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    Thermoplastic resin composition
    32.
    发明授权
    Thermoplastic resin composition 失效
    热塑性树脂组合物

    公开(公告)号：US5767198A

    公开(公告)日：1998-06-16

    申请号：US564243

    申请日：1995-12-20

    申请人： Tetsuo Shimizu ,  Takayuki Araki ,  Takafumi Yamato ,  Yoshihisa Yamamoto

    发明人： Tetsuo Shimizu ,  Takayuki Araki ,  Takafumi Yamato ,  Yoshihisa Yamamoto

    IPC分类号： C08L27/12 ,  C08L27/18 ,  C08L67/00 ,  C08L67/02 ,  C08L67/04 ,  C08L67/03

    CPC分类号： C08L27/12 ,  C08L27/18 ,  C08L67/00 ,  C08L67/02 ,  C08L67/04

    摘要： To provide a thermoplastic resin composition which comprises a fluorine-containing polymer having a molecular weight of 5.times.10.sup.2 to 5.times.10.sup.5 and 2.times.10.sup.2 to 1.times.10.sup.5 methylol groups per 1.times.10.sup.6 carbon atoms at its molecular chain ends and a liquid crystal polyester or in addition a perfluoro type resin having less than 2.times.10.sup.2 methylol groups mentioned above, and has improved shrinkage from mold dimensions and dimensional stability represented by a coefficient of linear expansion with maintaining excellent characteristics of the fluorine-containing resin, such as thermal resistance, chemical resistance, weather resistance, surface properties (non-stickiness, excellent friction property), antisoil property and dielectric property.

    摘要翻译： PCT No.PCT / JP95 / 00833 Sec。 371 1995年12月20日第 102（e）1995年12月20日日期PCT提交1995年4月26日PCT公布。 WO95 / 29956 PCT公开号 日期：1995年11月9日提供一种热塑性树脂组合物，其包含分子链末端分子量为5×10 2〜5×10 5的含氟聚合物和1×10 6个碳原子的2×102〜1×10 5个羟甲基，以及液晶聚酯， 具有上述小于2×102羟甲基的全氟型树脂，并且通过保持含氟树脂的优异特性，例如耐热性，耐化学性，耐候性，由模具尺寸和线性膨胀系数表示的尺寸稳定性提高了收缩率 ，表面性（不粘性，优异的摩擦性），防垢性和介电性。

    Method of forming thin film
    35.
    发明授权
    Method of forming thin film 有权
    薄膜形成方法

    公开(公告)号：US08450439B2

    公开(公告)日：2013-05-28

    申请号：US12641183

    申请日：2009-12-17

    申请人： Takayuki Araki ,  Tetsuhiro Kodani

    发明人： Takayuki Araki ,  Tetsuhiro Kodani

    IPC分类号： C08F14/18

    CPC分类号： C08F114/22 ,  C07C21/18 ,  Y10T428/3154 ,  Y10T428/31544

    摘要： There is provided a method of forming a thin film of vinylidene fluoride homopolymer having crystal form I which is applicable to various substrates in relatively easy way (coating conditions, application method, etc.), a process for preparing a vinylidene fluoride homopolymer having crystal form I efficiently at high purity, and novel vinylidene fluoride homopolymers which can give a thin film being excellent in ferroelectricity. The method of forming a thin film of vinylidene fluoride homopolymer comprises (i) a step for preparing a green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component by subjecting vinylidene fluoride to radical polymerization in the presence of a bromine compound or iodine compound having 1 to 20 carbon atoms which contains at least one moiety represented by —CRf1Rf2X1, wherein X1. is iodine atom or bromine atom; Rf1. and Rf2. are the same or different and each is selected from fluorine atom or perfluoroalkyl groups having 1 to 5 carbon atoms and (ii) a step for forming a thin film on a substrate surface by using vinylidene fluoride homopolymer which comprises crystal form I alone or as main component and is obtained from the green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component.

