利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

86 条记录 (耗时 0.024 秒)

    Catalytic dewaxing of light and heavy oils in dual parallel reactors
    33.
    发明授权
    Catalytic dewaxing of light and heavy oils in dual parallel reactors 失效
    双重并联反应器中轻油和重油的催化脱蜡

    公开(公告)号：US4605488A

    公开(公告)日：1986-08-12

    申请号：US733339

    申请日：1985-05-13

    申请人： Arthur W. Chester ,  William E. Garwood ,  James C. Vartuli

    发明人： Arthur W. Chester ,  William E. Garwood ,  James C. Vartuli

    IPC分类号： C10G65/10 ,  B01J29/00 ,  B01J29/40 ,  B01J29/65 ,  C10G45/64 ,  C10G65/00 ,  C10G65/16 ,  C10G73/02 ,  C10G65/18 ,  C10G65/12 ,  C10G67/02

    CPC分类号： C10G65/00 ,  C10G45/64 ,  C10G65/16

    摘要： Relatively heavy and relatively light lube chargestocks are dewaxed in two parallel, separate reactors. The reactor used for dewaxing the relatively light chargestock contains a crystallize zeolite having pore openings defined by: (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, of greater than 3, which sorption is determined at a P/P.sub.o of 0.1 and at a temperature of 50.degree. C. for n-hexane and 80.degree. C. for o-xylene and (2) by the ability of selectively cracking 3-methylpentane (3MP) in preference to the doubly branched 2,3-dimethylbutane (DMB) at 1000.degree. F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methyl-pentane/2,3-dimethylbutane, with the ratio of rate constants k.sub.3MP /k.sub.DMB determined at a temperature of 1000.degree. F. being in excess of about 2, e.g., natural and synthetic ferrierite, ZSM-22, ZSM-23, ZSM-35 and mixtures thereof. The reactor used for dewaxing the relatively heavy chargestock contains a crystalline aluminosilicate zeolite having pore openings defined by: (1) a ratio of sorption of n-hexane to o-xylene, on a volume percent basis, or less than 3, which sorption is determined at a P/P.sub.o of 0.1 and at a temperature of 50.degree. C. for n-hexane and 80.degree. C. for o-xylene, (2) the abiilty of selectively cracking 3-methylpentane (3MP) in preference to the doubly branched 2,3-dimethylbutane (DMB) at 1000.degree. F. and 1 atmosphere pressure from a 1/1/1 weight ratio mixture of n-hexane/3-methyl-pentane/2,3-dimethylbutane, with the ratio of rate constants k.sub.3MP /K.sub.DMB determined at a temperature of 1000.degree. F. being less than about 2, and (3) a Constraint Index value of greater than about 1, e.g., ZSM-5, ZSM-11, ZSM-5/ZSM-11 intermediate and mixtures thereof.

    摘要翻译： 在两个平行的单独的反应器中，相对较重和相对较轻的润滑剂进料脱蜡。 用于脱蜡相对轻的原料的反应器包含具有孔开口的结晶沸石，其定义为：（1）正己烷与邻二甲苯的吸附比（以体积百分数计）大于3，该吸附确定 在P / Po为0.1，温度为50℃，正己烷和80℃为邻二甲苯，（2）通过选择性裂解3-甲基戊烷（3MP）的能力优于双 支链的2,3-二甲基丁烷（DMB），1/1重量比的正己烷/ 3-甲基 - 戊烷/ 2,3-二甲基丁烷混合物的1个大气压，比率 在1000°F的温度下测定的常数k3MP / kDMB超过约2，例如天然和合成镁碱沸石，ZSM-22，ZSM-23，ZSM-35及其混合物。 用于脱蜡相对较重的原料的反应器含有具有孔开口的结晶硅铝酸盐沸石，其定义为：（1）正己烷与邻二甲苯的吸附比，基于体积百分比或小于3，该吸附是 在P / Po为0.1，温度为50℃，正己烷和80℃为邻二甲苯时测定，（2）优选选择性裂解3-甲基戊烷（3MP），优于双 支链的2,3-二甲基丁烷（DMB），1/1重量比的正己烷/ 3-甲基 - 戊烷/ 2,3-二甲基丁烷混合物的1个大气压，比率 在1000°F的温度下测定的常数k3MP / KDMB小于约2，（3）大于约1的约束指数值，例如ZSM-5，ZSM-11，ZSM-5 / ZSM-11 中间体及其混合物。

    Aromatics processing
    35.
    发明授权
    Aromatics processing 失效
    芳香加工

    公开(公告)号：US4385195A

    公开(公告)日：1983-05-24

    申请号：US296601

    申请日：1981-08-26

    申请人： Stephen A. Butter ,  Arthur W. Chester

    发明人： Stephen A. Butter ,  Arthur W. Chester

    IPC分类号： B01J29/44 ,  C07C5/27 ,  C07C15/00 ,  C07C5/22 ,  C07C5/24 ,  C07C5/30

    CPC分类号： B01J29/44 ,  C07C5/2724 ,  B01J2229/26 ,  B01J2229/42

    摘要： A method of preparing aromatics processing catalysts which comprises incorporating a noble metal with a member or members of a useful class of zeolites, with such incorporation occurring after zeolite crystallization, but prior to final catalyst particle formation, i.e. extrusion into particles. Said useful class of zeolites is characterized by a silica to alumina mole ratio of at least 12 and a Constraint Index in the approximate range of 1 to 12.

