F9/00 ,  C02F1/283 ,  C02F1/302 ,  C02F1/32 ,  C02F1/78 ,  C02F3/00 ,  C02F3/02 ,  C02F3/286 ,  C02F2103/14 ,  Y02W10/15

Abstract: Provided is an efficient treating method for coating material waste water which meets a change in a concentration of contaminants contained in waste water and a change in a treating amount by converting scarcely decomposable substances contained in the coating material waste water to easily decomposable substances. The coating material waste water is irradiated with a micro wave to decompose organic substances contained in the above waste water. Further, the coating material waste water before irradiated with a micro wave may be subjected, if necessary, to coagulation treatment by a flocculant or electrolytic treatment. After irradiating with a micro wave to decompose scarcely decomposable substances contained in the waste water to easily decomposable substances, the resulting treated water is preferably fed to a biological reaction bath and subjected to biological treatment under aerobic or anaerobic atmosphere.

Abstract translation: 提供了通过将包含在涂料废水中的几乎不分解的物质转化成易分解物质，能够满足废水中所含污染物浓度变化和处理量变化的涂料废水的有效处理方法。 用微波照射涂料废水，分解上述废水中含有的有机物质。 此外，如果需要，可以通过絮凝剂或电解处理对经过微波照射的涂料废水进行凝固处理。 在微波照射之后，将废水中含有的几乎不分解的物质分解成容易分解的物质，所得到的处理水优选进料到生物反应槽中，并在有氧或无氧气氛下进行生物处理。

公开(公告)号：US06736890B2

公开(公告)日：2004-05-18

申请号：US10312571

申请日：2003-01-14

Applicant: Yasuhiko Haruta ,  Jun Akui ,  Osamu Isozaki

Inventor： Yasuhiko Haruta ,  Jun Akui ,  Osamu Isozaki

IPC: C01G23053

CPC classification number: C23C22/34 ,  C09D1/00 ,  C23C18/1216 ,  C23C18/1241 ,  C23C22/83 ,  C23C30/00

Abstract: The present invention provides: a coating composition for forming a titanium oxide film, comprising (A) a titanium-containing aqueous liquid obtained by mixing at least one titanium compound selected from the group consisting of hydrolyzable titanium compounds, low condensates of hydrolyzable titanium compounds, titanium hydroxide and low condensates of titanium hydroxide with aqueous hydrogen peroxide, and (B) at least one halide selected from the group consisting of titanium halides, titanium halide salts, zirconium halides, zirconium halide salts, silicon halides and silicon halide salts; a process for forming a titanium oxide film, comprising applying the coating composition to a metal substrate and drying the resulting coat; and an undercoating material for metal substrates and a post-treating agent for phosphate undercoats on metal substrates, the material and agent being the above coating composition.

Abstract translation: 本发明提供：一种用于形成氧化钛膜的涂料组合物，其包含（A）通过混合至少一种钛化合物而获得的含钛水性液体，所述钛化合物选自可水解的钛化合物，可水解的钛化合物的低缩合物， 氢氧化钛和氢氧化钛与过氧化氢水溶液的低冷凝物，和（B）至少一种选自卤化钛，卤化钛盐，卤化锆，卤化锆盐，卤化硅和卤化硅盐的卤化物; 一种形成氧化钛膜的方法，包括将所述涂料组合物涂覆在金属基材上并干燥所得涂层; 以及用于金属基材的底漆材料和金属基材上的磷酸盐底漆的后处理剂，作为上述涂料组合物的材料和试剂。

公开(公告)号：US5641574A

公开(公告)日：1997-06-24

申请号：US553399

申请日：1995-11-21

Applicant: Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John David Nordstrom

Inventor： Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John David Nordstrom

IPC: B05D1/36 ,  B05D7/00 ,  B05D7/24 ,  C08G59/42 ,  C09D157/00 ,  C09D163/00 ,  C09D167/00 ,  C09D167/02 ,  C09D175/00 ,  C09D175/04 ,  C09D201/00

CPC classification number: B05D7/532 ,  C08G59/42 ,  Y10T428/31511

Abstract: A process for forming an overcoat by the two-coat one-bake method wherein a base coat composition and a clear coat composition are applied to a substrate ##STR1## wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is an aqueous coating composition consisting primarily of: (I) an aqueous dispersion or solution of a polymer containing a crosslinkable functional group, (II) a crosslinking agent, (III) a coloring pigment, and (IV) water, the clear coat composition being a coating composition comprising: (A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecule, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof, (B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by formula (1) wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500, and (C) a curing catalyst.