    摘要翻译： 提供一种以相对容易的方式（涂布条件，涂布方法等）形成可以适用于各种基材的结晶形式I的偏二氟乙烯均聚物的薄膜的方法，制备具有结晶形式的偏二氟乙烯均聚物 我高效率地得到高纯度的新型偏二氟乙烯均聚物，可以得到铁电性优异的薄膜。 形成偏氟乙烯均聚物薄膜的方法包括（i）通过在溴化合物的存在下使偏二氟乙烯进行自由基聚合，制备单晶或单体晶形的偏二氟乙烯均聚物的生粉产物的步骤 或含有至少一个由-CR f 1 R f 2 X 1表示的部分的具有1至20个碳原子的碘化合物，其中X1。 是碘原子或溴原子; Rf1。 和Rf2。 相同或不同，分别选自具有1至5个碳原子的氟原子或全氟烷基，和（ii）通过使用单晶形式的主要含氟乙烯均聚物或作为主要成分的偏氟乙烯均聚物在基材表面上形成薄膜的步骤 从单独的晶形I或作为主要成分的偏氟乙烯均聚物的绿色粉末产品获得。

    WEATHERABLE SHEET FOR SOLAR CELL MODULE, PRODUCT OBTAINED USING THE SHEET, AND PROCESS FOR PRODUCING THE WEATHERABLE SHEET FOR SOLAR CELL MODULE
    36.
    发明申请
    WEATHERABLE SHEET FOR SOLAR CELL MODULE, PRODUCT OBTAINED USING THE SHEET, AND PROCESS FOR PRODUCING THE WEATHERABLE SHEET FOR SOLAR CELL MODULE 有权
    太阳能电池模块的天气表，使用该产品的产品以及用于生产太阳能电池模块的耐候片的工艺

    公开(公告)号：US20120298196A1

    公开(公告)日：2012-11-29

    申请号：US13522098

    申请日：2011-01-13

    申请人： Hideto Nakagawa ,  Kenji Goboh ,  Kazuko Aoki ,  Takayuki Araki ,  Hiroshi Torii ,  Yoshihisa Yamamoto ,  Eiji Fujita

    发明人： Hideto Nakagawa ,  Kenji Goboh ,  Kazuko Aoki ,  Takayuki Araki ,  Hiroshi Torii ,  Yoshihisa Yamamoto ,  Eiji Fujita

    IPC分类号： B32B27/26 ,  B32B27/20 ,  C09D127/18 ,  H01L31/0216 ,  B05D3/02 ,  B32B27/00 ,  H01L31/0203

    CPC分类号： C08J7/047 ,  B32B17/10788 ,  C08J2367/02 ,  C08J2427/12 ,  H01L31/049 ,  Y02E10/50 ,  Y10T428/3154 ,  Y10T428/31544

    摘要： The present invention provides a weather-resistant sheet for a solar cell module, which has better adhesion to a water impermeable sheet, better blocking resistance against the water impermeable sheet, and better adhesion to EVA that is a sealant; a weather-resistant sheet for a solar cell module in which a cured coating film layer thereof can suppress UV transmission significantly; a product including the sheet; and a process for producing the sheet. The weather-resistant sheet for a solar cell module includes, on a water impermeable sheet, a cured coating film layer made of a crosslinked product of a coating composition that includes a hydroxyl group-containing fluoropolymer, wherein in a pressure-resistance test performed when a crosslinking degree of the cured coating film layer is 80 to 99%, the cured coating film layer and the water impermeable sheet without a cured coating film layer formed thereon are not adhered to each other after a load has been applied to the cured coating film layer and the water impermeable sheet being stacked.

