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公开(公告)号：US08148314B2
公开(公告)日：2012-04-03
申请号：US13213642
申请日：2011-08-19
CPC分类号： C12N9/18 , A61L2/183 , A61L2/186 , A61L2/22 , A61L2202/24 , C11D3/06 , C11D3/10 , C11D3/201 , C11D3/2017 , C11D3/2044 , C11D3/2048 , C11D3/2068 , C11D3/2079 , C11D3/2082 , C11D3/2086 , C11D3/2093 , C11D3/221 , C11D3/226 , C11D3/32 , C11D3/361 , C11D3/38636 , C11D3/3947 , C11D17/041 , C12P7/40 , C12Y301/01001 , Y02E50/16
摘要： Disclosed herein is a method for stabilization of the perhydrolase activity of the CE-7 esterase in a formulation with a carboxylic acid ester that employs the addition of a buffering agent, substantially undissolved, to the mixture of the CE-7 esterase and the carboxylic acid ester. Further, disinfectant and laundry care formulations comprising the peracids produced by the processes described herein are provided.
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公开(公告)号：US20110312053A1
公开(公告)日：2011-12-22
申请号：US13162631
申请日：2011-06-17
CPC分类号： C12P7/16 , A23K10/38 , B01D3/002 , B01D11/0492 , B01D21/26 , B01D21/262 , C07C29/86 , C11B1/025 , C11B13/00 , C12F3/10 , C12M1/00 , C12M21/12 , C12M45/04 , C12M45/09 , C12N1/14 , C12N15/00 , C12P7/18 , C12P7/6418 , Y02E50/10 , Y02E50/16 , Y02E50/17 , Y02W30/74
摘要： Fatty acids derived from biomass at a step in a fermentation process can be added to a fermentation medium comprising a recombinant microorganism that produces a product alcohol. At least one of growth rate and fermentable carbon consumption of the microorganism is greater in the presence of the fatty acids than the growth rate and the fermentable carbon consumption of the microorganism in the absence of the fatty acids. The addition of the fatty acids can increase glucose consumption, and can improve microorganism biomass production (cell growth/density) and growth rate, thereby reducing production time and increasing productivity of the fermentation process.
摘要翻译： 在发酵过程中的步骤中衍生自生物质的脂肪酸可以加入到包含产生产物醇的重组微生物的发酵培养基中。 在存在脂肪酸的情况下，微生物的生长速率和可发酵碳消耗量中的至少一种比在不存在脂肪酸时微生物的生长速率和可发酵碳消耗量更大。 脂肪酸的添加可以增加葡萄糖消耗，并且可以改善微生物生物量的生产（细胞生长/密度）和生长速率，从而减少生产时间并提高发酵过程的生产率。
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公开(公告)号：US20110236335A1
公开(公告)日：2011-09-29
申请号：US13070123
申请日：2011-03-23
IPC分类号： C12P7/40 , C12N15/63 , C12N1/00 , C12N9/18 , C07H21/04 , C12M1/40 , A01N37/16 , D21C9/16 , A61L2/16 , D06L3/02 , A01P1/00
CPC分类号： C12N9/18 , C11D3/38636 , C11D3/3945 , C12P7/40 , D21C5/005 , D21C9/1036
摘要： An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in specific activity. The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.
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公开(公告)号：US20110150857A1
公开(公告)日：2011-06-23
申请号：US13036763
申请日：2011-02-28
IPC分类号： A01N63/02 , A01N37/16 , A01P1/00 , C11D7/54 , C11D7/60 , C12N9/18 , C12P7/40 , C12M1/00 , D21H21/32 , C09K3/00
摘要： An acetyl xylan esterase variant having perhydrolytic activity is provided for producing peroxycarboxylic acids from carboxylic acid esters and a source of peroxygen. More specifically, a Thermotoga maritima acetyl xylan esterase gene was modified using error-prone PCR and site-directed mutagenesis to create an enzyme catalyst characterized by an increase in the ratio of peracetic acid formation to peracetic acid hydrolysis specific activities (PAAF/PAAH ratio). The variant acetyl xylan esterase may be used to produce peroxycarboxylic acids suitable for use in a variety of applications such as cleaning, disinfecting, sanitizing, bleaching, wood pulp processing, and paper pulp processing applications.
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公开(公告)号：US20090036716A1
公开(公告)日：2009-02-05
申请号：US11818353
申请日：2007-06-13
申请人： Michael B. D'Amore , Leo Ernest Manzer , Edward S. Miller, JR. , Robert Dicosimo , Jeffrey P. Knapp
发明人： Michael B. D'Amore , Leo Ernest Manzer , Edward S. Miller, JR. , Robert Dicosimo , Jeffrey P. Knapp
IPC分类号： C07C41/01
摘要： The present invention relates to a catalytic process for making dibutyl ethers using a reactant comprising 1-butanol and water. The dibutyl ethers so produced are useful in transportation fuels.