Abstract translation: PCT No.PCT / JP93 / 00678 Sec。 371日期：1995年11月21日 102（e）1995年11月21日日期PCT提交1993年5月24日PCT公布。 第WO94 / 27741号公报 日期1994年12月8日一种通过双层单烘烤法形成外涂层的方法，其中将底涂层组合物和透明涂层组合物施加到基底上（1）湿润湿润，然后在 该方法的特征在于底涂层组合物是主要由以下组成的水性涂料组合物：（I）含有可交联官能团的聚合物的水性分散体或溶液，（II）交联剂，（ III）着色颜料和（IV）水，所述透明涂料组合物为涂料组合物，其包含：（A）至少一种选自以下的树脂：（i）具有至少一个环氧基的树脂和至少一种 （ii）分子中具有至少两个环氧基的树脂（ii-1）和（ii-2）分子中具有至少两个羟基的树脂的树脂混合物，（iii）分子中具有至少两个羟基的树脂， 分子中具有至少两个环氧基的树脂，和（iv）任何混合物 （B）交联剂，其包含具有至少两个非环状酸酐基团并由式（1）表示的化合物，其中R是具有2至50个碳原子的一价烃基，R'是具有2至 50个碳原子，含有或不含醚键的烃基R和R'，氨基甲酸酯键或酯键，n为1〜500的整数，（C）固化催化剂。

公开(公告)号：US5609960A

公开(公告)日：1997-03-11

申请号：US553398

申请日：1995-11-21

Applicant: Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John D. Nordstrom

Inventor： Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John D. Nordstrom

IPC: B05D1/36 ,  B05D3/02 ,  B05D5/00 ,  B05D7/00 ,  B05D7/24 ,  B05D7/26 ,  C08G59/42 ,  C08L33/06 ,  C08L73/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D161/20 ,  C09D163/00 ,  C09D167/00 ,  C09D167/02 ,  C09D201/02 ,  C09D201/06

CPC classification number: B05D7/532 ,  C08G59/42 ,  C09D133/068 ,  C09D163/00 ,  C08L33/066 ,  C08L73/02 ,  Y10T428/31511

Abstract: A process for forming an overcoat by the two-coat one-bake method wherein a basecoat composition and a clear coat composition are applied to a substrate wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is a coating composition consisting primarily of a hydroxyl-containing resin, an amine resin, a pigment and an organic solvent, the clear coat composition being a coating composition comprising:(A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecue, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof,(B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500 and (C) a curing catalyst.

Abstract translation: PCT No.PCT / JP93 / 00669 Sec。 371日期：1995年11月21日 102（e）日期1995年11月21日PCT提交1993年5月21日PCT公布。 公开号WO94 / 27740 日期1994年12月8日一种通过双层单烘烤法形成外涂层的方法，其中将底涂层组合物和透明涂层组合物施加到湿润基板上，然后通过加热同时固化， 方法的特征在于，底涂层组合物是主要由含羟基树脂，胺树脂，颜料和有机溶剂组成的涂料组合物，透明涂料组合物是涂料组合物，其包含：（A）至少一种树脂 选自（i）在分子中具有至少一个环氧基和至少一个羟基的树脂，（ii）（ii-1）在分子中具有至少两个环氧基的树脂的树脂混合物 和（ii-2）在分子中具有至少两个羟基的树脂，（iii）分子中具有至少两个环氧基的树脂，和（iv）其任何混合物，（B）包含化合物 具有至少两个非环酸酐基团a d由下式表示：其中R是具有2至50个碳原子的一价烃基，R'是具有2至50个碳原子的二价烃基，烃基R和R'含有或不含有醚键 氨基甲酸酯键或酯键，n为1〜500的整数，（C）固化催化剂。

公开(公告)号：US5525673A

公开(公告)日：1996-06-11

申请号：US277429

申请日：1994-07-18

Applicant: Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

Inventor： Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

IPC: C08L63/00 ,  C09D201/04 ,  C08F4/52 ,  C08F4/76 ,  C08F24/00 ,  C08F30/08

CPC classification number: C08L63/00 ,  C09D201/04

Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.

Abstract translation: 公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。