    摘要翻译： 本发明提供一种太阳能电池组件的耐候性片材，其对不透水性片材具有更好的粘附性，对防水性片材具有更好的抗粘连性，以及对作为密封剂的EVA的更好的粘合性; 用于太阳能电池模块的耐候性片，其中固化的涂膜层可以显着地抑制UV透射; 包括片材的产品; 以及片材的制造方法。 用于太阳能电池组件的耐候性片材包括在不透水片材上的包含含羟基含氟聚合物的涂料组合物的交联产物的固化涂膜层，其中，在 固化涂膜层的交联度为80-99％，固化涂膜层和其上形成有固化涂膜层的不透水片在施加到固化涂膜上之后不彼此粘合 层和不透水片被堆叠。

    Curable fluorine-containing polymer, curable resin composition prepared from same and antireflection film
    38.
    发明授权
    Curable fluorine-containing polymer, curable resin composition prepared from same and antireflection film 有权
    可固化的含氟聚合物，由其制备的可固化树脂组合物和抗反射膜

    公开(公告)号：US07670640B2

    公开(公告)日：2010-03-02

    申请号：US11226355

    申请日：2005-09-15

    申请人： Takayuki Araki ,  Mihoko Ohashi ,  Yoshito Tanaka ,  Tetsuo Shimizu

    发明人： Takayuki Araki ,  Mihoko Ohashi ,  Yoshito Tanaka ,  Tetsuo Shimizu

    IPC分类号： B05D5/06

    CPC分类号： C09D127/12 ,  C08F8/00 ,  C08F8/14 ,  C08F16/32 ,  C08F214/18 ,  C08F290/04 ,  Y10T428/3154 ,  C08F14/18

    摘要： There are provided a curable fluorine-containing polymer which can realize a high hardness by photo-curing while maintaining a low refractive index, an antireflection film possessing improved scratch resistance and abrasion resistance while maintaining a reflection reducing effect, and an antireflection-treated article provided with such an antireflection film. The curable fluorine-containing polymer has a number average molecular weight of from 500 to 1,000,000 and is represented by the formula (1): AM  (1) in which the structural unit M is a structural unit derived from a fluorine-containing ethylenic monomer and represented by the formula (M): wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, CH3 or CF3; X4 and X5 are the same or different and each is H, F or CF3; Rf is an organic group in which 1 to 3 of Y1 (Y1 is a monovalent organic group having 2 to 10 carbon atoms and an ethylenic carbon-carbon double bond at its end) are bonded to a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having 2 to 100 carbon atoms and ether bond; a is 0 or an integer of from 1 to 3; b and c are the same or different and each is 0 or 1, the structural unit A is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M), and the structural unit M and the structural unit A are contained in amounts of from 0.1 to 100% by mole and from 0 to 99.9% by mole, respectively.

    摘要翻译： 提供了一种可固化的含氟聚合物，其可以通过光固化同时保持低折射率实现高硬度，在保持反射降低效果的同时具有改善的耐擦伤性和耐磨性的抗反射膜，以及提供的抗反射处理制品 具有这样的抗反射膜。 可固化含氟聚合物的数均分子量为500〜1,000,000，由式（1）表示：AM（1）其中，结构单元M是来自含氟乙烯性单体的结构单元， 由式（M）表示：其中X1和X2相同或不同，各自为H或F; X3是H，F，CH3或CF3; X4和X5相同或不同，分别为H，F或CF 3; Rf为1〜3的Y1（Y1为碳原子数为2〜10的一价有机基团，末端为烯属碳 - 碳双键）的1〜3的有机基团与1〜40的含氟烷基 碳原子或碳原子数2〜100的含氟烷基和醚键; a为0或1〜3的整数; b和c相同或不同，分别为0或1，结构单元A是衍生自与式（M）表示的含氟乙烯性单体共聚的单体的结构单元，结构单元M和 结构单元A的含量分别为0.1至100摩尔％和0至99.9摩尔％。

    Heat-resistant material and coating material for OA equipments having flexibility
    39.
    再颁专利
    Heat-resistant material and coating material for OA equipments having flexibility 失效
    具有柔性的OA设备的耐热材料和涂料

    公开(公告)号：USRE41110E1

    公开(公告)日：2010-02-09

    申请号：US11512391

    申请日：2006-08-30

    申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

    发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

    IPC分类号： B32B27/00

    CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

    摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

    摘要翻译： 可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。