摘要翻译： 本发明涉及使用包含1-丁醇和水的反应物制备二丁醚的催化方法。 如此生产的二丁醚可用于运输燃料。
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36.发明申请公开(公告)号：US20080032371A1
公开(公告)日：2008-02-07
申请号：US11485575
申请日：2006-07-12
申请人： Robert Dicosimo , Sharon L. Haynie , Lixuan Lisa Huang , Fateme Sima Sariaslani , Robert J. Trotman , Tina K. Van Dyk
发明人： Robert Dicosimo , Sharon L. Haynie , Lixuan Lisa Huang , Fateme Sima Sariaslani , Robert J. Trotman , Tina K. Van Dyk
摘要： TAL cell biocatalyst was immobilized in alginate cross-linked beads using low concentrations of glutaraldehyde. The biocatalyst beads have highly stable TAL activity and mechanical strength such that they withstand prolonged recycling in production of pHCA.
摘要翻译： 使用低浓度戊二醛将TAL细胞生物催化剂固定在藻酸盐交联珠粒中。 生物催化剂珠具有高度稳定的TAL活性和机械强度，使得它们在pHCA的生产中经受长时间的再循环。
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公开(公告)号：US20070004017A1
公开(公告)日：2007-01-04
申请号：US11516408
申请日：2006-09-05
申请人： Michael Bramucci , Robert Dicosimo , Robert Fallon , John Gavagan , Frank Herkes , Lech Wilczek
发明人： Michael Bramucci , Robert Dicosimo , Robert Fallon , John Gavagan , Frank Herkes , Lech Wilczek
摘要： This invention relates to a process for the preparation of a 3-hydroxycarboxylic acid from a 3-hydroxynitrile. More specifically, 3-hydroxyvaleronitrile is converted to 3-hydroxyvaleric acid in high yield at up to 100% conversion, using as an enzyme catalyst 1) nitrile hydratase activity and amidase activity or 2) nitrilase activity of a microbial cell. 3-Hydroxyvaleric acid is used as a substitute for ε-caprolactone in the preparation of highly branched copolyester.
摘要翻译： 本发明涉及一种由3-羟基腈制备3-羟基羧酸的方法。 更具体地，使用酶催化剂1）腈水合酶活性和酰胺酶活性或2）微生物细胞的腈水解酶活性，将3-羟基戊腈以高产率转化为3-羟基戊酸。 3-羟基戊酸用于制备高支化共聚酯中的ε-己内酯的替代物。
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公开(公告)号：US07091011B2
公开(公告)日：2006-08-15
申请号：US10378202
申请日：2003-03-03
申请人： Michael G. Bramucci , Robert Dicosimo , Robert Fallon , John E. Gavagan , Frank Herkes , Lech Wilczek
发明人： Michael G. Bramucci , Robert Dicosimo , Robert Fallon , John E. Gavagan , Frank Herkes , Lech Wilczek
摘要： This invention relates to a process for the preparation of a 3-hydroxycarboxylic acid from a 3-hydroxynitrile. More specifically, 3-hydroxyvaleronitrile is converted to 3-hydroxyvaleric acid in high yield at up to 100% conversion, using as an enzyme catalyst 1) nitrile hydratase activity and amidase activity or 2) nitrilase activity of a microbial cell. 3-Hydroxyvaleric acid is used as a substitute for ε-caprolactone in the preparation of highly branched copolyester.
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公开(公告)号：US06562603B2
公开(公告)日：2003-05-13
申请号：US09921260
申请日：2001-08-02
申请人： Michael G. Bramucci , Robert Dicosimo , Robert Fallon , John E. Gavagan , Frank Herkes , Lech Wilczek
发明人： Michael G. Bramucci , Robert Dicosimo , Robert Fallon , John E. Gavagan , Frank Herkes , Lech Wilczek
IPC分类号： C12P742
摘要： This invention relates to a process for the preparation of a 3-hydroxycarboxylic acid from a 3-hydroxynitrile. More specifically, 3-hydroxyvaleronitrile is converted to 3-hydroxyvaleric acid in high yield at up to 100% conversion, using as an enzyme catalyst 1) nitrile hydratase activity and amidase activity or 2) nitrilase activity of a microbial cell. 3-Hydroxyvaleric acid is used as a substitute for &egr;-caprolactone in the preparation of highly branched copolyester.
摘要翻译： 本发明涉及一种由3-羟基腈制备3-羟基羧酸的方法。 更具体地，使用酶催化剂1）腈水合酶活性和酰胺酶活性或2）微生物细胞的腈水解酶活性，将3-羟基戊腈以高产率转化为3-羟基戊酸。 在制备高支化共聚酯时，使用3-羟基戊酸作为ε-己内酯的替代物。
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40.发明授权公开(公告)号：US06455730B1
公开(公告)日：2002-09-24
申请号：US09632419
申请日：2000-08-04
IPC分类号： C07C5108
摘要： This invention relates to a process for preparing dicarboxylic acid monoesters from cyanocarboxylic acid esters. More particularly, using the nitrilase from Acidovorax facilis 72W (ATCC 55745) in various forms as an enzyme catalyst, an aliphatic or aromatic cyanocarboxylic acid ester is converted to the corresponding dicarboxylic acid monoester with high chemoselectivity at 100% conversion. An embodiment of the invention also provides a process for obtaining high chemoselectively and high regioselectivity.
摘要翻译： 本发明涉及由氰基羧酸酯制备二羧酸单酯的方法。 更具体地，使用来自Acidovorax facilis 72W（ATCC 55745）的腈水解酶以各种形式作为酶催化剂，将脂族或芳族氰基羧酸酯在100％转化率下转化为具有高化学选择性的相应的二羧酸单酯。 本发明的实施方案还提供了获得高化学选择性和高区域选择性的方法。
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