    摘要翻译： 一种制备芳族化合物加工催化剂的方法，其包括将贵金属与有效类型的沸石的成员或成员结合，其结合发生在沸石结晶之后，但在最终催化剂颗粒形成之前，即挤出成颗粒。 所述有用类别的沸石的特征在于二氧化硅与氧化铝的摩尔比为至少12，约束指数在约1至12的范围内。

    Alkylation of isoparaffins with olefins
    36.
    发明授权
    Alkylation of isoparaffins with olefins 失效
    异链烷烃与烯烃的烷基化

    公开(公告)号：US4377721A

    公开(公告)日：1983-03-22

    申请号：US276227

    申请日：1981-06-22

    申请人： Arthur W. Chester ,  Yung-Feng Chu

    发明人： Arthur W. Chester ,  Yung-Feng Chu

    IPC分类号： B01J29/08 ,  C07C2/58

    CPC分类号： C07C2/58 ,  B01J29/08 ,  C07C2529/04

    摘要： An improved process for alkylation of isoparaffins with olefins to yield a product which includes a high proportion of highly branched alkylates for blending into gasolines. The improved process comprises contacting the isoparaffins and olefins with a catalyst comprising ZSM-20, preferably a HZSM-20 zeolite or a rare-earth cation exchanged ZSM-20 zeolite.

    摘要翻译： 用烯烃烷基化异链烷烃的改进方法，以产生包含高比例的高度支化的烷基化物用于共混到汽油中的产物。 改进的方法包括使异链烷烃和烯烃与包含ZSM-20，优选HZSM-20沸石或稀土阳离子交换的ZSM-20沸石的催化剂接触。

    Alkyltitanium and alkylchromium catalysts for olefin polymerization
    37.
    发明授权
    Alkyltitanium and alkylchromium catalysts for olefin polymerization 失效
    用于烯烃聚合的烷基钛和烷基铬催化剂

    公开(公告)号：US4376722A

    公开(公告)日：1983-03-15

    申请号：US315827

    申请日：1981-10-27

    申请人： Arthur W. Chester ,  James G. Murray

    发明人： Arthur W. Chester ,  James G. Murray

    IPC分类号： C08F4/42 ,  C08F10/00 ,  C08F4/02

    CPC分类号： C08F10/00

    摘要： Zeolite supported, organometallic based catalyst composition are provided which are especially suitable for the polymerization of 1-olefins such as ethylene. Alkyltitanium and alkylchromium compounds such as tributylchromium and tetrabutyltitanium are reacted with ZSM-5 type zeolites to produce such novel catalysts.

    摘要翻译： 提供了沸石负载的有机金属基催化剂组合物，其特别适用于1-烯烃如乙烯的聚合。 烷基钛和烷基铬化合物如三丁基铬和四丁基钛与ZSM-5型沸石反应生成这种新型催化剂。

    Conversion of synthesis gas with iron-containing catalyst
    39.
    发明授权
    Conversion of synthesis gas with iron-containing catalyst 失效
    用含铁催化剂转化合成气

    公开(公告)号：US4293446A

    公开(公告)日：1981-10-06

    申请号：US129551

    申请日：1980-03-12

    申请人： Stephen A. Butter ,  Arthur W. Chester

    发明人： Stephen A. Butter ,  Arthur W. Chester

    IPC分类号： B01J29/46 ,  B01J29/76 ,  B01J29/34

    CPC分类号： B01J29/46 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2529/46

    摘要： A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead utilizing a novel catalyst prepared from a water-insoluble organic iron compound. The novel method involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.

    摘要翻译： 公开了一种使用由水不溶性有机铁化合物制备的新型催化剂，以90％塔顶转化合成气至沸点范围小于400°F的液体烃产物的方法。 该新方法包括使合成气与含铁的单一颗粒催化剂接触，二氧化硅与氧化铝之比至少为12的结晶酸性硅铝酸盐沸石，孔径大于约5埃单位，约束指数约为1 到12，和矩阵。 催化剂不含助催化剂。

    Selective high conversion cracking process
    40.
    发明授权
    Selective high conversion cracking process 失效
    选择性高转化裂解过程

    公开(公告)号：US4137152A

    公开(公告)日：1979-01-30

    申请号：US850183

    申请日：1977-11-10

    申请人： Arthur W. Chester ,  Albert B. Schwartz ,  William A. Stover

    发明人： Arthur W. Chester ,  Albert B. Schwartz ,  William A. Stover

    IPC分类号： B01J29/08 ,  B01J29/12 ,  B01J29/18 ,  B01J29/80 ,  C10G11/05 ,  B01J8/24 ,  C07C15/02 ,  C10G11/04

    CPC分类号： C10G11/05 ,  B01J29/80 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/084 ,  B01J29/126 ,  B01J29/18

    摘要： A catalytic process is provided for cracking a hydrocarbon charge stock containing aromatic nuclei components and non-aromatic nuclei components which involves contacting such chargestock with a catalyst composition having an alkali metal content less than about 1.5 weight percent and containing a mixture of faujasite and mordenite in which contacting takes place under catalytic cracking conditions of such severity that the conversion level exceeds that attributable to conversion of the non-aromatic nuclei portion of the chargestock. Under such conditions, the coke yield is substantially lower than would be obtained with the same catalyst in the absence of mordenite at the same level of conversion.

    摘要翻译： 提供了一种催化方法，用于裂解含有芳族核组分和非芳族核组分的烃电荷原料，其包括使这些电荷与碱金属含量低于约1.5重量％的催化剂组合物接触并含有八面沸石和丝光沸石的混合物 该接触发生在催化裂解条件下，其严重程度使得转化率超过归因于电荷转运的非芳族核部分的转化率。 在这种条件下，焦炭产量基本上低于在不存在丝光沸石时相同催化剂在相同转化水平下获得的焦炭产量。